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Intermediate honeycomb ordering to trigger oxygen redox chemistry in layered battery electrode
Open accessAbstract
Sodium-ion batteries are attractive energy storage media owing to the abundance of sodium, but the low capacities of available cathode materials make them impractical. Sodium-excess metal oxides Na 2 MO 3 (M: transition metal) are appealing cathode materials that may realize large capacities through additional oxygen redox reaction. However, the general strategies for enhancing the capacity of Na 2 MO 3 are poorly established. Here using two polymorphs of Na 2 RuO 3, we demonstrate the critical role of honeycomb-type cation ordering in Na 2 MO 3. Ordered Na 2 RuO 3 with honeycomb-ordered [Na 1/3 Ru 2/3]O 2 slabs delivers a capacity of 180 mAh g−1 (1.3-electron reaction), whereas disordered Na 2 RuO 3 only delivers 135 mAh g−1 (1.0-electron reaction). We clarify that the large extra capacity of ordered Na 2 RuO 3 is enabled by a spontaneously ordered intermediate Na 1 RuO 3 phase with ilmenite O1 structure, which induces frontier orbital reorganization to trigger the oxygen redox reaction, unveiling a general requisite for the stable oxygen redox reaction in high-capacity Na 2 MO 3 cathodes.
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Metadata
- Authors
- Mortemard de Boisse, B., Liu, G., Ma, J., Nishimura, S.-I., Chung, S.-C., Kiuchi, H., Harada, Y., Kikkawa, J., Kobayashi, Y., Okubo, M., & Yamada, A.
- Venue
- Nature Communications
- Published
- 2016-04-18
- Volume
- 7
- Issue
- 1
- Pages
- 11397-11397
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2336325276
- Cited by
- 334
- References
- 33
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- gold
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