The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms
Open accessAbstract
Construction of organic semiconducting materials with in-plane π-conjugated structures and robustness through carbon-carbon bond linkages, alternatively as organic graphene analogs, is extremely desired for powerfully optoelectrical conversion. However, the poor reversibility for sp2 carbon bond forming reactions makes them unavailable for building high crystalline well-defined organic structures through a self-healing process, such as covalent organic frameworks (COFs). Here we report a scalable solution-processing approach to synthesize a family of two-dimensional (2D) COFs with trans-disubstituted C = C linkages via condensation reaction at arylmethyl carbon atoms on the basis of 3,5-dicyano-2,4,6-trimethylpyridine and linear/trigonal aldehyde (i.e., 4,4″-diformyl-p-terphenyl, 4,4′-diformyl-1,1′-biphenyl, or 1,3,5-tris(4-formylphenyl)benzene) monomers. Such sp2 carbon-jointed-pyridinyl frameworks, featuring crystalline honeycomb-like structures with high surface areas, enable driving two half-reactions of water splitting separately under visible light irradiation, comparable to graphitic carbon nitride (g-C 3 N 4) derivatives.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
A metal-free polymeric photocatalyst for hydrogen production from water under visible light
Wang, X., Maeda, K., Thomas, A., Takanabe, K., Xin, G., Carlsson, J. M., Domen, K., & Antonietti, M. (2009) · Nature Materials · doi:10.1038/nmat2317 · Cited by 12,532
Self-citationLight-emitting diodes based on conjugated polymers
Burroughes, J. H., Bradley, D. D. C., Brown, A. R., Marks, R. N., Mackay, K., Friend, R. H., Burns, P. L., & Holmes, A. B. (1990) · Nature · doi:10.1038/347539a0 · Cited by 11,393
Electroluminescence in conjugated polymers
Friend, R. H., Gymer, R. W., Holmes, A. B., Burroughes, J. H., Marks, R. N., Taliani, C., Bradley, D. D. C., Santos, D. A. D., Brédas, J. L., Lögdlund, M., et al. (1999) · Nature · doi:10.1038/16393 · Cited by 5,977
A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
Uribe-Romo, F. J., Hunt, J. R., Furukawa, H., Klöck, C., O’Keeffe, M., & Yaghi, O. M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8096256 · Cited by 1,715
Efficient light-emitting diodes based on polymers with high electron affinities
Greenham, N. C., Moratti, S. C., Bradley, D. D. C., Friend, R. H., & Holmes, A. B. (1993) · Nature · doi:10.1038/365628a0 · Cited by 1,653
Two-dimensional sp 2 carbon–conjugated covalent organic frameworks
Jin, E., Asada, M., Xu, Q., Dalapati, S., Addicoat, M. A., Brady, M. A., Xu, H., Nakamura, T., Heine, T., Chen, Q., et al. (2017) · Science · doi:10.1126/science.aan0202 · Cited by 1,334
Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water
Wang, X., Chen, L., Chong, S. Y., Little, M. A., Wu, Y., Zhu, W.-H., Clowes, R., Yan, Y., Zwijnenburg, M. A., Sprick, R. S., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0141-5 · Cited by 1,320
Self-citationA tunable azine covalent organic framework platform for visible light-induced hydrogen generation
Vyas, V. S., Haase, F., Stegbauer, L., Savasci, G., Podjaski, F., Ochsenfeld, C., & Lotsch, B. V. (2015) · Nature Communications · doi:10.1038/ncomms9508 · Cited by 1,263
A hydrazone-based covalent organic framework for photocatalytic hydrogen production
Stegbauer, L., Schwinghammer, K., & Lotsch, B. V. (2014) · Chem. Sci. · doi:10.1039/c4sc00016a · Cited by 1,145
Rationally synthesized two-dimensional polymers
Colson, J. W., & Dichtel, W. R. (2013) · Nature Chemistry · doi:10.1038/nchem.1628 · Cited by 1,016
Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Liu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Metadata
- Authors
- Bi, S., Yang, C., Zhang, W., Xu, J., Liu, L., Wu, D., Wang, X., Han, Y., Liang, Q., & Zhang, F.
- Venue
- Nature Communications
- Published
- 2019-06-06
- Volume
- 10
- Issue
- 1
- Pages
- 2467-2467
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2948440280
- Cited by
- 616
- References
- 35
- FWCI
- 25.62
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms. https://app.cochat.ai/papers/10.1038/s41467-019-10504-6
- The paper
- Bi, S., Yang, C., Zhang, W., Xu, J., Liu, L., Wu, D., Wang, X., Han, Y., Liang, Q., & Zhang, F. (2019). Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms. Nature Communications. https://doi.org/10.1038/s41467-019-10504-6
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
