The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Metal-encapsulated organolead halide perovskite photocathode for solar-driven hydrogen evolution in water
Open accessAbstract
Lead-halide perovskites have triggered the latest breakthrough in photovoltaic technology. Despite the great promise shown by these materials, their instability towards water even in the presence of low amounts of moisture makes them, a priori, unsuitable for their direct use as light harvesters in aqueous solution for the production of hydrogen through water splitting. Here, we present a simple method that enables their use in photoelectrocatalytic hydrogen evolution while immersed in an aqueous solution. Field’s metal, a fusible InBiSn alloy, is used to efficiently protect the perovskite from water while simultaneously allowing the photogenerated electrons to reach a Pt hydrogen evolution catalyst. A record photocurrent density of −9.8 mA cm−2 at 0 V versus RHE with an onset potential as positive as 0.95±0.03 V versus RHE is obtained. The photoelectrodes show remarkable stability retaining more than 80% of their initial photocurrent for ∼1 h under continuous illumination.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Cited by
Han, N., Yang, K. R., Lu, Z., Li, Y., Xu, W., Gao, T., Cai, Z., Zhang, Y., Batista, V. S., Liu, W., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-03429-z · Cited by 766
Liu, Y., Zhang, Y., Zhao, K., Yang, Z., Feng, J., Zhang, X., Wang, K., Meng, L., Ye, H., Liu, M., et al. (2018) · Advanced Materials · doi:10.1002/adma.201707314 · Cited by 354
Fehr, A. M. K., Agrawal, A., Mandani, F., Conrad, C. L., Jiang, Q., Park, S. Y., Alley, O., Li, B., Sidhik, S., Metcalf, I., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-39290-y · Cited by 177
Guo, Z., & Lin, B. (2021) · Solar Energy · doi:10.1016/j.solener.2021.09.030 · Cited by 95
A Low-Cost and High-Efficiency Integrated Device toward Solar-Driven Water Splitting
Liang, J., Han, X., Qiu, Y., Fang, Q., Zhang, B., Wang, W., Zhang, J., Ajayan, P. M., & Lou, J. (2020) · ACS Nano · doi:10.1021/acsnano.9b09053 · Cited by 68
Metadata
- Authors
- Crespo-Quesada, M., Pazos-Outón, L. M., Warnan, J., Kuehnel, M. F., Friend, R. H., & Reisner, E.
- Venue
- Nature Communications
- Published
- 2016-09-06
- Volume
- 7
- Issue
- 1
- Pages
- 12555-12555
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2514738494
- Cited by
- 205
- References
- 2
- FWCI
- 4.92
- Type
- journal article
- Language
- en
- Open access
- gold
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- Crespo-Quesada, M., Pazos-Outón, L. M., Warnan, J., Kuehnel, M. F., Friend, R. H., & Reisner, E. (2016). Metal-encapsulated organolead halide perovskite photocathode for solar-driven hydrogen evolution in water. Nature Communications. https://doi.org/10.1038/ncomms12555
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