Cited by 1,865CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingElectrocatalysts for Energy Conversion

The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.

Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel

Gao, Shan, Lin, Yue, Jiao, Xingchen, Sun, Yongfu, Luo, Qiquan, Zhang, Wenhua, Li, Dianqi, Yang, Jinlong, Xie, Yi·2016·Nature

DOI 10.1038/nature16455

Open this paper in CoChat — free account

Abstract

Electroreduction of CO2 into useful fuels, especially if driven by renewable energy, represents a potentially 'clean' strategy for replacing fossil feedstocks and dealing with increasing CO2 emissions and their adverse effects on climate. The critical bottleneck lies in activating CO2 into the CO2(•-) radical anion or other intermediates that can be converted further, as the activation usually requires impractically high overpotentials. Recently, electrocatalysts based on oxide-derived metal nanostructures have been shown to enable CO2 reduction at low overpotentials. However, it remains unclear how the electrocatalytic activity of these metals is influenced by their native oxides, mainly because microstructural features such as interfaces and defects influence CO2 reduction activity yet are difficult to control. To evaluate the role of the two different catalytic sites, here we fabricate two kinds of four-atom-thick layers: pure cobalt metal, and co-existing domains of cobalt metal and cobalt oxide. Cobalt mainly produces formate (HCOO(-)) during CO2 electroreduction; we find that surface cobalt atoms of the atomically thin layers have higher intrinsic activity and selectivity towards formate production, at lower overpotentials, than do surface cobalt atoms on bulk samples. Partial oxidation of the atomic layers further increases their intrinsic activity, allowing us to realize stable current densities of about 10 milliamperes per square centimetre over 40 hours, with approximately 90 per cent formate selectivity at an overpotential of only 0.24 volts, which outperforms previously reported metal or metal oxide electrodes evaluated under comparable conditions. The correct morphology and oxidation state can thus transform a material from one considered nearly non-catalytic for the CO2 electroreduction reaction into an active catalyst. These findings point to new opportunities for manipulating and improving the CO2 electroreduction properties of metal systems, especially once the influence of both the atomic-scale structure and the presence of oxide are mechanistically better understood.

Integrity signals

Registry

Crossref · 10.1038/nature16455

Cites

26 of 26 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Low-temperature oxidation of CO catalysed by Co3O4 nanorods
Xie, X., Li, Y., Liu, Z., Haruta, M., & Shen, W. (2009) · Nature · doi:10.1038/nature07877 · Cited by 2,615
CO 2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu 2 O Films
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661
Freestanding palladium nanosheets with plasmonic and catalytic properties
Huang, X., Tang, S., Mu, X., Dai, Y., Chen, G., Zhou, Z., Ruan, F., Yang, Z., & Zheng, N. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2010.235 · Cited by 1,602
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons
Roy, S. C., Varghese, O. K., Paulose, M., & Grimes, C. A. (2010) · ACS Nano · doi:10.1021/nn9015423 · Cited by 1,528
A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,482
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate
Zhang, S., Kang, P., & Meyer, T. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4113885 · Cited by 1,159
Tin Oxide Dependence of the CO 2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts
Chen, Y., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2108799 · Cited by 982

