The DOI matches its Crossref record; 12 of the 13 references it cites were found in a registry or an index.
Oxygen isotope behavior in the Sulfate-Water System
Abstract
Fundamental data on oxygen isotope behavior in the sulfate-water system are given. Oxygen exchange rates between sulfate ions and water are very slow and show a marked pH dependence. Of the order of 10/sup +3/ to 10/sup +5/ years are required to closely approach isotopic equilibrium at earth surface conditions. Oxygen isotope fractionation experiments yielded the following relationships: Ln alpha = 3878/(t+2) -0.0034 anhydrite water (and) Ln alpha = 3251/(t+2) -0.0056 dissolved sulfate water. During progressive evaporation of saturated CaSO/sub 4/ solution the gypsum formed tends to concentrate oxygen-18 relative to dissolved sulfate by 2%. Sulfate reducing bacteria preferentially metabolize oxygen-16 by about 4.6% in both pure and natural cultures. Oxidation of sulfide to sulfate in natural environments is a complex process making use of both water oxygen and molecular oxygen.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“This is consistent with the hydrothermal experiments of Lloyd (1968), Kusakabe and Robinson (1977) and Chiba et al. (1981).”
From Oxygen isotope fractionation in carbonate and sulfate minerals. (1999) · cites this paper as Lloyd (1968)
Citations
Cites
Craig, H. (1957) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(57)90024-8 · Cited by 4,170
The thermodynamic properties of isotopic substances
Urey, H. C. (1947) · Journal of the Chemical Society (Resumed) · doi:10.1039/jr9470000562 · Cited by 2,544
Urey, H. C., Lowenstam, H. A., Epstein, S., & McKinney, C. R. (1951) · Geological Society of America Bulletin · doi:10.1130/0016-7606(1951)62[399:mopato]2.0.co;2 · Cited by 809
Mechanism of the bacterial reduction of sulphate from isotope fractionation studies
Harrison, A. G., & Thode, H. G. (1958) · Transactions of the Faraday Society · doi:10.1039/tf9585400084 · Cited by 484
Oxygen-Isotope Fractionations in Systems Containing Dolomite
Northrop, D. A., & Clayton, R. N. (1966) · The Journal of Geology · doi:10.1086/627153 · Cited by 405
Oxygen-18 Composition of Oceanic Sulfate
Llyod, R. M. (1967) · Science · doi:10.1126/science.156.3779.1228 · Cited by 192
Oxygen-18 Variations in Sulfate Ions in Sea Water and Saline Lakes
Longinelli, A., & Craig, H. (1967) · Science · doi:10.1126/science.156.3771.56 · Cited by 173
Isotopic geochemistry of sulphur
Ault, W. U., & Kulp, J. L. (1959) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(59)90112-7 · Cited by 154
Clayton, R. N., & Epstein, S. (1958) · The Journal of Geology · doi:10.1086/626523 · Cited by 112
Oxidation rate of sulfide in sea water, A preliminary study
Göte, Ö. H., & Alexander, J. (1963) · Journal of Geophysical Research Atmospheres · doi:10.1029/jz068i013p03995 · Cited by 92
The Exchange of Oxygen between Sulfuric Acid and Water1
Hoering, T. C., & Kennedy, J. W. (1957) · Journal of the American Chemical Society · doi:10.1021/ja01558a013 · Cited by 78
Preliminary Study of Variations of Oxygen and Sulphur Isotope in Natural Sulphates
Rafter, T. A., & Mizutani, Y. (1967) · Nature · doi:10.1038/2161000a0 · Cited by 26
Research works printed but not linked: 3
- Sunge, 1957, The oxidation of sulfur dioxide in dilute solutions, Quart. J. Roy. Meteorol. Soc., 15, 46
- O'Neil, 1964, Cosmic and Isotopic Chemistry
- Teis, 1957, Isotopic composition of oxygen in natural sulfates, Geochemistry, USSR, 257
Cited by
Sorted by citations
Compilation of stable isotope fractionation factors of geochemical interest
Friedman, I., & O'Neil, J. R. (1977) · Professional Paper · doi:10.3133/pp440kk · Cited by 2,691
Oxygen Isotope Fractionation in Divalent Metal Carbonates
O'Neil, J. R., Clayton, R. N., & Mayeda, T. K. (1969) · The Journal of Chemical Physics · doi:10.1063/1.1671982 · Cited by 2,549
The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation
Claypool, G. E., Holser, W. T., Kaplan, I. R., Sakai, H., & Zak, I. (1980) · Chemical Geology · doi:10.1016/0009-2541(80)90047-9 · Cited by 1,948
Oxygen isotope exchange between quartz and water
Clayton, R. N., O'Neil, J. R., & Mayeda, T. K. (1972) · Journal of Geophysical Research · doi:10.1029/jb077i017p03057 · Cited by 1,513
The geochemistry of carbonate diagenesis: The past, present and future
Swart, P. K. (2015) · Sedimentology · doi:10.1111/sed.12205 · Cited by 775
Metadata
- Authors
- Lloyd, R. M.
- Corresponding author
- Lloyd, R. M.
- Venue
- Journal of Geophysical Research
- Publisher
- American Geophysical Union (AGU)
- Published
- 1968-09-15
- Volume
- 73
- Issue
- 18
- Pages
- 6099-6110
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2112478326
- Cited by
- 499
- References
- 13
- Citations by year
- 2026: 8 · 2025: 18 · 2024: 10 · 2023: 8 · 2022: 8 · 2021: 27 · 2020: 14 · 2019: 15 · 2018: 11 · 2017: 17 · 2016: 19 · 2015: 16 · 2014: 16 · 2013: 15 · 2012: 15
- FWCI
- 12.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- oxygen isotopes, oxygen exchange kinetics, isotope fractionation, anhydrite, gypsum, evaporation, pH dependence, sulfate-reducing bacteria, oxygen-16, sulfide oxidation, molecular oxygen, dissolved sulfate
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
