The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Biomacromolecules enabled dendrite-free lithium metal battery and its origin revealed by cryo-electron microscopy
Open accessAbstract
Metallic lithium anodes are highly promising for revolutionizing current rechargeable batteries because of their ultrahigh energy density. However, the application of lithium metal batteries is considerably impeded by lithium dendrite growth. Here, a biomacromolecule matrix obtained from the natural membrane of eggshell is introduced to control lithium growth and the mechanism is motivated by how living organisms regulate the orientation of inorganic crystals in biomineralization. Specifically, cryo-electron microscopy is utilized to probe the structure of lithium at the atomic level. The dendrites growing along the preferred < 111 > crystallographic orientation are greatly suppressed in the presence of the biomacromolecule. Furthermore, the naturally soluble chemical species in the biomacromolecules can participate in the formation of solid electrolyte interphase upon cycling, thus effectively homogenizing the lithium deposition. The lithium anodes employing bioinspired design exhibit enhanced cycling capability. This work sheds light on identifying substantial challenges in lithium anodes for developing advanced batteries.
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Citations
Cites
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
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Role of molecular charge and hydrophilicity in regulating the kinetics of crystal growth
Elhadj, S., De Yoreo, J. J., Hoyer, J. R., & Dove, P. M. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0605748103 · Cited by 270
High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes
Yang, Y., Davies, D. M., Yin, Y., Borodin, O., Lee, J. Z., Fang, C., Olguin, M., Zhang, Y., Sablina, E. S., Wang, X., et al. (2019) · Joule · doi:10.1016/j.joule.2019.06.008 · Cited by 268
Shaping crystals with biomolecules
De Yoreo, J. J., & Dove, P. M. (2004) · Science · doi:10.1126/science.1100889 · Cited by 180
Cited by
A Growing Appreciation for the Role of LiF in the Solid Electrolyte Interphase
Tan, J., Matz, J., Dong, P., Shen, J., & Ye, M. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100046 · Cited by 1,019
Self-assembled monolayers direct a LiF-rich interphase toward long-life lithium metal batteries
Liu, Y., Tao, X., Wang, Y., Jiang, C., Ma, C., Sheng, O., Lu, G., & Lou, X. W. (. (2022) · Science · doi:10.1126/science.abn1818 · Cited by 962
Self-citationHow to avoid dendrite formation in metal batteries: Innovative strategies for dendrite suppression
Aslam, M. K., Niu, Y., Hussain, T., Tabassum, H., Tang, W., Xu, M., & Ahuja, R. (2021) · Nano Energy · doi:10.1016/j.nanoen.2021.106142 · Cited by 308
Han, Y., Liu, B., Xiao, Z., Zhang, W., Wang, X., Pan, G., Xia, Y., Xia, X., & Tu, J. (2021) · InfoMat · doi:10.1002/inf2.12166 · Cited by 267
Self-citationBiomass‐Derived Carbon for High‐Performance Batteries: From Structure to Properties
Sun, Y., Shi, X., Yang, Y., Suo, G., Zhang, L., Lu, S., & Chen, Z. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202201584 · Cited by 253
Metadata
- Authors
- Ju, Z., Nai, J., Wang, Y., Liu, T., Zheng, J., Yuan, H., Sheng, O., Jin, C., Zhang, W., Jin, Z., Tian, H., Liu, Y., & Tao, X.
- Venue
- Nature Communications
- Published
- 2020-01-24
- Volume
- 11
- Issue
- 1
- Pages
- 488-488
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3002990880
- Cited by
- 224
- References
- 6
- FWCI
- 13.17
- Type
- journal article
- Language
- en
- Open access
- gold
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- Ju, Z., Nai, J., Wang, Y., Liu, T., Zheng, J., Yuan, H., Sheng, O., Jin, C., Zhang, W., Jin, Z., Tian, H., Liu, Y., & Tao, X. (2020). Biomacromolecules enabled dendrite-free lithium metal battery and its origin revealed by cryo-electron microscopy. Nature Communications. https://doi.org/10.1038/s41467-020-14358-1
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