The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Efficient photosynthesis of carbon monoxide from CO2 using perovskite photovoltaics
Open accessAbstract
Artificial photosynthesis, mimicking nature in its efforts to store solar energy, has received considerable attention from the research community. Most of these attempts target the production of H 2 as a fuel and our group recently demonstrated solar-to-hydrogen conversion at 12.3% efficiency. Here, in an effort to take this approach closer to real photosynthesis, which is based on the conversion of CO 2, we demonstrate the efficient reduction of CO 2 to carbon monoxide driven solely by simulated sunlight using water as the electron source. Employing series-connected perovskite photovoltaics and high-performance catalyst electrodes, we reach a solar-to-CO efficiency exceeding 6.5%, which represents a new benchmark in sunlight-driven CO 2 conversion. Considering hydrogen as a secondary product, an efficiency exceeding 7% is observed. Furthermore, this study represents one of the first demonstrations of extended, stable operation of perovskite photovoltaics, whose large open-circuit voltage is shown to be particularly suited for this process.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
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Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Self-citationElectroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
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Technical photosynthesis involving CO2 electrolysis and fermentation
Haas, T., Krause, R., Weber, R., Demler, M., & Schmid, G. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0005-1 · Cited by 649
Super-dry reforming of methane intensifies CO 2 utilization via Le Chatelier’s principle
Buelens, L. C., Galvita, V. V., Poelman, H., Detavernier, C., & Marin, G. B. (2016) · Science · doi:10.1126/science.aah7161 · Cited by 528
New-generation integrated devices based on dye-sensitized and perovskite solar cells
Yun, S., Qin, Y., Uhl, A. R., Vlachopoulos, N., Yin, M., Li, D., Han, X., & Hagfeldt, A. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03165c · Cited by 478
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
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Metadata
- Authors
- Schreier, M., Curvat, L., Giordano, F., Steier, L., Abate, A., Zakeeruddin, S. M., Luo, J., Mayer, M. T., & Grätzel, M.
- Venue
- Nature Communications
- Published
- 2015-06-11
- Volume
- 6
- Issue
- 1
- Pages
- 7326-7326
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W1836053286
- Cited by
- 348
- References
- 6
- FWCI
- 12.61
- Type
- journal article
- Language
- en
- Open access
- gold
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.