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Carbonate control of H2 and CH4 production in serpentinization systems at elevated P‐Ts
Abstract
Serpentinization of forsteritic olivine results in the inorganic synthesis of molecular hydrogen (H 2) in ultramafic hydrothermal systems (e.g., mid‐ocean ridge and forearc environments). Inorganic carbon in those hydrothermal systems may react with H 2 to produce methane (CH 4) and other hydrocarbons or react with dissolved metal ions to form carbonate minerals. Here, we report serpentinization experiments at 200°C and 300 bar demonstrating Fe 2+ being incorporated into carbonates more rapidly than Fe 2+ oxidation (and concomitant H 2 formation) leading to diminished yields of H 2 and H 2‐dependent CH 4. In addition, carbonate formation is temporally fast in carbonate oversaturated fluids. Our results demonstrate that carbonate chemistry ultimately modulates the abiotic synthesis of both H 2 and CH 4 in hydrothermal ultramafic systems and that ultramafic systems present great potential for CO 2‐mineral sequestration.
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“Higher CO2 concentrations are unlikely to overcome this restriction because Fe2+ will be incorporated into siderite rather than form magnetite and H2 (57).”
From Disequilibrium biosignatures over Earth history and implications for detecting exoplanet life (2018) · cites this paper as [57]
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Metadata
- Authors
- Jones, L. C., Rosenbauer, R., Goldsmith, J. I., & Oze, C.
- Affiliations
- Bryn Mawr College (US)
- United States Geological Survey (US)
- ORCID
- Oze, Christopher
- Venue
- Geophysical Research Letters
- Publisher
- American Geophysical Union (AGU)
- Published
- 2010-07
- Volume
- 37
- Issue
- 14
- ISSN
- 0094-8276 (ISSN-L)
- 1944-8007
- OpenAlex
- W2059798676
- Cited by
- 120
- References
- 19
- Citations by year
- 2026: 17 · 2025: 15 · 2024: 4 · 2023: 5 · 2022: 7 · 2021: 7 · 2020: 7 · 2019: 11 · 2018: 5 · 2017: 1 · 2016: 9 · 2015: 8 · 2014: 2 · 2013: 13 · 2012: 7
- FWCI
- 6.74
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geophysical Research Letters (publishedVersion)
- Scholarship, Research, and Creative Work at Bryn Mawr College (Bryn Mawr College) (submittedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Environmental Science › Environmental Chemistry › Methane Hydrates and Related Phenomena
- Keywords
- serpentinization, methane production, carbonate precipitation, forsterite, ultramafic rocks, hydrothermal systems, high temperature and pressure, iron oxidation, CO2 mineralization
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