Cited by 122CO2 Sequestration and Geologic InteractionsGeochemistry and Elemental AnalysisMethane Hydrates and Related Phenomena

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Carbonate control of H2 and CH4 production in serpentinization systems at elevated P‐Ts

Jones, L. Camille, Rosenbauer, Robert, Goldsmith, Jonas I., Oze, Christopher·2010·Geophysical Research Letters

DOI 10.1029/2010gl043769

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Abstract

Serpentinization of forsteritic olivine results in the inorganic synthesis of molecular hydrogen (H 2) in ultramafic hydrothermal systems (e.g., mid‐ocean ridge and forearc environments). Inorganic carbon in those hydrothermal systems may react with H 2 to produce methane (CH 4) and other hydrocarbons or react with dissolved metal ions to form carbonate minerals. Here, we report serpentinization experiments at 200°C and 300 bar demonstrating Fe 2+ being incorporated into carbonates more rapidly than Fe 2+ oxidation (and concomitant H 2 formation) leading to diminished yields of H 2 and H 2‐dependent CH 4. In addition, carbonate formation is temporally fast in carbonate oversaturated fluids. Our results demonstrate that carbonate chemistry ultimately modulates the abiotic synthesis of both H 2 and CH 4 in hydrothermal ultramafic systems and that ultramafic systems present great potential for CO 2‐mineral sequestration.

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Authors: Jones, L. C., Rosenbauer, R., Goldsmith, J. I., & Oze, C.
Affiliations: Bryn Mawr College (US)
United States Geological Survey (US)
ORCID: Oze, Christopher
Venue: Geophysical Research Letters
Publisher: American Geophysical Union (AGU)
Published: 2010-07
Volume: 37
Issue: 14
ISSN: 0094-8276 (ISSN-L)
1944-8007
DOI: 10.1029/2010gl043769
OpenAlex: W2059798676
Cited by: 120
References: 19
Citations by year: 2026: 17 · 2025: 15 · 2024: 4 · 2023: 5 · 2022: 7 · 2021: 7 · 2020: 7 · 2019: 11 · 2018: 5 · 2017: 1 · 2016: 9 · 2015: 8 · 2014: 2 · 2013: 13 · 2012: 7
FWCI: 6.74
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor, 22 d)
Locations: Geophysical Research Letters (publishedVersion)
Scholarship, Research, and Creative Work at Bryn Mawr College (Bryn Mawr College) (submittedVersion)
Topics: Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
Physical Sciences › Environmental Science › Environmental Chemistry › Methane Hydrates and Related Phenomena
Keywords: serpentinization, methane production, carbonate precipitation, forsterite, ultramafic rocks, hydrothermal systems, high temperature and pressure, iron oxidation, CO2 mineralization

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Carbonate control of H2 and CH4 production in serpentinization systems at elevated P‐Ts

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