The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Unraveling the coordination structure-performance relationship in Pt1/Fe2O3 single-atom catalyst
Open accessAbstract
Heterogeneous single-atom catalyst (SAC) opens a unique entry to establishing structure–performance relationship at the molecular level similar to that in homogeneous catalysis. The challenge lies in manipulating the coordination chemistry of single atoms without changing single-atom dispersion. Here, we develop an efficient synthetic method for SACs by using ethanediamine to chelate Pt cations and then removing the ethanediamine by a rapid thermal treatment (RTT) in inert atmosphere. The coordination chemistry of Pt single atoms on a Fe 2 O 3 support is finely tuned by merely adjusting the RTT temperature. With the decrease in Pt-O coordination number, the oxidation state of Pt decreases, and consequently the hydrogenation activity increases to a record level without loss of chemoselectivity. The tunability of the local coordination chemistry, oxidation states of the metal, and the catalytic performance of single atoms reveals the unique role of SACs as a bridge between heterogeneous and homogeneous catalysis.
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1 retracted
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Cited by
Shi, Y., Ma, Z.-R., Xiao, Y.-Y., Yin, Y.-C., Huang, W.-M., Huang, Z.-C., Zheng, Y.-Z., Mu, F.-Y., Huang, R., Shi, G.-Y., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-23306-6 · Cited by 894
Functional CeOx nanoglues for robust atomically dispersed catalysts
Li, X., Pereira-Hernández, X. I., Chen, Y., Xu, J., Zhao, J., Pao, C.-W., Fang, C.-Y., Zeng, J., Wang, Y., Gates, B. C., et al. (2022) · Nature · doi:10.1038/s41586-022-05251-6 · Cited by 543
Understanding the structure-performance relationship of active sites at atomic scale
Li, R., & Wang, D. (2022) · Nano Research · doi:10.1007/s12274-022-4371-x · Cited by 537
Phase-dependent growth of Pt on MoS2 for highly efficient H2 evolution
Shi, Z., Zhang, X., Lin, X., Liu, G., Ling, C., Xi, S., Chen, B., Ge, Y., Tan, C., Lai, Z., et al. (2023) · Nature · doi:10.1038/s41586-023-06339-3 · Cited by 463
Self-citationMa, X., Liu, H., Yang, W., Mao, G., Zheng, L., & Jiang, H.-L. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05032 · Cited by 445
Metadata
- Authors
- Ren, Y., Tang, Y., Zhang, L., Liu, X., Li, L., Miao, S., Sheng Su, D., Wang, A., Li, J., & Zhang, T.
- Venue
- Nature Communications
- Published
- 2019-10-03
- Volume
- 10
- Issue
- 1
- Pages
- 4500-4500
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2977270706
- Cited by
- 458
- References
- 43
- FWCI
- 17.98
- Type
- journal article
- Language
- en
- Open access
- gold
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- Ren, Y., Tang, Y., Zhang, L., Liu, X., Li, L., Miao, S., Sheng Su, D., Wang, A., Li, J., & Zhang, T. (2019). Unraveling the coordination structure-performance relationship in Pt1/Fe2O3 single-atom catalyst. Nature Communications. https://doi.org/10.1038/s41467-019-12459-0
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