The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Natural short-lived halogens exert an indirect cooling effect on climate
Open accessAbstract
Observational evidence shows the ubiquitous presence of ocean-emitted short-lived halogens in the global atmosphere 1–3 . Natural emissions of these chemical compounds have been anthropogenically amplified since pre-industrial times 4–6 , while, in addition, anthropogenic short-lived halocarbons are currently being emitted to the atmosphere 7,8 . Despite their widespread distribution in the atmosphere, the combined impact of these species on Earth’s radiative balance remains unknown. Here we show that short-lived halogens exert a substantial indirect cooling effect at present (−0.13 ± 0.03 watts per square metre) that arises from halogen-mediated radiative perturbations of ozone (−0.24 ± 0.02 watts per square metre), compensated by those from methane (+0.09 ± 0.01 watts per square metre), aerosols (+0.03 ± 0.01 watts per square metre) and stratospheric water vapour (+0.011 ± 0.001 watts per square metre). Importantly, this substantial cooling effect has increased since 1750 by −0.05 ± 0.03 watts per square metre (61 per cent), driven by the anthropogenic amplification of natural halogen emissions, and is projected to change further (18–31 per cent by 2100) depending on climate warming projections and socioeconomic development. We conclude that the indirect radiative effect due to short-lived halogens should now be incorporated into climate models to provide a more realistic natural baseline of Earth’s climate system.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The change in radiative forcing due to a lower tropospheric ozone burden from halogen chemistry has been simulated to be ca -0.20 W m−2 and -0.25 W m−2 for the year 2100 following the RCP6.0 and RCP8.5 scenarios, respectively.
“The change in radiative forcing due to a lower tropospheric ozone burden from halogen chemistry has been simulated to be ca –0.20 W m−2 and –0.25 W m−2 for the year 2100 following the scenarios RCP6.0 and RCP8.5, respectively [81].”
From Environmental consequences of interacting effects of changes in stratospheric ozone, ultraviolet radiation, and climate: UNEP Environmental Effects Assessment Panel, Update 2024 (2025) · cites this paper as [81]
The Ozone section reports year-2100 ozone radiative effects of −0.19 ± 0.01 W m−2 under RCP6.0 and −0.24 ± 0.02 W m−2 under RCP8.5, consistent with the claim’s approximate values. But these are effects of total ozone loss, not solely a lower tropospheric ozone burden; the Change relative to pre-industrial times section notes a significant contribution from the lower stratosphere. (LLM, conf=0.88)
Experimental — accuracy not yet measuredA lower burden of tropospheric ozone reduces production of the hydroxyl radical, because photolysis of ozone by UV-B radiation is the principal source of OH.
“An adverse effect of a lower burden of tropospheric ozone is a reduced production of OH, the major tropospheric cleaning agent; this occurs, because photolysis of ozone by UV-B radiation is the principal source of OH.”
From Environmental consequences of interacting effects of changes in stratospheric ozone, ultraviolet radiation, and climate: UNEP Environmental Effects Assessment Panel, Update 2024 (2025) · cites this paper as [81]
The Net radiative effect > Methane section (page unavailable) says tropospheric ozone is the principal source of OH and reports reduced methane oxidation by OH associated with halogen-driven changes. The Ozone section reports a lower tropospheric ozone burden. Our copy does not specify UV-B photolysis as the mechanism of OH production, so that part of the claim is unsupported. (LLM, conf=0.86)
Experimental — accuracy not yet measuredThis study shows the importance of including tropospheric VSLS halogen chemistry in the modelling of the future radiative forcing of climate change.
“This study shows the importance of including tropospheric VSLS halogen chemistry in the modelling of the future radiative forcing of climate change.”
According to simulations, the increases in radiative forcing caused by increases in the methane burden due to halogen-ozone chemistry is ca 0.1 W m−2 for both RCP6.0 and RCP8.5.
“According to simulations [81], the increases in radiative forcing caused by increases in the CH4 burden due to the halogen–ozone chemistry is ca 0.1 W m−2 for both scenarios, RCP6.0 and RCP8.5.”
