The DOI matches its Crossref record; 67 of the 67 references it cites were found in a registry or an index.
Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2
Open accessAbstract
Direct electrochemical reduction of CO 2 to fuels and chemicals using renewable electricity has attracted significant attention partly due to the fundamental challenges related to reactivity and selectivity, and partly due to its importance for industrial CO 2-consuming gas diffusion cathodes. Here, we present advances in the understanding of trends in the CO 2 to CO electrocatalysis of metal- and nitrogen-doped porous carbons containing catalytically active M–N x moieties (M = Mn, Fe, Co, Ni, Cu). We investigate their intrinsic catalytic reactivity, CO turnover frequencies, CO faradaic efficiencies and demonstrate that Fe–N–C and especially Ni–N–C catalysts rival Au- and Ag-based catalysts. We model the catalytically active M–N x moieties using density functional theory and correlate the theoretical binding energies with the experiments to give reactivity-selectivity descriptors. This gives an atomic-scale mechanistic understanding of potential-dependent CO and hydrocarbon selectivity from the M–N x moieties and it provides predictive guidelines for the rational design of selective carbon-based CO 2 reduction catalysts.
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Ross, M. B., De Luna, P., Li, Y., Dinh, C.-T., Kim, D., Yang, P., & Sargent, E. H. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0306-7 · Cited by 1,302
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Domino electroreduction of CO2 to methanol on a molecular catalyst
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Metadata
- Authors
- Ju, W., Bagger, A., Hao, G.-P., Varela, A. S., Sinev, I., Bon, V., Roldan Cuenya, B., Kaskel, S., Rossmeisl, J., & Strasser, P.
- Venue
- Nature Communications
- Published
- 2017-10-16
- Volume
- 8
- Issue
- 1
- Pages
- 944-944
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2761329828
- Cited by
- 1,203
- References
- 67
- FWCI
- 26.54
- Type
- journal article
- Language
- en
- Open access
- gold
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- Ju, W., Bagger, A., Hao, G.-P., Varela, A. S., Sinev, I., Bon, V., Roldan Cuenya, B., Kaskel, S., Rossmeisl, J., & Strasser, P. (2017). Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2. Nature Communications. https://doi.org/10.1038/s41467-017-01035-z
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