The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization
Open accessAbstract
Single crystals of methylammonium lead trihalide perovskites (MAPbX 3; MA=CH 3 NH 3+, X=Br− or I−) have shown remarkably low trap density and charge transport properties; however, growth of such high-quality semiconductors is a time-consuming process. Here we present a rapid crystal growth process to obtain MAPbX 3 single crystals, an order of magnitude faster than previous reports. The process is based on our observation of the substantial decrease of MAPbX 3 solubility, in certain solvents, at elevated temperatures. The crystals can be both size- and shape-controlled by manipulating the different crystallization parameters. Despite the rapidity of the method, the grown crystals exhibit transport properties and trap densities comparable to the highest quality MAPbX 3 reported to date. The phenomenon of inverse or retrograde solubility and its correlated inverse temperature crystallization strategy present a major step forward for advancing the field on perovskite crystallization.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3
Xing, G., Mathews, N., Sun, S., Lim, S. S., Lam, Y. M., Grätzel, M., Mhaisalkar, S., & Sum, T. C. (2013) · Science · doi:10.1126/science.1243167 · Cited by 6,909
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
Dong, Q., Fang, Y., Shao, Y., Mulligan, P., Qiu, J., Cao, L., & Huang, J. (2015) · Science · doi:10.1126/science.aaa5760 · Cited by 5,643
Stoumpos, C. C., Malliakas, C. D., & Kanatzidis, M. G. (2013) · Inorganic Chemistry · doi:10.1021/ic401215x · Cited by 5,416
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
Shi, D., Adinolfi, V., Comin, R., Yuan, M., Alarousu, E., Buin, A., Chen, Y., Hoogland, S., Rothenberger, A., Katsiev, K., et al. (2015) · Science · doi:10.1126/science.aaa2725 · Cited by 5,139
Self-citationNoh, J. H., Im, S. H., Heo, J. H., Mandal, T. N., & Seok, S. I. (2013) · Nano Letters · doi:10.1021/nl400349b · Cited by 4,829
Bright light-emitting diodes based on organometal halide perovskite
Tan, Z.-K., Moghaddam, R. S., Lai, M. L., Docampo, P., Higler, R., Deschler, F., Price, M., Sadhanala, A., Pazos, L. M., Credgington, D., et al. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.149 · Cited by 4,450
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
Nie, W., Tsai, H., Asadpour, R., Blancon, J.-C., Neukirch, A. J., Gupta, G., Crochet, J. J., Chhowalla, M., Tretiak, S., Alam, M. A., et al. (2015) · Science · doi:10.1126/science.aaa0472 · Cited by 3,295
Low-temperature solution-processed wavelength-tunable perovskites for lasing
Xing, G., Mathews, N., Lim, S. S., Yantara, N., Liu, X., Sabba, D., Grätzel, M., Mhaisalkar, S., & Sum, T. C. (2014) · Nature Materials · doi:10.1038/nmat3911 · Cited by 3,219
A hole-conductor–free, fully printable mesoscopic perovskite solar cell with high stability
Mei, A., Li, X., Liu, L., Ku, Z., Liu, T., Rong, Y., Xu, M., Hu, M., Chen, J., Yang, Y., et al. (2014) · Science · doi:10.1126/science.1254763 · Cited by 3,043
Solution-processed hybrid perovskite photodetectors with high detectivity
Dou, L., Yang, Y., You, J., Hong, Z., Chang, W.-H., Li, G., & Yang, Y. (2014) · Nature Communications · doi:10.1038/ncomms6404 · Cited by 2,765
Baikie, T., Fang, Y., Kadro, J. M., Schreyer, M., Wei, F., Mhaisalkar, S. G., Graetzel, M., & White, T. J. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta10518k · Cited by 2,534
Docampo, P., Ball, J. M., Darwich, M., Eperon, G. E., & Snaith, H. J. (2013) · Nature Communications · doi:10.1038/ncomms3761 · Cited by 1,703
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy
Poglitsch, A., & Weber, D. (1987) · The Journal of Chemical Physics · doi:10.1063/1.453467 · Cited by 1,625
Christians, J. A., Fung, R. C. M., & Kamat, P. V. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411014k · Cited by 1,313
