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Cited by 483

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Coherent coupling of molecular resonators with a microcavity mode

Open access
Shalabney, A., George, J., Hutchison, J., Pupillo, G., Genet, C., Ebbesen, T. W.·2015·Nature Communications

Abstract

The optical hybridization of the electronic states in strongly coupled molecule–cavity systems have revealed unique properties, such as lasing, room temperature polariton condensation and the modification of excited electronic landscapes involved in molecular isomerization. Here we show that molecular vibrational modes of the electronic ground state can also be coherently coupled with a microcavity mode at room temperature, given the low vibrational thermal occupation factors associated with molecular vibrations, and the collective coupling of a large ensemble of molecules immersed within the cavity-mode volume. This enables the enhancement of the collective Rabi-exchange rate with respect to the single-oscillator coupling strength. The possibility of inducing large shifts in the vibrational frequency of selected molecular bonds should have immediate consequences for chemistry.

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Crossref · 10.1038/ncomms6981

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Metadata

Authors
Shalabney, A., George, J., Hutchison, J., Pupillo, G., Genet, C., & Ebbesen, T. W.
Venue
Nature Communications
Published
2015-01-13
Volume
6
Issue
1
Pages
5981-5981
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2067597620
Cited by
483
References
3
FWCI
18.68
Type
journal article
Language
en
Open access
gold

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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