Show all 26 references

Sorted by citations

Items 101–200 of 1,001

Heterostructured Catalysts for Electrocatalytic and Photocatalytic Carbon Dioxide Reduction
Prabhu, P., Jose, V. K., & Lee, J. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201910768 · Cited by 431
Metallenes as functional materials in electrocatalysis
Prabhu, P., & Lee, J.-M. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01041c · Cited by 427
In Situ Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface‐Bound Nickel Single‐Atom Catalysts
Yang, J., Qiu, Z., Zhao, C., Wei, W.-C., Chen, W., Li, Z., Qu, Y., Dong, J., Luo, J., Li, Z., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201808049 · Cited by 424
Self-citation
Transition-Metal Single Atoms in a Graphene Shell as Active Centers for Highly Efficient Artificial Photosynthesis
Jiang, K., Siahrostami, S., Akey, A. J., Li, Y., Lu, Z., Lattimer, J., Hu, Y., Stokes, C., Gangishetty, M., Chen, G., et al. (2017) · Chem · doi:10.1016/j.chempr.2017.09.014 · Cited by 406
Hybrid nanostructures of metal/two-dimensional nanomaterials for plasmon-enhanced applications
Li, X., Zhu, J., & Wei, B. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00195e · Cited by 405
Carbon‐Based Metal‐Free Catalysts for Key Reactions Involved in Energy Conversion and Storage
Zhao, S., Wang, D., Amal, R., & Dai, L. (2018) · Advanced Materials · doi:10.1002/adma.201801526 · Cited by 410
Boosting Formate Production in Electrocatalytic CO 2 Reduction over Wide Potential Window on Pd Surfaces
Jiang, B., Zhang, X.-G., Jiang, K., Wu, D.-Y., & Cai, W.-B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12506 · Cited by 402
Emerging beyond-graphene elemental 2D materials for energy and catalysis applications
Fan, F. R., Wang, R., Zhang, H., & Wu, W. (2021) · Chemical Society Reviews · doi:10.1039/c9cs00821g · Cited by 405
Progress and perspective for conversion of plastic wastes into valuable chemicals
Zheng, K., Wu, Y. J., Hu, Z., Wang, S., Jiao, X., Zhu, J., Sun, Y., & Xie, Y. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00688j · Cited by 401
Self-citation
Hydroxide promotes carbon dioxide electroreduction to ethanol on copper via tuning of adsorbed hydrogen
Luo, M., Wang, Z., Li, Y., Li, J., Li, F., Lum, Y., Nam, D., Chen, B., Wicks, J., Xu, A., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-13833-8 · Cited by 412
Fundamentals and challenges of ultrathin 2D photocatalysts in boosting CO 2 photoreduction
Jiao, X., Zheng, K., Liang, L., Li, X., Sun, Y., & Xie, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00332h · Cited by 396
Self-citation
Recent advances in electrocatalysis with phthalocyanines
Yang, S., Yu, Y., Gao, X., Zhang, Z., & Wang, F. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01605e · Cited by 395
From Solar Energy to Fuels: Recent Advances in Light‐Driven C1 Chemistry
Chen, G., Waterhouse, G. I. N., Shi, R., Zhao, J., Li, Z., Wu, L., Tung, C., & Zhang, T. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201814313 · Cited by 396
Facet effect of Pd cocatalyst on photocatalytic CO 2 reduction over g-C 3 N 4
Cao, S., Li, Y., Zhu, B., Jaroniec, M., & Yu, J. (2017) · Journal of Catalysis · doi:10.1016/j.jcat.2017.02.005 · Cited by 388
MOF-derived bi-metal embedded N-doped carbon polyhedral nanocages with enhanced lithium storage
Huang, M., Mi, K., Zhang, J., Liu, H., Yu, T., Yuan, A., Kong, Q., & Xiong, S. L. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta09030c · Cited by 380
Controlling cation segregation in perovskite-based electrodes for high electro-catalytic activity and durability
Li, Y., Zhang, W., Zheng, Y. H., Chen, J., Yu, B. H., Chen, Y., & Liu, M. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00120g · Cited by 383
Self-citation
Controlled Synthesis of a Vacancy‐Defect Single‐Atom Catalyst for Boosting CO 2 Electroreduction
Rong, X., Wang, H., Lu, X., Si, R., & Lu, T. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201912458 · Cited by 379
Ultrathin Ni(0)‐Embedded Ni(OH) 2 Heterostructured Nanosheets with Enhanced Electrochemical Overall Water Splitting
Dai, L., Chen, Z., Li, L., Yin, P., Liu, Z., & Zhang, H. (2020) · Advanced Materials · doi:10.1002/adma.201906915 · Cited by 380
An alkaline polymer electrolyte CO 2 electrolyzer operated with pure water
