The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine
Open accessAbstract
Molecular catalysts that combine high product selectivity and high current density for CO 2 electrochemical reduction to CO or other chemical feedstocks are urgently needed. While earth-abundant metal-based molecular electrocatalysts with high selectivity for CO 2 to CO conversion are known, they are characterized by current densities that are significantly lower than those obtained with solid-state metal materials. Here, we report that a cobalt phthalocyanine bearing a trimethyl ammonium group appended to the phthalocyanine macrocycle is capable of reducing CO 2 to CO in water with high activity over a broad pH range from 4 to 14. In a flow cell configuration operating in basic conditions, CO production occurs with excellent selectivity (ca. 95%), and good stability with a maximum partial current density of 165 mA cm−2 (at −0.92 V vs. RHE), matching the most active noble metal-based nanocatalysts. These results represent state-of-the-art performance for electrolytic carbon dioxide reduction by a molecular catalyst.
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Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Verma, S., Hamasaki, Y., Kim, C., Huang, W., Lu, S., Jhong, H.-R. M., Gewirth, A. A., Fujigaya, T., Nakashima, N., & Kenis, P. J. A. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.7b01096 · Cited by 521
Cited by
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Fang, S., Rahaman, M., Bharti, J., Reisner, E., Robert, M., Ozin, G. A., & Hu, Y. H. (2023) · Nature Reviews Methods Primers · doi:10.1038/s43586-023-00243-w · Cited by 834
Self-citationZhang, X., Wang, Y., Gu, M., Wang, M., Zhang, Z., Pan, W., Jiang, Z., Zheng, H., Lucero, M., Wang, H., et al. (2020) · Nature Energy · doi:10.1038/s41560-020-0667-9 · Cited by 631
Self-citationBoutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Self-citationWang, J.-W., Jiang, L., Huang, H.-H., Han, Z., & Ouyang, G. (2021) · Nature Communications · doi:10.1038/s41467-021-24647-y · Cited by 164
Metadata
- Authors
- Wang, M., Torbensen, K., Salvatore, D., Ren, S., Joulié, D., Dumoulin, F., Mendoza, D., Lassalle-Kaiser, B., Işci, U., Berlinguette, C. P., & Robert, M.
- Venue
- Nature Communications
- Published
- 2019-08-09
- Volume
- 10
- Issue
- 1
- Pages
- 3602-3602
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2968917598
- Cited by
- 505
- References
- 3
- FWCI
- 11.85
- Type
- journal article
- Language
- en
- Open access
- gold
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- Wang, M., Torbensen, K., Salvatore, D., Ren, S., Joulié, D., Dumoulin, F., Mendoza, D., Lassalle-Kaiser, B., Işci, U., Berlinguette, C. P., & Robert, M. (2019). CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine. Nature Communications. https://doi.org/10.1038/s41467-019-11542-w
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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