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Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production
Open accessAbstract
The protonic ceramic electrochemical cell (PCEC) is an emerging and attractive technology that converts energy between power and hydrogen using solid oxide proton conductors at intermediate temperatures. To achieve efficient electrochemical hydrogen and power production with stable operation, highly robust and durable electrodes are urgently desired to facilitate water oxidation and oxygen reduction reactions, which are the critical steps for both electrolysis and fuel cell operation, especially at reduced temperatures. In this study, a triple conducting oxide of PrNi 0.5 Co 0.5 O 3-δ perovskite is developed as an oxygen electrode, presenting superior electrochemical performance at 400~600 °C. More importantly, the self-sustainable and reversible operation is successfully demonstrated by converting the generated hydrogen in electrolysis mode to electricity without any hydrogen addition. The excellent electrocatalytic activity is attributed to the considerable proton conduction, as confirmed by hydrogen permeation experiment, remarkable hydration behavior and computations.
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Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Cited by
Vidas, L., & Castro, R. (2021) · Applied Sciences · doi:10.3390/app112311363 · Cited by 269
Luo, Z., Hu, X., Zhou, Y., Ding, Y., Zhang, W., Li, T., & Liu, M. (2024) · Advanced Materials · doi:10.1002/adma.202311159 · Cited by 59
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Metadata
- Authors
- Ding, H., Wu, W., Jiang, C., Ding, Y., Bian, W., Hu, B., Singh, P., Orme, C. J., Wang, L., Zhang, Y., & Ding, D.
- Venue
- Nature Communications
- Published
- 2020-04-20
- Volume
- 11
- Issue
- 1
- Pages
- 1907-1907
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3017195183
- Cited by
- 498
- References
- 2
- FWCI
- 18.65
- Type
- journal article
- Language
- en
- Open access
- gold
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- Ding, H., Wu, W., Jiang, C., Ding, Y., Bian, W., Hu, B., Singh, P., Orme, C. J., Wang, L., Zhang, Y., & Ding, D. (2020). Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production. Nature Communications. https://doi.org/10.1038/s41467-020-15677-z
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