Cited by 704Perovskite Materials and Applications2D Materials and ApplicationsOrganic Electronics and Photovoltaics

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Hot-carrier cooling and photoinduced refractive index changes in organic–inorganic lead halide perovskites

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Price, Michael B., Butkus, Justinas, Jellicoe, Tom C., Sadhanala, Aditya, Briane, Anouk, Halpert, Jonathan E., Broch, Katharina, Hodgkiss, Justin M., Friend, Richard H., Deschler, Felix·2015·Nature Communications

DOI 10.1038/ncomms9420PMC PMC4598728

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Abstract

Metal-halide perovskites are at the frontier of optoelectronic research due to solution processability and excellent semiconductor properties. Here we use transient absorption spectroscopy to study hot-carrier distributions in CH 3 NH 3 PbI 3 and quantify key semiconductor parameters. Above bandgap, non-resonant excitation creates quasi-thermalized carrier distributions within 100 fs. During carrier cooling, a sub-bandgap transient absorption signal arises at ∼1.6 eV, which is explained by the interplay of bandgap renormalization and hot-carrier distributions. At higher excitation densities, a ‘phonon bottleneck’ substantially slows carrier cooling. This effect indicates a low contribution from inelastic carrier-impurity or phonon–impurity scattering in these polycrystalline materials, which supports high charge-carrier mobilities. Photoinduced reflectivity changes distort the shape of transient absorption spectra and must be included to extract physical constants. Using a simple band-filling model that accounts for these changes, we determine a small effective mass of m r =0.14 m o , which agrees with band structure calculations and high photovoltaic performance.

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Hecht, E. Optics Addison Wesley (1987) .

