Highly Efficient Electroreduction of CO2 to Methanol on Palladium–Copper Bimetallic Aerogels
Abstract
Electrochemical reduction of CO 2 to CH 3 OH is of great interest. Aerogels have fine inorganic superstructure with high porosity and are known to be exceptional materials. Now a Pd-Cu bimetallic aerogel electrocatalyst has been developed for conversion of CO 2 into CH 3 OH. The current density and Faradaic efficiency of CH 3 OH can be as high as 31.8 mA cm -2 and 80.0 % over the Pd 83 Cu 17 aerogel at a very low overpotential (0.24 V). The superior performance of the electrocatalyst results from efficient adsorption and stabilization of the CO 2 radical anion, high Pd 0 /Pd II and Cu I +Cu 0 /Cu II ratios, and sufficient Pd/Cu grain boundaries of aerogel nanochains.
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Increasing temperature to promote the synthesis of aerogels has been reported, but the time required is not satisfactory, with reaction times of several hours.
“Increasing temperature to promote the synthesis of aerogels has been reported, but the time required for the synthesis is not satisfactory, and the reaction time of several hours does not highlight the superiority of this method.31,42−44”
From Ultrafast Generation of Nanostructured Noble Metal Aerogels by a Microwave Method for Electrocatalytic Hydrogen Evolution and Ethanol Oxidation (2021) · cites this paper as [31]
The one-step method for preparing NMAs usually requires a longer cycle to settle the gel (up to several days at room temperature).
“it usually requires a longer cycle to settle the gel (up to several days at room temperature).”
From Ultrafast Generation of Nanostructured Noble Metal Aerogels by a Microwave Method for Electrocatalytic Hydrogen Evolution and Ethanol Oxidation (2021) · cites this paper as [31]
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Bimetallic Electrocatalysts for CO2 Reduction
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Closing the Anthropogenic Chemical Carbon Cycle toward a Sustainable Future via CO2 Valorization
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Self-citationIonic Liquids Promoted Transformation of Carbon Dioxide
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Technological advances in the transformative utilization of CO2 to value-added products
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Electrochemical CO2 Reduction on Cu: Synthesis‐Controlled Structure Preference and Selectivity
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Multi-shelled CuO microboxes for carbon dioxide reduction to ethylene
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Structure‐Tunable Copper–Indium Catalysts for Highly Selective CO2 Electroreduction to CO or HCOOH
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Cu 2 O/CuO Electrocatalyst for Electrochemical Reduction of Carbon Dioxide to Methanol
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CuSn Alloy Nanoparticles on Nitrogen‐Doped Graphene for Electrocatalytic CO2 Reduction
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Palladium-Copper bimetallic catalysts for electroreduction of CO2 and nitrogenous species
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Electrochemical CO2 reduction: From catalysts to reactive thermodynamics and kinetics
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Electrochemical CO 2 reduction with ionic liquids: review and evaluation
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Strong effect-correlated electrochemical CO 2 reduction
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Self-citationBoron-doped CuO nanobundles for electroreduction of carbon dioxide to ethylene
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Self-citationElectrodeposited Cu–Pd bimetallic catalysts for the selective electroreduction of CO 2 to ethylene
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Self-citationLewis‐Basic EDTA as a Highly Active Molecular Electrocatalyst for CO2 Reduction to CH4
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Ag-Cu aerogel for electrochemical CO2 conversion to CO
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Self-citationHighly Selective CO 2 Electroreduction to CO on Cu–Co Bimetallic Catalysts
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Self-citationTunable selectivity on copper–bismuth bimetallic aerogels for electrochemical CO2 reduction
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CO 2 valorisation towards alcohols by Cu-based electrocatalysts: challenges and perspectives
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A rhenium catalyst with bifunctional pyrene groups boosts natural light-driven CO 2 reduction
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Catalyst Design for Electrolytic CO2 Reduction Toward Low-Carbon Fuels and Chemicals
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Tandem strategy for electrochemical CO2 reduction reaction
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Self-citationEnhancing electroreduction of CO 2 over Bi 2 WO 6 nanosheets by oxygen vacancies
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Self-citationComposition-Tuned Surface Binding on CuZn-Ni Catalysts Boosts CO2RR Selectivity toward CO Generation
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- Authors
- Lu, L., Sun, X., Ma, J., Yang, D., Wu, H., Zhang, B., Zhang, J., & Han, B.
- Affiliations
- Chinese Academy of Sciences (CN)
- East China Normal University (CN)
- Corresponding author
- Sun, Xiaofu
- Han, Buxing
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-10-02
- Volume
- 57
- Issue
- 43
- Pages
- 14149-14153
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2889349896
- Cited by
- 310
- References
- 48
- Citations by year
- 2026: 16 · 2025: 34 · 2024: 46 · 2023: 34 · 2022: 51 · 2021: 52 · 2020: 48 · 2019: 28 · 2018: 1
- FWCI
- 7.45
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Science Foundation
- National Natural Science Foundation of China
- National Key Research and Development Program of China
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, methanol synthesis, palladium-copper bimetallic catalyst, Faradaic efficiency, grain boundaries
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