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A lead-halide perovskite molecular ferroelectric semiconductor
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Inorganic semiconductor ferroelectrics such as BiFeO 3 have shown great potential in photovoltaic and other applications. Currently, semiconducting properties and the corresponding application in optoelectronic devices of hybrid organo-plumbate or stannate are a hot topic of academic research; more and more of such hybrids have been synthesized. Structurally, these hybrids are suitable for exploration of ferroelectricity. Therefore, the design of molecular ferroelectric semiconductors based on these hybrids provides a possibility to obtain new or high-performance semiconductor ferroelectrics. Here we investigated Pb-layered perovskites, and found the layer perovskite (benzylammonium)2 PbCl 4 is ferroelectric with semiconducting behaviours. It has a larger ferroelectric spontaneous polarization Ps=13 μC cm−2 and a higher Curie temperature Tc=438 K with a band gap of 3.65 eV. This finding throws light on the new properties of the hybrid organo-plumbate or stannate compounds and provides a new way to develop new semiconductor ferroelectrics.
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Metadata
- Authors
- Liao, W.-Q., Zhang, Y., Hu, C.-L., Mao, J.-G., Ye, H.-Y., Li, P.-F., Huang, S. D., & Xiong, R.-G.
- Venue
- Nature Communications
- Published
- 2015-05-29
- Volume
- 6
- Issue
- 1
- Pages
- 7338-7338
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2230715130
- Cited by
- 710
- References
- 53
- FWCI
- 28.87
- Type
- journal article
- Language
- en
- Open access
- gold
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