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Self-assembled three-dimensional and compressible interdigitated thin-film supercapacitors and batteries
Open accessAbstract
Traditional thin-film energy-storage devices consist of stacked layers of active films on two-dimensional substrates and do not exploit the third dimension. Fully three-dimensional thin-film devices would allow energy storage in bulk materials with arbitrary form factors and with mechanical properties unique to bulk materials such as compressibility. Here we show three-dimensional energy-storage devices based on layer-by-layer self-assembly of interdigitated thin films on the surface of an open-cell aerogel substrate. We demonstrate a reversibly compressible three-dimensional supercapacitor with carbon nanotube electrodes and a three-dimensional hybrid battery with a copper hexacyanoferrate ion intercalating cathode and a carbon nanotube anode. The three-dimensional supercapacitor shows stable operation over 400 cycles with a capacitance of 25 F g−1 and is fully functional even at compressions up to 75%. Our results demonstrate that layer-by-layer self-assembly inside aerogels is a rapid, precise and scalable route for building high-surface-area 3D thin-film devices.
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Citations
Cites
Chemistry of Aerogels and Their Applications
Pierre, A. C., & Pajonk, G. M. (2002) · Chemical Reviews · doi:10.1021/cr0101306 · Cited by 2,239
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Chen, Y., Zhang, L., Yang, Y., Pang, B., Xu, W., Duan, G., Jiang, S., & Zhang, K. (2021) · Advanced Materials · doi:10.1002/adma.202005569 · Cited by 721
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Benchmarking Cellulose Nanocrystals: From the Laboratory to Industrial Production
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Metadata
- Authors
- Nyström, G., Marais, A., Karabulut, E., Wågberg, L., Cui, Y., & Hamedi, M. M.
- Venue
- Nature Communications
- Published
- 2015-05-29
- Volume
- 6
- Issue
- 1
- Pages
- 7259-7259
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W946063174
- Cited by
- 280
- References
- 1
- FWCI
- 13.89
- Type
- journal article
- Language
- en
- Open access
- gold
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- Nyström, G., Marais, A., Karabulut, E., Wågberg, L., Cui, Y., & Hamedi, M. M. (2015). Self-assembled three-dimensional and compressible interdigitated thin-film supercapacitors and batteries. Nature Communications. https://doi.org/10.1038/ncomms8259
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.