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Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer

Open access
Gu, Long, Wu, Hongwei, Ma, Huili, Ye, Wenpeng, Jia, Wenyong, Wang, He, Chen, Hongzhong, Zhang, Nan, Wang, Dongdong, Qian, Cheng, An, Zhongfu, Huang, Wei, Zhao, Yanli·2020·Nature Communications

Abstract

Functional materials displaying tunable emission and long-lived luminescence have recently emerged as a powerful tool for applications in information encryption, organic electronics and bioelectronics. Herein, we present a design strategy to achieve color-tunable ultralong organic room temperature phosphorescence (UOP) in polymers through radical multicomponent cross-linked copolymerization. Our experiments reveal that by changing the excitation wavelength from 254 to 370 nm, these polymers display multicolor luminescence spanning from blue to yellow with a long-lived lifetime of 1.2 s and a maximum phosphorescence quantum yield of 37.5% under ambient conditions. Moreover, we explore the application of these polymers in multilevel information encryption based on the color-tunable UOP property. This strategy paves the way for the development of multicolor bio-labels and smart luminescent materials with long-lived emission at room temperature.

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Metadata

Authors
Gu, L., Wu, H., Ma, H., Ye, W., Jia, W., Wang, H., Chen, H., Zhang, N., Wang, D., Qian, C., An, Z., Huang, W., & Zhao, Y.
Venue
Nature Communications
Published
2020-02-18
Volume
11
Issue
1
Pages
944-944
ISSN
2041-1723 (ISSN-L)
OpenAlex
W3007198460
Cited by
471
References
2
FWCI
24.52
Type
journal article
Language
en
Open access
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CoChat. (2026). Citation check: Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer. https://app.cochat.ai/papers/10.1038/s41467-020-14792-1
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Gu, L., Wu, H., Ma, H., Ye, W., Jia, W., Wang, H., Chen, H., Zhang, N., Wang, D., Qian, C., An, Z., Huang, W., & Zhao, Y. (2020). Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer. Nature Communications. https://doi.org/10.1038/s41467-020-14792-1

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