Yin, Z., Peng, H., Wei, X., Zhou, H., Gong, J. Y., Huai, M., Xiao, L., Wang, G., Lu, J., & Zhuang, L. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01204d · Cited by 384
Two-Dimensional Covalent Organic Frameworks with Cobalt(II)-Phthalocyanine Sites for Efficient Electrocatalytic Carbon Dioxide Reduction
Han, B., Ding, X., Yu, B., Wu, H., Zhou, W., Liu, W., Wei, C., Chen, B., Qi, D., Wang, H., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c02145 · Cited by 377
In Situ Reconstruction of a Hierarchical Sn‐Cu/SnO x Core/Shell Catalyst for High‐Performance CO 2 Electroreduction
Ye, K., Zhou, Z., Shao, J., Lin, L., Gao, D., Ta, N., Si, R., Wang, G., & Bao, X. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201916538 · Cited by 374
Highly Selective Reduction of CO2 to C2+ Hydrocarbons at Copper/Polyaniline Interfaces
Wei, X., Yin, Z., Lyu, K., Li, Z., Gong, J. Y., Wang, G., Xiao, L., Lu, J., & Zhuang, L. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c00049 · Cited by 377
Progress in catalyst exploration for heterogeneous CO 2 reduction and utilization: a critical review
Zhao, G., Huang, X., Wang, X., & Wang, X. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta07290b · Cited by 375
Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells
Brennaman, M. K., Dillon, R. J., Alibabaei, L., Gish, M. K., Dares, C. J., Ashford, D. L., House, R. L., Meyer, G. J., Papanikolas, J. M., & Meyer, T. J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06466 · Cited by 374
Electrolytic cell design for electrochemical CO2 reduction
Liang, S., Altaf, N., Huang, L., Gao, Y., & Wang, Q. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.09.007 · Cited by 383
Rationally Designing Bifunctional Catalysts as an Efficient Strategy To Boost CO2 Hydrogenation Producing Value-Added Aromatics
Wang, Y., Tan, L., Tan, M., Zhang, P., Fang, Y., Yoneyama, Y., Yang, G., & Tsubaki, N. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01344 · Cited by 367
Surface Immobilization of Transition Metal Ions on Nitrogen‐Doped Graphene Realizing High‐Efficient and Selective CO2 Reduction
Bi, W., Li, X., You, R., Chen, M., Yuan, R., Huang, W., Wu, X., Chu, W., Wu, C., & Xie, Y. (2018) · Advanced Materials · doi:10.1002/adma.201706617 · Cited by 361
Self-citation
Orbital Interactions in Bi‐Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO 2 Reduction toward Formate Production
Wen, G., Lee, D. U., Ren, B., Hassan, F. M. B., Jiang, G., Cano, Z. P., Gostick, J. T., Croiset, E., Bai, Z., Yang, L., et al. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201802427 · Cited by 366
Morphology‐Directed Selective Production of Ethylene or Ethane from CO2 on a Cu Mesopore Electrode
Yang, K. D., Ko, W. R., Lee, J., Kim, S. J., Lee, H., Lee, M. H., & Nam, K. T. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201610432 · Cited by 359
Oxygen defective metal oxides for energy conversion and storage
Wang, G., Yang, Y., Han, D., & Li, Y. (2017) · Nano Today · doi:10.1016/j.nantod.2017.02.009 · Cited by 358
Metal Surface and Interface Energy Electrocatalysis: Fundamentals, Performance Engineering, and Opportunities
Yang, Y., Luo, M., Zhang, W., Sun, Y., Xu, C., & Guo, S. (2018) · Chem · doi:10.1016/j.chempr.2018.05.019 · Cited by 356
Self-citation
Quasi-Covalently Coupled Ni–Cu Atomic Pair for Synergistic Electroreduction of CO 2
Zhu, J., Xiao, M., Ren, D., Gao, R., Liu, X., Zhang, Z., Luo, D., Xing, W., Su, D., Yu, A., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c00937 · Cited by 351
Elemental two-dimensional nanosheets beyond graphene
Kong, X., Liu, Q., Zhang, C., Peng, Z., & Chen, Q. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00937a · Cited by 345
Crucial Role of Surface Hydroxyls on the Activity and Stability in Electrochemical CO2 Reduction
Deng, W., Zhang, L., Li, L., Chen, S., Hu, C., Zhao, Z., Wang, T., & Gong, J. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b13786 · Cited by 345
Electronic Modulation of Non‐van der Waals 2D Electrocatalysts for Efficient Energy Conversion
Wang, H., Chen, J., Lin, Y., Wang, X., Li, J., Li, Y., Gao, L., Zhang, L., Chao, D., Xiao, X. R., et al. (2021) · Advanced Materials · doi:10.1002/adma.202008422 · Cited by 344
Self-citation
Amorphizing of Cu Nanoparticles toward Highly Efficient and Robust Electrocatalyst for CO 2 Reduction to Liquid Fuels with High Faradaic Efficiencies
