The DOI matches its Crossref record; 60 of the 60 references it cites were found in a registry or an index.
Quantifying the factors limiting rate performance in battery electrodes
Open accessAbstract
One weakness of batteries is the rapid falloff in charge-storage capacity with increasing charge/discharge rate. Rate performance is related to the timescales associated with charge/ionic motion in both electrode and electrolyte. However, no general fittable model exists to link capacity-rate data to electrode/electrolyte properties. Here we demonstrate an equation which can fit capacity versus rate data, outputting three parameters which fully describe rate performance. Most important is the characteristic time associated with charge/discharge which can be linked by a second equation to physical electrode/electrolyte parameters via various rate-limiting processes. We fit these equations to ~200 data sets, deriving parameters such as diffusion coefficients or electrolyte conductivities. It is possible to show which rate-limiting processes are dominant in a given situation, facilitating rational design and cell optimisation. In addition, this model predicts the upper speed limit for lithium/sodium ion batteries, yielding a value that is consistent with the fastest electrodes in the literature.
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Cites
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Cited by
Lu, X., Bertei, A., Finegan, D. P., Tan, C., Daemi, S. R., Weaving, J. S., O’Regan, K. B., Heenan, T. M. M., Hinds, G., Kendrick, E., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-15811-x · Cited by 513
High areal capacity battery electrodes enabled by segregated nanotube networks
Park, S.-H., King, P. J., Tian, R., Boland, C. S., Coelho, J., Zhang, C., McBean, P., McEvoy, N., Kremer, M. P., Daly, D., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0398-y · Cited by 477
Self-citationTu, S., Zhang, B., Zhang, Y., Chen, Z., Wang, X., Zhan, R., Ou, Y., Wang, W., Liu, X., Duan, X., et al. (2023) · Nature Energy · doi:10.1038/s41560-023-01387-5 · Cited by 382
Two-Dimensional Materials to Address the Lithium Battery Challenges
Rojaee, R., & Shahbazian-Yassar, R. (2020) · ACS Nano · doi:10.1021/acsnano.9b08396 · Cited by 344
Multiscale Understanding and Architecture Design of High Energy/Power Lithium‐Ion Battery Electrodes
Zhang, X., Ju, Z., Zhu, Y., Takeuchi, K. J., Takeuchi, E. S., Marschilok, A. C., & Yu, G. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202000808 · Cited by 299
Metadata
- Authors
- Tian, R., Park, S.-H., King, P. J., Cunningham, G., Coelho, J., Nicolosi, V., & Coleman, J. N.
- Venue
- Nature Communications
- Published
- 2019-04-29
- Volume
- 10
- Issue
- 1
- Pages
- 1933-1933
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2951341763
- Cited by
- 326
- References
- 60
- FWCI
- 12.25
- Type
- journal article
- Language
- en
- Open access
- gold
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