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Cited by 329

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In-situ cross-linking strategy for efficient and operationally stable methylammoniun lead iodide solar cells

Open access
Li, Xiaodong, Zhang, Wenxiao, Wang, Ying-Chiao, Zhang, Wenjun, Wang, Hai-Qiao, Fang, Junfeng·2018·Nature Communications

Abstract

Long-term operational stability is the foremost issue delaying the commercialization of perovskite solar cells (PSCs). Here we demonstrate an in-situ cross-linking strategy for operationally stable inverted MAPbI 3 PSCs through the incorporation of a cross-linkable organic small molecule additive trimethylolpropane triacrylate (TMTA) into perovskite films. TMTA can chemically anchor to grain boundaries and then in-situ cross-link to a robust continuous network polymer after thermal treatment, thus enhancing the thermal, water-resisting and light-resisting properties of organic/perovskite films. As a result, the cross-linked PSCs exhibit 590-fold improvement in operational stability, retaining nearly 80% of their initial efficiency after continuous power output for 400 h at maximum power point under full-sun AM 1.5 G illumination of Xenon lamp without any UV-filter. In addition, under moisture or thermal (85 °C) conditions, cross-linked TMTA-based PSCs also show excellent stability with over 90% of their initial or post burn-in efficiency after aging for over 1000 h.

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Metadata

Authors
Li, X., Zhang, W., Wang, Y.-C., Zhang, W., Wang, H.-Q., & Fang, J.
Venue
Nature Communications
Published
2018-09-18
Volume
9
Issue
1
Pages
3806-3806
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2890564463
Cited by
329
References
1
FWCI
13.64
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: In-situ cross-linking strategy for efficient and operationally stable methylammoniun lead iodide solar cells. https://app.cochat.ai/papers/10.1038/s41467-018-06204-2
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Li, X., Zhang, W., Wang, Y.-C., Zhang, W., Wang, H.-Q., & Fang, J. (2018). In-situ cross-linking strategy for efficient and operationally stable methylammoniun lead iodide solar cells. Nature Communications. https://doi.org/10.1038/s41467-018-06204-2

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