Duan, Y., Meng, F., Liu, K., Yi, S., Li, S., Yan, J., & Jiang, Q. (2018) · Advanced Materials · doi:10.1002/adma.201706194 · Cited by 345
Manganese acting as a high-performance heterogeneous electrocatalyst in carbon dioxide reduction
Zhang, B., Zhang, J., Shi, J., Tan, D., Liu, L., Zhang, F., Su, Z., Su, Z., Tan, X., Cheng, X., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-10854-1 · Cited by 344
Oxygen vacancy associated single-electron transfer for photofixation of CO2 to long-chain chemicals
Chen, S., Wang, H., Kang, Z., Jin, S., Zhang, X., Zheng, X., Qi, Z., Zhu, J., Pan, B., & Xie, Y. (2019) · Nature Communications · doi:10.1038/s41467-019-08697-x · Cited by 341
Self-citation
Recent Progress of Carbon-Supported Single-Atom Catalysts for Energy Conversion and Storage
Yang, Y., Yang, Y., Pei, Z., Wu, K., Tan, C. H., Wang, H., Li, W., Mahmood, A., Yan, C., Dong, J., et al. (2020) · Matter · doi:10.1016/j.matt.2020.07.032 · Cited by 341
A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible‐Light Driven CO2 Reduction to CO in CH3CN/H2O Solution
Ouyang, T., Huang, H., Wang, J., Zhong, D., & Lu, T. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201610607 · Cited by 337
Pd-Containing Nanostructures for Electrochemical CO2 Reduction Reaction
Gao, D., Zhou, H., Cai, F., Wang, J., Wang, G., & Bao, X. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03612 · Cited by 338
Adjacent Copper Single Atoms Promote C–C Coupling in Electrochemical CO 2 Reduction for the Efficient Conversion of Ethanol
Xia, W., Xie, Y., Jia, S., Han, S., Qi, R., Chen, T., Xing, X., Yao, T., Zhou, D., Dong, X. H., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c04612 · Cited by 340
Self-citation
Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation
Zhou, H., Fang, Y., Sun, J., He, R., Chen, S., Chu, C. W., & Ren, Z. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1701562114 · Cited by 335
Cu 2 O Nanoparticles with Both {100} and {111} Facets for Enhancing the Selectivity and Activity of CO 2 Electroreduction to Ethylene
Gao, Y., Wu, Q., Liang, X., Wang, Z., Zheng, Z., Wang, P., Liu, Y., Dai, Y., Whangbo, M., & Huang, B. (2020) · Advanced Science · doi:10.1002/advs.201902820 · Cited by 334
Identifying Active Sites of Nitrogen‐Doped Carbon Materials for the CO2 Reduction Reaction
Liu, S., Yang, H., Huang, X., Liu, L., Cai, W., Gao, J., Li, X., Zhang, T., Huang, Y., & Liu, B. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201800499 · Cited by 336
Electrocatalytic carbon dioxide reduction: from fundamental principles to catalyst design
Zhang, X., Guo, S., Gandionco, K. A., Bond, A. M., & Zhang, J. (2020) · Materials Today Advances · doi:10.1016/j.mtadv.2020.100074 · Cited by 345
Exclusive Formation of Formic Acid from CO 2 Electroreduction by a Tunable Pd‐Sn Alloy
Bai, X., Chen, W., Zhao, C., Li, S., Song, Y., Ge, R., Wei, W., & Sun, Y. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201707098 · Cited by 332
Self-citation
Towards a better Sn: Efficient electrocatalytic reduction of CO2 to formate by Sn/SnS2 derived from SnS2 nanosheets
Li, F., Chen, L., Xue, M., Williams, T., Zhang, Y., MacFarlane, D. R., & Zhang, J. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.11.004 · Cited by 327
The role of oxygen-vacancy in bifunctional indium oxyhydroxide catalysts for electrochemical coupling of biomass valorization with CO2 conversion
Ye, F., Zhang, S., Cheng, Q., Long, Y., Liu, D., Paul, R., Fang, Y., Su, Y., Qu, L., Dai, L., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-37679-3 · Cited by 345
Electrochemical Conversion of CO 2 to Syngas with Controllable CO/H 2 Ratios over Co and Ni Single‐Atom Catalysts
He, Q., Liu, D., Lee, J. H., Liu, Y., Xie, Z., Hwang, S., Kattel, S. P., Song, L., & Chen, J. G. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201912719 · Cited by 323
Electrocatalytic Alloys for CO2 Reduction
He, J., Johnson, N. J. J., Huang, A., & Berlinguette, C. P. (2017) · ChemSusChem · doi:10.1002/cssc.201701825 · Cited by 327
Liquid-phase exfoliated ultrathin Bi nanosheets: Uncovering the origins of enhanced electrocatalytic CO2 reduction on two-dimensional metal nanostructure