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Wiedinmyer, C., Yokelson, R. J., & Gullett, B. K. (2014) · Environmental Science & Technology · doi:10.1021/es502250z · Cited by 527
Tropospheric ozone in CMIP6 simulations
Griffiths, P. T., Murray, L. T., Zeng, G., Shin, Y. M., Abraham, N. L., Archibald, A. T., Deushi, M., Emmons, L. K., Galbally, I. E., Hassler, B., et al. (2021) · Atmospheric Chemistry and Physics · doi:10.5194/acp-21-4187-2021 · Cited by 289
Self-citationTropospheric Ozone Assessment Report
Archibald, A. T., Neu, J. L., Elshorbany, Y. F., Cooper, O. R., Young, P. J., Akiyoshi, H., Cox, R. A., Coyle, M., Derwent, R. G., Deushi, M., et al. (2020) · Elementa: Science of the Anthropocene · doi:10.1525/elementa.2020.034 · Cited by 239
Self-citation
Flagged first, then by citations
Research works printed but not linked: 107
- Saiz-Lopez, A. & von Glasow, R. Reactive halogen chemistry in the troposphere. Chem. Soc. Rev. 41, 6448–6472 (2012). · DOI
- Simpson, W. R., Brown, S. S., Saiz-Lopez, A., Thornton, J. A. & Von Glasow, R. Tropospheric halogen chemistry: sources, cycling, and impacts. Chem. Rev. 115, 4035–4062 (2015). · DOI
- Cuevas, C. A. et al. Rapid increase in atmospheric iodine levels in the North Atlantic since the mid-20th century. Nat. Commun. 9, 1452 (2018). · DOI
- Legrand, M. et al. Alpine ice evidence of a three-fold increase in atmospheric iodine deposition since 1950 in Europe due to increasing oceanic emissions. Proc. Natl Acad. Sci. USA 115, 12136–12141 (2018). · DOI
- Zhao, X., Hou, X. & Zhou, W. Atmospheric iodine (127I and 129I) record in spruce tree rings in the northeast Qinghai-Tibet Plateau. Environ. Sci. Technol. 53, 8706–8714 (2019). · DOI
- Fang, X. et al. Rapid increase in ozone-depleting chloroform emissions from China. Nat. Geosci. 12, 89–93 (2019). · DOI
- An, M. et al. Rapid increase in dichloromethane emissions from China inferred through atmospheric observations. Nat. Commun. 12, 7279 (2021). · DOI
- Andreae, M. O. & Crutzen, P. J. Atmospheric aerosols: biogeochemical sources and role in atmospheric chemistry. Science 276, 1052–1058 (1997). · DOI
- Alicke, B., Hebestreit, K., Stutz, J. & Platt, U. Iodine oxide in the marine boundary layer. Nature 397, 572–573 (1999). · DOI
- Chance, K. Analysis of BrO measurements from the Global Ozone Monitoring Experiment. Geophys. Res. Lett. 25, 3335–3338 (1998). · DOI
- Dix, B. et al. Detection of iodine monoxide in the tropical free troposphere. Proc. Natl Acad. Sci. USA 110, 2035–2040 (2013). · DOI
- Koenig, T. K. et al. Quantitative detection of iodine in the stratosphere. Proc. Natl Acad. Sci. USA 117, 1860–1866 (2020). · DOI
- Liao, J. et al. High levels of molecular chlorine in the Arctic atmosphere. Nat. Geosci. 7, 91–94 (2014). · DOI
- Platt, U. & Wagner, T. Satellite mapping of enhanced BrO concentrations in the troposphere. Nature 395, 486–490 (1998). · DOI
- Read, K. A. et al. Extensive halogen-mediated ozone destruction over the tropical Atlantic Ocean. Nature 453, 1232–1235 (2008). · DOI
- Saiz-Lopez, A. et al. Boundary layer halogens in coastal Antarctica. Science 317, 348–351 (2007). · DOI
- Thornton, J. A. et al. A large atomic chlorine source inferred from mid-continental reactive nitrogen chemistry. Nature 464, 271–274 (2010). · DOI · Paper page
- Prados-Roman, C. et al. Iodine oxide in the global marine boundary layer. Atmos. Chem. Phys. 15, 583–593 (2015). · DOI
- Ziska, F., Quack, B., Tegtmeier, S., Stemmler, I. & Krüger, K. Future emissions of marine halogenated very-short lived substances under climate change. J. Atmos. Chem. 74, 245–260 (2017). · DOI
- Hossaini, R. et al. The increasing threat to stratospheric ozone from dichloromethane. Nat. Commun. 8, 15962 (2017). · DOI
- Breider, T. J., Chipperfield, M. P., Mann, G. W., Woodhouse, M. T. & Carslaw, K. S. Suppression of CCN formation by bromine chemistry in the remote marine atmosphere. Atmos. Sci. Lett. 16, 141–147 (2015). · DOI
- O’Dowd, C. D. et al. A dedicated study of New Particle Formation and Fate in the Coastal Environment (PARFORCE): overview of objectives and achievements. J. Geophys. Res. Atmos. 107, 8108 (2002). · DOI
- Sipilä, M. et al. Molecular-scale evidence of aerosol particle formation via sequential addition of HIO3. Nature 537, 532–534 (2016). · DOI
- Gómez Martín, J. C. et al. A gas-to-particle conversion mechanism helps to explain atmospheric particle formation through clustering of iodine oxides. Nat. Commun. 11, 4521 (2020). · DOI
- Ordóñez, C. et al. Bromine and iodine chemistry in a global chemistry–climate model: description and evaluation of very short-lived oceanic sources. Atmos. Chem. Phys. 12, 1423–1447 (2012). · DOI
- Saiz-Lopez, A. et al. Estimating the climate significance of halogen-driven ozone loss in the tropical marine troposphere. Atmos. Chem. Phys. 12, 3939–3949 (2012). · DOI
- Hossaini, R. et al. Efficiency of short-lived halogens at influencing climate through depletion of stratospheric ozone. Nat. Geosci. 8, 186–190 (2015). · DOI
- Sherwen, T. et al. Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem. Atmos. Chem. Phys. 16, 12239–12271 (2016). · DOI
- Saiz-Lopez, A. et al. Iodine chemistry in the troposphere and its effect on ozone. Atmos. Chem. Phys. 14, 13119–13143 (2014). · DOI
- Stone, D. et al. Impacts of bromine and iodine chemistry on tropospheric OH and HO2: comparing observations with box and global model perspectives. Atmos. Chem. Phys. 18, 3541–3561 (2018). · DOI
- Forster, P. et al. in Climate Change 2021: The Physical Science Basis (eds Masson-Delmotte, V. et al.) 923–1054 (Cambridge Univ. Press, 2021).
- Szopa, S. et al. in Climate Change 2021: The Physical Science Basis (eds Masson-Delmotte, V. et al.) 817–922 (Cambridge Univ. Press, 2021).
- Isaksen, I. S. A. et al. Atmospheric composition change: climate–chemistry interactions. Atmos. Environ. 43, 5138–5192 (2009). · DOI
- Myhre, G. et al. in Climate Change 2013: The Physical Science Basis Ch. 8 (eds Stocker, T. F. et al.) 659–740 (Cambridge Univ. Press., 2013).
- Penner, J. E., