The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Promoting H2O2 production via 2-electron oxygen reduction by coordinating partially oxidized Pd with defect carbon
Open accessAbstract
Electrochemical synthesis of H 2 O 2 through a selective two-electron (2e−) oxygen reduction reaction (ORR) is an attractive alternative to the industrial anthraquinone oxidation method, as it allows decentralized H 2 O 2 production. Herein, we report that the synergistic interaction between partially oxidized palladium (Pd δ+) and oxygen-functionalized carbon can promote 2e−ORR in acidic electrolytes. An electrocatalyst synthesized by solution deposition of amorphous Pd δ+clusters (Pd 3δ+and Pd 4δ+) onto mildly oxidized carbon nanotubes (Pd δ+-OCNT) shows nearly 100% selectivity toward H 2 O 2 and a positive shift of ORR onset potential by ~320 mV compared with the OCNT substrate. A high mass activity (1.946 A mg−1 at 0.45 V) of Pd δ+-OCNT is achieved. Extended X-ray absorption fine structure characterization and density functional theory calculations suggest that the interaction between Pd clusters and the nearby oxygen-containing functional groups is key for the high selectivity and activity for 2e−ORR.
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Double-slit photoelectron interference in strong-field ionization of the neon dimer
Kunitski, M., Eicke, N., Huber, P., Köhler, J., Zeller, S., Voigtsberger, J., Schlott, N., Henrichs, K., Sann, H., Trinter, F., et al. (2019) · Nature Communications · doi:10.1038/s41467-018-07882-8 · Cited by 8,162
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Self-citationElectro-Fenton Process and Related Electrochemical Technologies Based on Fenton’s Reaction Chemistry
Brillas, E., Sirés, I., & Oturan, M. A. (2009) · Chemical Reviews · doi:10.1021/cr900136g · Cited by 3,437
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Analysis of Soils and Minerals Using X‐ray Absorption Spectroscopy
Kelly, S. D., Hesterberg, D., & Ravel, B. (2008) · SSSA Book Series · doi:10.2136/sssabookser5.5.c14 · Cited by 400
Cited by
Siahrostami, S., Villegas, S. J., Bagherzadeh Mostaghimi, A. H., Back, S., Farimani, A. B., Wang, H., Persson, K. A., & Montoya, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01641 · Cited by 503
Self-citationHighly active and selective oxygen reduction to H2O2 on boron-doped carbon for high production rates
Xia, Y., Zhao, X., Xia, C., Wu, Z.-Y., Zhu, P., Kim, J. Y., Bai, X., Gao, G., Hu, Y., Zhong, J., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-24329-9 · Cited by 499
Self-citationCation‐Vacancy‐Enriched Nickel Phosphide for Efficient Electrosynthesis of Hydrogen Peroxides
Zhou, Z., Kong, Y., Tan, H., Huang, Q., Wang, C., Pei, Z., Wang, H., Liu, Y., Wang, Y., Li, S., et al. (2022) · Advanced Materials · doi:10.1002/adma.202106541 · Cited by 325
Metadata
- Authors
- Chang, Q., Zhang, P., Mostaghimi, A. H. B., Zhao, X., Denny, S. R., Lee, J. H., Gao, H., Zhang, Y., Xin, H. L., Siahrostami, S., Chen, J. G., & Chen, Z.
- Venue
- Nature Communications
- Published
- 2020-05-01
- Volume
- 11
- Issue
- 1
- Pages
- 2178-2178
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3020883793
- Cited by
- 416
- References
- 5
- FWCI
- 9.30
- Type
- journal article
- Language
- en
- Open access
- gold
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- Chang, Q., Zhang, P., Mostaghimi, A. H. B., Zhao, X., Denny, S. R., Lee, J. H., Gao, H., Zhang, Y., Xin, H. L., Siahrostami, S., Chen, J. G., & Chen, Z. (2020). Promoting H2O2 production via 2-electron oxygen reduction by coordinating partially oxidized Pd with defect carbon. Nature Communications. https://doi.org/10.1038/s41467-020-15843-3
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