Zhang, W., Hu, Y. T., Ma, L., Zhu, G., Zhao, P., Xue, X., Chen, R., Yang, S., Ma, J., Liu, J., et al. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.09.053 · Cited by 314
Self-citation
Efficient Electrocatalytic Reduction of CO 2 by Nitrogen‐Doped Nanoporous Carbon/Carbon Nanotube Membranes: A Step Towards the Electrochemical CO 2 Refinery
Wang, H., Jia, J., Song, P., Wang, Q., Li, D., Min, S., Qian, C., Wang, L., Li, Y. F., Ma, C., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201703720 · Cited by 316
Self-citation
Bi‐Based Metal‐Organic Framework Derived Leafy Bismuth Nanosheets for Carbon Dioxide Electroreduction
Yang, J., Wang, X., Qu, Y., Wang, X., Huo, H., Fan, Q., Wang, J., Yang, L., & Wu, Y. S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001709 · Cited by 314
Self-citation
Regulating the oxidation state of nanomaterials for electrocatalytic CO 2 reduction
Wu, Z., Gao, F., & Gao, M. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02747b · Cited by 314
Recent Progresses in Electrochemical Carbon Dioxide Reduction on Copper‐Based Catalysts toward Multicarbon Products
Yu, J., Wang, J., Ma, Y., Zhou, J., Wang, Y., Lu, P., Yin, J., Ye, R., Zhu, Z., & Fan, Z. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202102151 · Cited by 317
Highly Efficient Electroreduction of CO2 to Methanol on Palladium–Copper Bimetallic Aerogels
Lu, L., Sun, X., Ma, J., Yang, D., Wu, H., Zhang, B., Zhang, J., & Han, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201808964 · Cited by 310
Energy related CO2 conversion and utilization: Advanced materials/nanomaterials, reaction mechanisms and technologies
Zheng, Y. H., Zhang, W., Li, Y., Chen, J., Yu, B. H., Wang, J., Zhang, L., & Zhang, J. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.08.049 · Cited by 314
Self-citation
Recent Advances in Growth of Novel 2D Materials: Beyond Graphene and Transition Metal Dichalcogenides
Geng, D., & Yang, H. Y. (2018) · Advanced Materials · doi:10.1002/adma.201800865 · Cited by 313
Regulation of Coordination Number over Single Co Sites: Triggering the Efficient Electroreduction of CO 2
Wang, X., Chen, Z., Zhao, X., Yao, T., Chen, W., You, R., Zhao, C., Wu, G., Wang, J., Huang, W., et al. (2017) · Angewandte Chemie · doi:10.1002/ange.201712451 · Cited by 311
Self-citation
Challenges and Opportunities in Electrocatalytic CO 2 Reduction to Chemicals and Fuels
She, X., Wang, Y., Xu, H. F., Tsang, S. C. E., & Lau, S. P. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202211396 · Cited by 317
Selective Electrochemical Reduction of Carbon Dioxide to Ethanol on a Boron‐ and Nitrogen‐Co‐doped Nanodiamond
Liu, Y., Zhang, Y., Cheng, K. F., Quan, X., Fan, X., Su, Y., Chen, S., Zhao, H., Zhang, Y., Yu, H., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201706311 · Cited by 315
Regulating the coordination structure of metal single atoms for efficient electrocatalytic CO 2 reduction
Wang, Y., Liu, Y., Liu, W., Wu, J., Li, Q., Feng, Q., Chen, Z., Xiong, X., Wang, D. S., & Lei, Y. (2020) · Energy & Environmental Science · doi:10.1039/d0ee02833a · Cited by 306
Review on strategies for improving the added value and expanding the scope of CO 2 electroreduction products
Jiang, M., Wang, H., Zhu, M., Luo, X., He, Y. N., Wang, M., Wu, C., Zhang, L., Xiao, L., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 306
Sulfur-Modified Copper Catalysts for the Electrochemical Reduction of Carbon Dioxide to Formate
Shinagawa, T., Larrazábal, G. O., Martín, A. J., Krumeich, F., & Pérez‐Ramírez, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b03161 · Cited by 307
Recent advances in two-dimensional materials and their nanocomposites in sustainable energy conversion applications
Khan, K., Tareen, A. K., Aslam, M., Zhang, Y., Wang, R., Ouyang, Z., Gou, Z., & Zhang, H. (2019) · Nanoscale · doi:10.1039/c9nr05919a · Cited by 310
Uniform Ordered Two-Dimensional Mesoporous TiO2 Nanosheets from Hydrothermal-Induced Solvent-Confined Monomicelle Assembly
Lan, K., Liu, Y., Zhang, W., Liu, Y., Elzatahry, A. A. F., Wang, R., Xia, Y., Aldhayan, D. M., Zheng, N., & Zhao, D. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b00909 · Cited by 303
Self-citation
Metal-organic framework membranes with single-atomic centers for photocatalytic CO2 and O2 reduction
Hao, Y., Chen, L., Li, J., Guo, Y., Su, X., Shu, M., Zhang, Q., Gao, W., Li, S., Yu, Z., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-22991-7 · Cited by 303