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Hintermayr, V. A., Polavarapu, L., Urban, A. S., & Feldmann, J. (2018) · ACS Nano · doi:10.1021/acsnano.8b05029 · Cited by 124
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Dai, L., Deng, Z., Auras, F., Goodwin, H., Zhang, Z., Walmsley, J. C., Bristowe, P. D., Deschler, F., & Greenham, N. C. (2021) · Nature Photonics · doi:10.1038/s41566-021-00847-2 · Cited by 122
Self-citation
Intrinsic Charge Transport across Phase Transitions in Hybrid Organo‐Inorganic Perovskites
Yi, H. T., Wu, X., Zhu, X., & Podzorov, V. (2016) · Advanced Materials · doi:10.1002/adma.201600011 · Cited by 121
Formation, location and beneficial role of PbI 2 in lead halide perovskite solar cells
Du, T., Burgess, C. H., Kim, J., Zhang, J., Durrant, J. R., & McLachlan, M. A. (2017) · Sustainable Energy & Fuels · doi:10.1039/c6se00029k · Cited by 121
Acoustic phonon lifetimes limit thermal transport in methylammonium lead iodide
Gold‐Parker, A., Gehring, P. M., Skelton, J. M., Smith, I. C., Parshall, D., Frost, J. M., Karunadasa, H. I., Walsh, A., & Toney, M. F. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1812227115 · Cited by 121
Photophysics of Hybrid Lead Halide Perovskites: The Role of Microstructure
Srimath Kandada, A. R., & Petrozza, A. (2016) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00464 · Cited by 120
Impact of Small Phonon Energies on the Charge-Carrier Lifetimes in Metal-Halide Perovskites
Kirchartz, T., Markvart, T., Rau, U., & Egger, D. A. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b03414 · Cited by 121
Visualizing excitations at buried heterojunctions in organic semiconductor blends
Jakowetz, A. C., Böhm, M. L., Sadhanala, A., Huettner, S., Rao, A., & Friend, R. H. (2017) · Nature Materials · doi:10.1038/nmat4865 · Cited by 114
Self-citation
Carriers, Quasi-particles, and Collective Excitations in Halide Perovskites
Fu, J., Ramesh, S., Lim, J. W. M., & Sum, T. C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00843 · Cited by 116
Terahertz Emission from Hybrid Perovskites Driven by Ultrafast Charge Separation and Strong Electron–Phonon Coupling
Güzeltürk, B., Belisle, R. A., Smith, M. D., Brüning, K., Prasanna, R., Yuan, Y., Gopalan, V., Tassone, C. J., Karunadasa, H. I., McGehee, M. D., et al. (2018) · Advanced Materials · doi:10.1002/adma.201704737 · Cited by 113
Inter-phase charge and energy transfer in Ruddlesden–Popper 2D perovskites: critical role of the spacing cations
Zheng, K., Chen, Y., Sun, Y., Chen, J., Chábera, P., Schaller, R. D., Al-Marri, M. J., Canton, S. E., Liang, Z., & Pullerits, T. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta01518j · Cited by 112
Effect of Zinc‐Doping on the Reduction of the Hot‐Carrier Cooling Rate in Halide Perovskites
Wei, Q., Yin, J. L., Bakr, O. M., Wang, Z., Wang, C., Mohammed, O. F., Li, M., & Xing, G. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202100099 · Cited by 109
Dynamic Screening and Slow Cooling of Hot Carriers in Lead Halide Perovskites
Joshi, P. P., Maehrlein, S. F., & Zhu, X. (2019) · Advanced Materials · doi:10.1002/adma.201803054 · Cited by 108
Impact of nonparabolic electronic band structure on the optical and transport properties of photovoltaic materials
Whalley, L. D., Frost, J. M., Morgan, B. J., & Walsh, A. (2019) · Physical review. B./Physical review. B · doi:10.1103/physrevb.99.085207 · Cited by 106
Free Carrier Emergence and Onset of Electron–Phonon Coupling in Methylammonium Lead Halide Perovskite Films
Ghosh, T., Aharon, S., Etgar, L., & Ruhman, S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b09508 · Cited by 105
There is plenty of room at the top: generation of hot charge carriers and their applications in perovskite and other semiconductor-based optoelectronic devices
Ahmed, I., Shi, L., Pasanen, H. P., Vivo, P., Maity, P., Hatamvand, M., & Zhan, Y. (2021) · Light Science & Applications · doi:10.1038/s41377-021-00609-3 · Cited by 106
Spatially segregated free-carrier and exciton populations in individual lead halide perovskite grains
Nah, S., Spokoyny, B., Stoumpos, C. C., Soe, C. M. M., Kanatzidis, M. G., & Harel, E. (2017) · Nature Photonics · doi:10.1038/nphoton.2017.36 · Cited by 103
High Excitation Intensity Opens a New Trapping Channel in Organic–Inorganic Hybrid Perovskite Nanoparticles
Zheng, K., Žídek, K., Abdellah, M. A., Chen, J., Chábera, P., Zhang, W., Al-Marri, M. J., & Pullerits, T. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00352 · Cited by 101
Carrier Lifetimes and Polaronic Mass Enhancement in the Hybrid Halide Perovskite CH 3 NH 3 PbI 3 from Multiphonon Fröhlich Coupling
Schlipf, M., Poncé, S., & Giustino, F. (2018) · Physical Review Letters · doi:10.1103/physrevlett.121.086402 · Cited by 104
From Large to Small Polarons in Lead, Tin, and Mixed Lead–Tin Halide Perovskites
Mahata, A., Meggiolaro, D., & Angelis, F. D. (2019) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.9b00422 · Cited by 101
Two-dimensional electronic spectroscopy reveals liquid-like lineshape dynamics in CsPbI3 perovskite nanocrystals
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Thermodynamic Stabilization of Mixed-Halide Perovskites against Phase Segregation
Hutter, E. M., Muscarella, L. A., Wittmann, F., Versluis, J., McGovern, L., Bakker, H. J., Woo, Y.-W., Jung, Y., Walsh, A., & Ehrler, B. (2020) · Cell Reports Physical Science · doi:10.1016/j.xcrp.2020.100120 · Cited by 96
Metal replacement in perovskite solar cell materials: chemical bonding effects and optoelectronic properties
Pazoki, M., & Edvinsson, T. (2018) · Sustainable Energy & Fuels · doi:10.1039/c8se00143j · Cited by 98
Electron transport and visible light absorption in a plasmonic photocatalyst based on strontium niobate
Wan, D., Zhao, Y., Cai, Y. Q., Asmara, T. C., Huang, Z., Chen, J. Q., Hong, J., Yin, S., Nelson, C. T., Motapothula, M., et al. (2017) · Nature Communications · doi:10.1038/ncomms15070 · Cited by 97
Protecting hot carriers by tuning hybrid perovskite structures with alkali cations
Wang, T., Jin, L., Hidalgo, J., Chu, W., Snaider, J. M., Deng, S., Zhu, T., Lai, B. C. H., Prezhdo, O. V., Correa‐Baena, J., et al. (2020) · Science Advances · doi:10.1126/sciadv.abb1336 · Cited by 94
Room-Temperature Coherent Optical Phonon in 2D Electronic Spectra of CH3NH3PbI3 Perovskite as a Possible Cooling Bottleneck
Monahan, D. M., Guo, L., Lin, J. H., Dou, L., Yang, P., & Fleming, G. R. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01357 · Cited by 93
Multiple exciton generation in quantum dot‐based solar cells
Goodwin, H., Jellicoe, T. C., Davis, N. J. L. K., & Böhm, M. L. (2017) · Nanophotonics · doi:10.1515/nanoph-2017-0034 · Cited by 96
Self-citation
Low electron-polar optical phonon scattering as a fundamental aspect of carrier mobility in methylammonium lead halide CH 3 NH 3 PbI 3 perovskites
Filippetti, A., Mattoni, A., Caddeo, C., Saba, M. I., & Delugas, P. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp01402j · Cited by 91
Why are Hot Holes Easier to Extract than Hot Electrons from Methylammonium Lead Iodide Perovskite?
Dursun, İ., Maity, P., Yin, J. L., Türedi, B., Zhumekenov, A. A., Lee, K. J., Mohammed, O. F., & Bakr, O. M. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201900084 · Cited by 93
Manipulation of hot carrier cooling dynamics in two-dimensional Dion–Jacobson hybrid perovskites via Rashba band splitting
Yin, J. L., Naphade, R. A., Maity, P., Gutiérrez‐Arzaluz, L., Almalawi, D. R., Roqan, I. S., Brédas, J., Bakr, O. M., & Mohammed, O. F. (2021) · Nature Communications · doi:10.1038/s41467-021-24258-7 · Cited by 103

