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Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction
Open accessAbstract
Metallic-phase MoS 2 (M-MoS 2) is metastable and does not exist in nature. Pure and stable M-MoS 2 has not been previously prepared by chemical synthesis, to the best of our knowledge. Here we report a hydrothermal process for synthesizing stable two-dimensional M-MoS 2 nanosheets in water. The metal–metal Raman stretching mode at 146 cm−1 in the M-MoS 2 structure, as predicted by theoretical calculations, is experimentally observed. The stability of the M-MoS 2 is associated with the adsorption of a monolayer of water molecules on both sides of the nanosheets, which reduce restacking and prevent aggregation in water. The obtained M-MoS 2 exhibits excellent stability in water and superior activity for the hydrogen evolution reaction, with a current density of 10 mA cm−2 at a low potential of −175 mV and a Tafel slope of 41 mV per decade.
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Cites
High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide
Zheng, J., Zhang, H., Dong, S., Liu, Y., Tai Nai, C., Suk Shin, H., Young Jeong, H., Liu, B., & Ping Loh, K. (2014) · Nature Communications · doi:10.1038/ncomms3995 · Cited by 787
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Fu, H. Q., Zhou, M., Liu, P. F., Liu, P., Yin, H., Sun, K. Z., Yang, H. G., Al-Mamun, M., Hu, P., Wang, H.-F., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c01094 · Cited by 508
Liu, Y., Jiang, S., Li, S., Zhou, L., Li, Z., Li, J., & Shao, M. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.01.094 · Cited by 508
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Prabhu, P., Jose, V., & Lee, J.-M. (2020) · Matter · doi:10.1016/j.matt.2020.01.001 · Cited by 460
Tan, C., Luo, Z., Chaturvedi, A., Cai, Y., Du, Y., Gong, Y., Huang, Y., Lai, Z., Zhang, X., Zheng, L., et al. (2018) · Advanced Materials · doi:10.1002/adma.201705509 · Cited by 455
Metadata
- Authors
- Geng, X., Sun, W., Wu, W., Chen, B., Al-Hilo, A., Benamara, M., Zhu, H., Watanabe, F., Cui, J., & Chen, T.-P.
- Venue
- Nature Communications
- Published
- 2016-02-10
- Volume
- 7
- Issue
- 1
- Pages
- 10672-10672
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2342787304
- Cited by
- 917
- References
- 1
- FWCI
- 26.64
- Type
- journal article
- Language
- en
- Open access
- gold
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- Geng, X., Sun, W., Wu, W., Chen, B., Al-Hilo, A., Benamara, M., Zhu, H., Watanabe, F., Cui, J., & Chen, T.-P. (2016). Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction. Nature Communications. https://doi.org/10.1038/ncomms10672
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