Steric engineering of metal-halide perovskites with tunable optical band gaps
Filip, M. R., Eperon, G. E., Snaith, H. J., & Giustino, F. (2014) · Nature Communications · doi:10.1038/ncomms6757 · Cited by 1,081
Wu, Y., Islam, A., Yang, X., Qin, C., Liu, J., Zhang, K., Peng, W., & Han, L. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01624f · Cited by 887
Self-citationMechanism of carrier accumulation in perovskite thin-absorber solar cells
Kim, H.-S., Mora-Sero, I., Gonzalez-Pedro, V., Fabregat-Santiago, F., Juarez-Perez, E. J., Park, N.-G., & Bisquert, J. (2013) · Nature Communications · doi:10.1038/ncomms3242 · Cited by 844
Tuning the Light Emission Properties by Band Gap Engineering in Hybrid Lead Halide Perovskite
D’Innocenzo, V., Srimath Kandada, A. R., De Bastiani, M., Gandini, M., & Petrozza, A. (2014) · Journal of the American Chemical Society · doi:10.1021/ja511198f · Cited by 623
Bulk crystal growth of hybrid perovskite material CH3NH3PbI3
Dang, Y., Liu, Y., Sun, Y., Yuan, D., Liu, X., Lu, W., Liu, G., Xia, H., & Tao, X. (2015) · CrystEngComm · doi:10.1039/c4ce02106a · Cited by 590
Compact Layer Free Perovskite Solar Cells with 13.5% Efficiency
Liu, D., Yang, J., & Kelly, T. L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja508758k · Cited by 460
Dual nature of the excited state in organic–inorganic lead halide perovskites
Stamplecoskie, K. G., Manser, J. S., & Kamat, P. V. (2015) · Energy & Environmental Science · doi:10.1039/c4ee02988g · Cited by 432
Densities of aqueous solutions of 18 inorganic substances
Sohnel, O., Novotny, P., & Solc, Z. (1984) · Journal of Chemical & Engineering Data · doi:10.1021/je00038a004 · Cited by 368
Choi, J. J., Yang, X., Norman, Z. M., Billinge, S. J. L., & Owen, J. S. (2014) · Nano Letters · doi:10.1021/nl403514x · Cited by 298
Wakamiya, A., Endo, M., Sasamori, T., Tokitoh, N., Ogomi, Y., Hayase, S., & Murata, Y. (2014) · Chemistry Letters · doi:10.1246/cl.140074 · Cited by 293
Chen, Y.-S., Manser, J. S., & Kamat, P. V. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511739y · Cited by 281
THE CRYSTAL STRUCTURE OF LEAD(II) IODIDE-DIMETHYLSULPHOXIDE(1/2), PbI2(dmso)2
Miyamae, H., Numahata, Y., & Nagata, M. (1980) · Chemistry Letters · doi:10.1246/cl.1980.663 · Cited by 96
Mohammed, O. F., Xiao, D., Batista, V. S., & Nibbering, E. T. J. (2014) · The Journal of Physical Chemistry A · doi:10.1021/jp501612f · Cited by 73
Self-citation
Cited by
Brenner, T. M., Egger, D. A., Kronik, L., Hodes, G., & Cahen, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.7 · Cited by 1,557
Understanding the physical properties of hybrid perovskites for photovoltaic applications
Huang, J., Yuan, Y., Shao, Y., & Yan, Y. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.42 · Cited by 1,252
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Metal Halide Perovskites for X-ray Imaging Scintillators and Detectors
Zhou, Y., Chen, J., Bakr, O. M., & Mohammed, O. F. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.0c02430 · Cited by 891
Self-citationPlanar-integrated single-crystalline perovskite photodetectors
Saidaminov, M. I., Adinolfi, V., Comin, R., Abdelhady, A. L., Peng, W., Dursun, I., Yuan, M., Hoogland, S., Sargent, E. H., & Bakr, O. M. (2015) · Nature Communications · doi:10.1038/ncomms9724 · Cited by 734
Self-citation
Metadata
- Authors
- Saidaminov, M. I., Abdelhady, A. L., Murali, B., Alarousu, E., Burlakov, V. M., Peng, W., Dursun, I., Wang, L., He, Y., Maculan, G., Goriely, A., Wu, T., Mohammed, O. F., & Bakr, O. M.
- Venue
- Nature Communications
- Published
- 2015-07-06
- Volume
- 6
- Issue
- 1
- Pages
- 7586-7586
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W773815729
- Cited by
- 1,922
- References
- 29
- FWCI
- 82.76
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
