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Enabling long-lived organic room temperature phosphorescence in polymers by subunit interlocking

Open access
Cai, Suzhi, Ma, Huili, Shi, Huifang, Wang, He, Wang, Xuan, Xiao, Leixin, Ye, Wenpeng, Huang, Kaiwei, Cao, Xudong, Gan, Nan, Ma, Chaoqun, Gu, Mingxing, Song, Lulu, Xu, Hai, Tao, Youtian, Zhang, Chunfeng, Yao, Wei, An, Zhongfu, Huang, Wei·2019·Nature Communications

Abstract

Long-lived room temperature phosphorescence (LRTP) is an attractive optical phenomenon in organic electronics and photonics. Despite the rapid advance, it is still a formidable challenge to explore a universal approach to obtain LRTP in amorphous polymers. Based on the traditional polyethylene derivatives, we herein present a facile and concise chemical strategy to achieve ultralong phosphorescence in polymers by ionic bonding cross-linking. Impressively, a record LRTP lifetime of up to 2.1 s in amorphous polymers under ambient conditions is set up. Moreover, multicolor long-lived phosphorescent emission can be procured by tuning the excitation wavelength in single-component polymer materials. These results outline a fundamental principle for the construction of polymer materials with LRTP, endowing traditional polymers with fresh features for potential applications.

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Metadata

Authors
Cai, S., Ma, H., Shi, H., Wang, H., Wang, X., Xiao, L., Ye, W., Huang, K., Cao, X., Gan, N., Ma, C., Gu, M., Song, L., Xu, H., Tao, Y., Zhang, C., Yao, W., An, Z., & Huang, W.
Venue
Nature Communications
Published
2019-09-18
Volume
10
Issue
1
Pages
4247-4247
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2973616789
Cited by
302
References
2
FWCI
11.64
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Enabling long-lived organic room temperature phosphorescence in polymers by subunit interlocking. https://app.cochat.ai/papers/10.1038/s41467-019-11749-x
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Cai, S., Ma, H., Shi, H., Wang, H., Wang, X., Xiao, L., Ye, W., Huang, K., Cao, X., Gan, N., Ma, C., Gu, M., Song, L., Xu, H., Tao, Y., Zhang, C., Yao, W., An, Z., & Huang, W. (2019). Enabling long-lived organic room temperature phosphorescence in polymers by subunit interlocking. Nature Communications. https://doi.org/10.1038/s41467-019-11749-x

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.