The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
In situ inorganic conductive network formation in high-voltage single-crystal Ni-rich cathodes
Open accessAbstract
High nickel content in LiNi x Co y Mn z O 2 (NCM, x ≥ 0.8, x + y + z = 1) layered cathode material allows high specific energy density in lithium-ion batteries (LIBs). However, Ni-rich NCM cathodes suffer from performance degradation, mechanical and structural instability upon prolonged cell cycling. Although the use of single-crystal Ni-rich NCM can mitigate these drawbacks, the ion-diffusion in large single-crystal particles hamper its rate capability. Herein, we report a strategy to construct an in situ Li 1.4 Y 0.4 Ti 1.6(PO 4)3 (LYTP) ion/electron conductive network which interconnects single-crystal LiNi 0.88 Co 0.09 Mn 0.03 O 2 (SC-NCM88) particles. The LYTP network facilitates the lithium-ion transport between SC-NCM88 particles, mitigates mechanical instability and prevents detrimental crystalline phase transformation. When used in combination with a Li metal anode, the LYTP-containing SC-NCM88-based cathode enables a coin cell capacity of 130 mAh g−1 after 500 cycles at 5 C rate in the 2.75-4.4 V range at 25 °C. Tests in Li-ion pouch cell configuration (i.e., graphite used as negative electrode active material) demonstrate capacity retention of 85% after 1000 cycles at 0.5 C in the 2.75-4.4 V range at 25 °C for the LYTP-containing SC-NCM88-based positive electrode.
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Cites
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Nickel‐Rich Layered Lithium Transition‐Metal Oxide for High‐Energy Lithium‐Ion Batteries
Liu, W., Oh, P., Liu, X., Lee, M., Cho, W., Chae, S., Kim, Y., & Cho, J. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409262 · Cited by 1,960
Ryu, H.-H., Park, K.-J., Yoon, C. S., & Sun, Y.-K. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b05269 · Cited by 1,629
Bajdich, M., García-Mota, M., Vojvodic, A., Nørskov, J. K., & Bell, A. T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405997s · Cited by 1,403
Yan, P., Zheng, J., Gu, M., Xiao, J., Zhang, J.-G., & Wang, C.-M. (2017) · Nature Communications · doi:10.1038/ncomms14101 · Cited by 1,010
Self-citationProspect and Reality of Ni‐Rich Cathode for Commercialization
Kim, J., Lee, H., Cha, H., Yoon, M., Park, M., & Cho, J. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201702028 · Cited by 933
Ionic Conductivity of Solid Electrolytes Based on Lithium Titanium Phosphate
Aono, H., Sugimoto, E., Sadaoka, Y., Imanaka, N., & Adachi, G. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086597 · Cited by 923
Yan, P., Zheng, J., Liu, J., Wang, B., Cheng, X., Zhang, Y., Sun, X., Wang, C., & Zhang, J.-G. (2018) · Nature Energy · doi:10.1038/s41560-018-0191-3 · Cited by 826
Self-citationElectric Vehicles Batteries: Requirements and Challenges
Deng, J., Bae, C., Denlinger, A., & Miller, T. (2020) · Joule · doi:10.1016/j.joule.2020.01.013 · Cited by 761
Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries
Xu, C., Märker, K., Lee, J., Mahadevegowda, A., Reeves, P. J., Day, S. J., Groh, M. F., Emge, S. P., Ducati, C., Layla Mehdi, B., et al. (2021) · Nature Materials · doi:10.1038/s41563-020-0767-8 · Cited by 707
Cited by
Ou, X., Liu, T., Zhong, W., Fan, X., Guo, X., Huang, X., Cao, L., Hu, J., Zhang, B., Chu, Y. S., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-30020-4 · Cited by 454
Self-citationWang, J., Li, D., Zeng, W., Chen, X., Zhang, Y., Zhang, S., Li, Z., Li, C., & Mu, S. (2025) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2024.11.016 · Cited by 62
Metadata
- Authors
- Fan, X., Ou, X., Zhao, W., Liu, Y., Zhang, B., Zhang, J., Zou, L., Seidl, L., Li, Y., Hu, G., Battaglia, C., & Yang, Y.
- Venue
- Nature Communications
- Published
- 2021-09-07
- Volume
- 12
- Issue
- 1
- Pages
- 5320-5320
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3197300555
- Cited by
- 488
- References
- 47
- FWCI
- 21.31
- Type
- journal article
- Language
- en
- Open access
- gold
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- Fan, X., Ou, X., Zhao, W., Liu, Y., Zhang, B., Zhang, J., Zou, L., Seidl, L., Li, Y., Hu, G., Battaglia, C., & Yang, Y. (2021). In situ inorganic conductive network formation in high-voltage single-crystal Ni-rich cathodes. Nature Communications. https://doi.org/10.1038/s41467-021-25611-6
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