The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation
Open accessAbstract
The surface chemistry of solid electrolyte interphase is one of the critical factors that govern the cycling life of rechargeable batteries. However, this chemistry is less explored for zinc anodes, owing to their relatively high redox potential and limited choices in electrolyte. Here, we report the observation of a zinc fluoride-rich organic/inorganic hybrid solid electrolyte interphase on zinc anode, based on an acetamide-Zn(TFSI)2 eutectic electrolyte. A combination of experimental and modeling investigations reveals that the presence of anion-complexing zinc species with markedly lowered decomposition energies contributes to the in situ formation of an interphase. The as-protected anode enables reversible (~100% Coulombic efficiency) and dendrite-free zinc plating/stripping even at high areal capacities (>2.5 mAh cm‒2), endowed by the fast ion migration coupled with high mechanical strength of the protective interphase. With this interphasial design the assembled zinc batteries exhibit excellent cycling stability with negligible capacity loss at both low and high rates.
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Cites
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
“Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries
Suo, L., Borodin, O., Gao, T., Olguin, M., Ho, J., Fan, X., Luo, C., Wang, C., & Xu, K. (2015) · Science · doi:10.1126/science.aab1595 · Cited by 3,821
Ionic Liquids Based upon Metal Halide/Substituted Quaternary Ammonium Salt Mixtures
Abbott, A. P., Capper, G., Davies, D. L., & Rasheed, R. (2004) · Inorganic Chemistry · doi:10.1021/ic049931s · Cited by 364
Li + Solvation and Ionic Transport in Lithium Solvate Ionic Liquids Diluted by Molecular Solvents
Ueno, K., Murai, J., Ikeda, K., Tsuzuki, S., Tsuchiya, M., Tatara, R., Mandai, T., Umebayashi, Y., Dokko, K., & Watanabe, M. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b11642 · Cited by 149
Cited by
Insight on Organic Molecules in Aqueous Zn‐Ion Batteries with an Emphasis on the Zn Anode Regulation
Wang, D., Li, Q., Zhao, Y., Hong, H., Li, H., Huang, Z., Liang, G., Yang, Q., & Zhi, C. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202102707 · Cited by 478
Design of a Solid Electrolyte Interphase for Aqueous Zn Batteries
Li, D., Cao, L., Deng, T., Liu, S., & Wang, C. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202103390 · Cited by 466
Zinc dendrite growth and inhibition strategies
Zuo, Y., Wang, K., Pei, P., Wei, M., Liu, X., Xiao, Y., & Zhang, P. (2021) · Materials Today Energy · doi:10.1016/j.mtener.2021.100692 · Cited by 409
Electrochemical Zinc Ion Capacitors: Fundamentals, Materials, and Systems
Yin, J., Zhang, W., Alhebshi, N. A., Salah, N., & Alshareef, H. N. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100201 · Cited by 325
Metadata
- Authors
- Qiu, H., Du, X., Zhao, J., Wang, Y., Ju, J., Chen, Z., Hu, Z., Yan, D., Zhou, X., & Cui, G.
- Venue
- Nature Communications
- Published
- 2019-11-26
- Volume
- 10
- Issue
- 1
- Pages
- 5374-5374
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2989628316
- Cited by
- 953
- References
- 5
- FWCI
- 33.04
- Type
- journal article
- Language
- en
- Open access
- gold
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- Qiu, H., Du, X., Zhao, J., Wang, Y., Ju, J., Chen, Z., Hu, Z., Yan, D., Zhou, X., & Cui, G. (2019). Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation. Nature Communications. https://doi.org/10.1038/s41467-019-13436-3
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