Hierarchical Cu@CoFe layered double hydroxide core-shell nanoarchitectures as bifunctional electrocatalysts for efficient overall water splitting
Yu, L., Zhou, H., Sun, J., Qin, F., Luo, D., Xie, L., Fang, Y., Bao, J., Li, Y., Yu, Y., et al. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.09.045 · Cited by 302
Design of Single-Atom Catalysts and Tracking Their Fate Using Operando and Advanced X-ray Spectroscopic Tools
Sarma, B. B., Maurer, F., Doronkin, D. E., & Grunwaldt, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00495 · Cited by 313
From CO 2 methanation to ambitious long-chain hydrocarbons: alternative fuels paving the path to sustainability
Mota, F. M., & Kim, D. H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00527c · Cited by 293
Ethylene Selectivity in Electrocatalytic CO2 Reduction on Cu Nanomaterials: A Crystal Phase-Dependent Study
Chen, Y., Fan, Z., Wang, J., Ling, C., Niu, W., Huang, Z., Liu, G., Chen, B., Lai, Z., Liu, X., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c04981 · Cited by 292
Two-dimensional biomaterials: material science, biological effect and biomedical engineering applications
Huang, H., Feng, W., & Chen, Y. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01138j · Cited by 289
RETRACTED ARTICLE: Theory-guided Sn/Cu alloying for efficient CO2 electroreduction at low overpotentials
Zheng, X. R., Ji, Y., Tang, J., Wang, J., Liu, B., Steinrück, H., Lim, K., Li, Y., Toney, M. F., Chan, K., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0200-8 · Cited by 289
Retracted
Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces
Esrafilzadeh, D., Zavabeti, A., Jalili, R., Atkin, P., Choi, J., Carey, B. J., Brkljača, R., O'Mullane, A. P., Dickey, M. D., Officer, D. L., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-08824-8 · Cited by 285
Facile synthesis of single-nickel-atomic dispersed N-doped carbon framework for efficient electrochemical CO2 reduction
Lu, P., Yang, Y., Yao, J., Wang, M., Dilpazir, S., Yuan, M., Zhang, J., Wang, X., Xie, Z., & Zhang, G. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.09.025 · Cited by 284
Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles
Gao, D., Zhou, H., Cai, F., Wang, D., Hu, Y., Jiang, B., Cai, W., Chen, X., Si, R., Yang, F., et al. (2017) · Nano Research · doi:10.1007/s12274-017-1514-6 · Cited by 284
Electrochemical Reduction of Carbon Dioxide to Methanol on Hierarchical Pd/SnO2 Nanosheets with Abundant Pd–O–Sn Interfaces
Zhang, W., Qin, Q., Dai, L., Qin, R., Zhao, X., Chen, X., Ou, D., Chen, J., Chuong, T. T., Wu, B., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201804142 · Cited by 283
Self-citation
Recent progress in high-entropy alloys for catalysts: synthesis, applications, and prospects
Li, K., & Chen, W. (2021) · Materials Today Energy · doi:10.1016/j.mtener.2021.100638 · Cited by 279
Surface‐Confined Fabrication of Ultrathin Nickel Cobalt‐Layered Double Hydroxide Nanosheets for High‐Performance Supercapacitors
Yang, J., Yu, C., Hu, C., Wang, M., Li, S., Huang, H., Bustillo, K. C., Han, X., Zhao, C., Guo, W., et al. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201803272 · Cited by 279
Self-citation
Molybdenum–Bismuth Bimetallic Chalcogenide Nanosheets for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Methanol
Sun, X., Zhu, Q., Kang, X., Liu, H., Qian, Q., Zhang, Z., & Han, B. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201603034 · Cited by 279
Sub-1.1 nm ultrathin porous CoP nanosheets with dominant reactive {200} facets: a high mass activity and efficient electrocatalyst for the hydrogen evolution reaction
Zhang, C., Huang, Y., Yu, Y., Zhang, J., Zhuo, S., & Zhang, B. (2017) · Chemical Science · doi:10.1039/c6sc05687c · Cited by 273
Efficient and Selective CO2 Reduction Integrated with Organic Synthesis by Solar Energy
Guo, Q., Liang, F., Li, X., Gao, Y., Huang, M., Wang, Y., Xia, S., Gao, X., Gan, Q., Lin, Z., et al. (2019) · Chem · doi:10.1016/j.chempr.2019.06.019 · Cited by 277
Amination strategy to boost the CO 2 electroreduction current density of M–N/C single-atom catalysts to the industrial application level
Chen, Z., Zhang, X., Liu, W., Jiao, M., Mou, K., Wang, Z., Ma, X., Cheng, F., Zhang, X., & Liu, L. (2021) · Energy & Environmental Science · doi:10.1039/d0ee04052e · Cited by 274