Authors: Price, M. B., Butkus, J., Jellicoe, T. C., Sadhanala, A., Briane, A., Halpert, J. E., Broch, K., Hodgkiss, J. M., Friend, R. H., & Deschler, F.
Affiliations: University of Cambridge (GB)
Victoria University of Wellington (NZ)
Corresponding author: Deschler, Felix
ORCID: Price, Michael B.
Jellicoe, Tom C.
Sadhanala, Aditya
Halpert, Jonathan E.
Broch, Katharina
Hodgkiss, Justin M.
Friend, Richard H.
Deschler, Felix
Venue: Nature Communications
Publisher: Springer Science and Business Media LLC
Published: 2015-09-25
Volume: 6
Issue: 1
Pages: 8420-8420
ISSN: 2041-1723 (ISSN-L)
DOI: 10.1038/ncomms9420
PMC: PMC4598728
OpenAlex: W2233449626
Cited by: 704
References: 42
Citations by year: 2026: 58 · 2025: 49 · 2024: 69 · 2023: 84 · 2022: 59 · 2021: 66 · 2020: 75 · 2019: 74 · 2018: 65 · 2017: 61 · 2016: 40 · 2015: 4
FWCI: 27.28
Type: journal article
Language: en
Open access: gold
doi.org
Licence: cc-by
creativecommons.org/licenses/by/4.0 (tdm)
creativecommons.org/licenses/by/4.0 (vor)
Locations: Nature Communications (publishedVersion, cc-by)
Europe PMC (PubMed Central) (publishedVersion, cc-by)
PubMed Central (publishedVersion, cc-by)
PubMed (publishedVersion)
Rare & Special e-Zone (The Hong Kong University of Science and Technology) (submittedVersion)
RePEc: Research Papers in Economics (submittedVersion)
Apollo (University of Cambridge) (submittedVersion, cc-by)
Funders: Deutsche Forschungsgemeinschaft
Cambridge Commonwealth Trust
Engineering and Physical Sciences Research Council (EP/M005143/1, EP/G060738/1)
Marsden Fund
Topics: Physical Sciences › Engineering › Electrical and Electronic Engineering › Perovskite Materials and Applications
Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
Keywords: hot carrier cooling, organic-inorganic lead halide perovskites, methylammonium lead iodide, photoinduced refractive index change, transient absorption spectroscopy, band gap renormalization, phonon bottleneck, effective mass, carrier mobility, polycrystalline perovskite

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Hot-carrier cooling and photoinduced refractive index changes in organic–inorganic lead halide perovskites

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