The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization
Open accessAbstract
Single crystals of methylammonium lead trihalide perovskites (MAPbX 3; MA=CH 3 NH 3+, X=Br− or I−) have shown remarkably low trap density and charge transport properties; however, growth of such high-quality semiconductors is a time-consuming process. Here we present a rapid crystal growth process to obtain MAPbX 3 single crystals, an order of magnitude faster than previous reports. The process is based on our observation of the substantial decrease of MAPbX 3 solubility, in certain solvents, at elevated temperatures. The crystals can be both size- and shape-controlled by manipulating the different crystallization parameters. Despite the rapidity of the method, the grown crystals exhibit transport properties and trap densities comparable to the highest quality MAPbX 3 reported to date. The phenomenon of inverse or retrograde solubility and its correlated inverse temperature crystallization strategy present a major step forward for advancing the field on perovskite crystallization.
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Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3
Xing, G., Mathews, N., Sun, S., Lim, S. S., Lam, Y. M., Grätzel, M., Mhaisalkar, S., & Sum, T. C. (2013) · Science · doi:10.1126/science.1243167 · Cited by 6,909
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
Dong, Q., Fang, Y., Shao, Y., Mulligan, P., Qiu, J., Cao, L., & Huang, J. (2015) · Science · doi:10.1126/science.aaa5760 · Cited by 5,643
Stoumpos, C. C., Malliakas, C. D., & Kanatzidis, M. G. (2013) · Inorganic Chemistry · doi:10.1021/ic401215x · Cited by 5,416
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
Shi, D., Adinolfi, V., Comin, R., Yuan, M., Alarousu, E., Buin, A., Chen, Y., Hoogland, S., Rothenberger, A., Katsiev, K., et al. (2015) · Science · doi:10.1126/science.aaa2725 · Cited by 5,139
Self-citationNoh, J. H., Im, S. H., Heo, J. H., Mandal, T. N., & Seok, S. I. (2013) · Nano Letters · doi:10.1021/nl400349b · Cited by 4,829
Bright light-emitting diodes based on organometal halide perovskite
Tan, Z.-K., Moghaddam, R. S., Lai, M. L., Docampo, P., Higler, R., Deschler, F., Price, M., Sadhanala, A., Pazos, L. M., Credgington, D., et al. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.149 · Cited by 4,450
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
Nie, W., Tsai, H., Asadpour, R., Blancon, J.-C., Neukirch, A. J., Gupta, G., Crochet, J. J., Chhowalla, M., Tretiak, S., Alam, M. A., et al. (2015) · Science · doi:10.1126/science.aaa0472 · Cited by 3,295
Low-temperature solution-processed wavelength-tunable perovskites for lasing
Xing, G., Mathews, N., Lim, S. S., Yantara, N., Liu, X., Sabba, D., Grätzel, M., Mhaisalkar, S., & Sum, T. C. (2014) · Nature Materials · doi:10.1038/nmat3911 · Cited by 3,219
Cited by
Brenner, T. M., Egger, D. A., Kronik, L., Hodes, G., & Cahen, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.7 · Cited by 1,557
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Planar-integrated single-crystalline perovskite photodetectors
Saidaminov, M. I., Adinolfi, V., Comin, R., Abdelhady, A. L., Peng, W., Dursun, I., Yuan, M., Hoogland, S., Sargent, E. H., & Bakr, O. M. (2015) · Nature Communications · doi:10.1038/ncomms9724 · Cited by 734
Self-citationSelf-Driving Laboratories for Chemistry and Materials Science
Tom, G., Schmid, S. P., Baird, S. G., Cao, Y., Darvish, K., Hao, H., Lo, S., Pablo-García, S., Rajaonson, E. M., Skreta, M., et al. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.4c00055 · Cited by 707
Metal-Doped Lead Halide Perovskites: Synthesis, Properties, and Optoelectronic Applications
Zhou, Y., Chen, J., Bakr, O. M., & Sun, H.-T. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b02989 · Cited by 650
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Metadata
- Authors
- Saidaminov, M. I., Abdelhady, A. L., Murali, B., Alarousu, E., Burlakov, V. M., Peng, W., Dursun, I., Wang, L., He, Y., Maculan, G., Goriely, A., Wu, T., Mohammed, O. F., & Bakr, O. M.
- Venue
- Nature Communications
- Published
- 2015-07-06
- Volume
- 6
- Issue
- 1
- Pages
- 7586-7586
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W773815729
- Cited by
- 1,922
- References
- 29
- FWCI
- 82.76
- Type
- journal article
- Language
- en
- Open access
- gold
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- Saidaminov, M. I., Abdelhady, A. L., Murali, B., Alarousu, E., Burlakov, V. M., Peng, W., Dursun, I., Wang, L., He, Y., Maculan, G., Goriely, A., Wu, T., Mohammed, O. F., & Bakr, O. M. (2015). High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization. Nature Communications. https://doi.org/10.1038/ncomms8586
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