Reaction mechanism and kinetics for CO2 reduction on nickel single atom catalysts from quantum mechanics
Hossain, M. D., Huang, Y., Yu, T. H., Goddard, W. A., & Luo, Z. (2020) · Nature Communications · doi:10.1038/s41467-020-16119-6 · Cited by 274
Atomic Ni Anchored Covalent Triazine Framework as High Efficient Electrocatalyst for Carbon Dioxide Conversion
Lu, C., Yang, J., Wei, S., Bi, S., Xia, Y., Chen, M., Hou, Y., Qiu, M., Yuan, C. Y., Su, Y., et al. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201806884 · Cited by 271
Self-citation
Role of zirconium in direct CO2 hydrogenation to lower olefins on oxide/zeolite bifunctional catalysts
Dang, S., Gao, P., Liu, Z., Chen, X., Yang, C., Wang, H., Zhong, L., Li, S., & Sun, Y. (2018) · Journal of Catalysis · doi:10.1016/j.jcat.2018.06.010 · Cited by 270
Self-citation
Ultrastable atomic copper nanosheets for selective electrochemical reduction of carbon dioxide
Dai, L., Qin, Q., Wang, P., Zhao, X., Hu, C., Liu, P., Qin, R., Chen, M., Ou, D., Xu, C., et al. (2017) · Science Advances · doi:10.1126/sciadv.1701069 · Cited by 268
Rational design of cobalt–chromium layered double hydroxide as a highly efficient electrocatalyst for water oxidation
Dong, C., Yuan, X., Wang, X., Liu, X., Dong, W., Wang, R., Duan, Y., & Huang, F. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta04052g · Cited by 267
Efficient Methane Electrosynthesis Enabled by Tuning Local CO2 Availability
Wang, X., Xu, A., Li, F., Hung, S., Nam, D., Gabardo, C. M., Wang, Z., Xu, Y., Ozden, A., Rasouli, A. S., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b12445 · Cited by 269
Noble-Metal-Free Multicomponent Nanointegration for Sustainable Energy Conversion
Lu, H., Tournet, J., Dastafkan, K., Liu, Y., Ng, Y. H., Karuturi, S. K., Zhao, C., & Yin, Z. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01328 · Cited by 267
Boosting water decomposition by sulfur vacancies for efficient CO 2 photoreduction
Yin, S., Zhao, X., Jiang, E., Yan, Y., Zhou, P. C., & Huo, P. (2022) · Energy & Environmental Science · doi:10.1039/d1ee03764a · Cited by 263
Two-dimensional nanosheets for electrocatalysis in energy generation and conversion
Tao, H., Gao, Y., Talreja, N., Guo, F., Texter, J. A., Yan, C., & Sun, Z. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta00075h · Cited by 261
Synergistic enhancement of electrocatalytic CO2 reduction to C2 oxygenates at nitrogen-doped nanodiamonds/Cu interface
Wang, H., Tzeng, Y., Ji, Y., Li, Y., Li, J., Zheng, X. R., Yang, A., Liu, Y., Gong, Y., Cai, L., et al. (2020) · Nature Nanotechnology · doi:10.1038/s41565-019-0603-y · Cited by 267
In-situ construction of lattice-matching NiP2/NiSe2 heterointerfaces with electron redistribution for boosting overall water splitting
Yang, L., Huang, L., Yao, Y., & Jiao, L. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119584 · Cited by 261
2D Metal Oxyhalide‐Derived Catalysts for Efficient CO2 Electroreduction
García de Arquer, F. P., Bushuyev, O. S., De Luna, P., Dinh, C., Seifitokaldani, A., Saidaminov, M. I., Tan, C., Quan, L. N., Proppe, A., Kibria, M. G., et al. (2018) · Advanced Materials · doi:10.1002/adma.201802858 · Cited by 260
Accelerating CO 2 Electroreduction to CO Over Pd Single‐Atom Catalyst
He, Q., Lee, J. H., Liu, D., Liu, Y., Lin, Z., Xie, Z., Hwang, S., Kattel, S. P., Song, L., & Chen, J. G. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000407 · Cited by 263
Oxygen vacancies enhanced cooperative electrocatalytic reduction of carbon dioxide and nitrite ions to urea
Cao, N., Quan, Y., Guan, A., Yang, C., Ji, Y., Zhang, L., & Zheng, G. (2020) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2020.05.014 · Cited by 259
Cobalt oxide-based nanoarchitectures for electrochemical energy applications
Mei, J., Liao, T., Ayoko, G. A., Bell, J. M., & Sun, Z. (2019) · Progress in Materials Science · doi:10.1016/j.pmatsci.2019.03.001 · Cited by 264
Integration of Strong Electron Transporter Tetrathiafulvalene into Metalloporphyrin-Based Covalent Organic Framework for Highly Efficient Electroreduction of CO 2
Wu, Q., Xie, R., Mao, M., Chai, G., Yi, J., Zhao, S., Huang, Y., & Cao, R. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.9b02756 · Cited by 258

