The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring
Open accessAbstract
Single-site catalysts feature high catalytic activity but their facile construction and durable utilization are highly challenging. Herein, we report a simple impregnation-adsorption method to construct platinum single-site catalysts by synergic micropore trapping and nitrogen anchoring on hierarchical nitrogen-doped carbon nanocages. The optimal catalyst exhibits a record-high electrocatalytic hydrogen evolution performance with low overpotential, high mass activity and long stability, much superior to the platinum-based catalysts to date. Theoretical simulations and experiments reveal that the micropores with edge-nitrogen-dopants favor the formation of isolated platinum atoms by the micropore trapping and nitrogen anchoring of [PtCl 6]2-, followed by the spontaneous dechlorination. The platinum-nitrogen bonds are more stable than the platinum-carbon ones in the presence of adsorbed hydrogen atoms, leading to the superior hydrogen evolution stability of platinum single-atoms on nitrogen-doped carbon. This method has been successfully applied to construct the single-site catalysts of other precious metals such as palladium, gold and iridium.
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Cites
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., Xiao, B., Li, R., Sham, T.-K., Liu, L.-M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13638 · Cited by 2,072
Fei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
Kibsgaard, J., Jaramillo, T. F., & Besenbacher, F. (2014) · Nature Chemistry · doi:10.1038/nchem.1853 · Cited by 839
Ma, Y.-Y., Wu, C.-X., Feng, X.-J., Tan, H.-Q., Yan, L.-K., Liu, Y., Kang, Z.-H., Wang, E.-B., & Li, Y.-G. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03768b · Cited by 781
High performance platinum single atom electrocatalyst for oxygen reduction reaction
Liu, J., Jiao, M., Lu, L., Barkholtz, H. M., Li, Y., Wang, Y., Jiang, L., Wu, Z., Liu, D.-J., Zhuang, L., et al. (2017) · Nature Communications · doi:10.1038/ncomms15938 · Cited by 772
Self-citation
Cited by
Single atom electrocatalysts supported on graphene or graphene-like carbons
Fei, H., Dong, J., Chen, D., Hu, T., Duan, X., Shakir, I., Huang, Y., & Duan, X. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00422j · Cited by 673
Feng, G., Ning, F., Song, J., Shang, H., Zhang, K., Ding, Z., Gao, P., Chu, W., & Xia, D. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c07643 · Cited by 560
He, H., Zhang, R., Zhang, P., Wang, P., Chen, N., Qian, B., Zhang, L., Yu, J., & Dai, B. (2023) · Advanced Science · doi:10.1002/advs.202205557 · Cited by 432
Self-citationLiu, M., Wang, L., Zhao, K., Shi, S., Shao, Q., Zhang, L., Sun, X., Zhao, Y., & Zhang, J. (2019) · Energy & Environmental Science · doi:10.1039/c9ee01722d · Cited by 429
Jiang, K., Luo, M., Liu, Z., Peng, M., Chen, D., Lu, Y.-R., Chan, T.-S., de Groot, F. M. F., & Tan, Y. (2021) · Nature Communications · doi:10.1038/s41467-021-21956-0 · Cited by 411
Metadata
- Authors
- Zhang, Z., Chen, Y., Zhou, L., Chen, C., Han, Z., Zhang, B., Wu, Q., Yang, L., Du, L., Bu, Y., Wang, P., Wang, X., Yang, H., & Hu, Z.
- Venue
- Nature Communications
- Published
- 2019-04-10
- Volume
- 10
- Issue
- 1
- Pages
- 1657-1657
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2940165352
- Cited by
- 351
- References
- 5
- FWCI
- 9.53
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhang, Z., Chen, Y., Zhou, L., Chen, C., Han, Z., Zhang, B., Wu, Q., Yang, L., Du, L., Bu, Y., Wang, P., Wang, X., Yang, H., & Hu, Z. (2019). The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring. Nature Communications. https://doi.org/10.1038/s41467-019-09596-x
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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