Authors: Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y.
Affiliations: University of Science and Technology of China (CN)
Corresponding author: Sun, Yongfu
Xie, Yi
ORCID: Gao, Shan
Lin, Yue
Jiao, Xingchen
Sun, Yongfu
Luo, Qiquan
Zhang, Wenhua
Yang, Jinlong
Xie, Yi
Venue: Nature
Publisher: Springer Science and Business Media LLC
Published: 2016-01
Volume: 529
Issue: 7584
Pages: 68-71
ISSN: 0028-0836 (ISSN-L)
1476-4687
DOI: 10.1038/nature16455
OpenAlex: W2227974961
Cited by: 1,865
References: 26
Citations by year: 2026: 62 · 2025: 108 · 2024: 153 · 2023: 154 · 2022: 195 · 2021: 222 · 2020: 264 · 2019: 226 · 2018: 233 · 2017: 171 · 2016: 77
FWCI: 63.89
Type: journal article
Language: en
Open access: closed
Licence: www.springer.com/tdm (tdm)
Locations: Nature (publishedVersion)
PubMed (publishedVersion)
RePEc: Research Papers in Economics (submittedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords: carbon dioxide electroreduction, cobalt electrocatalyst, atomic layers, cobalt oxide, partial oxidation, formate production, CO2 radical anion, liquid fuels, CO2 emission reduction, catalyst stability, CO2 selectivity

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks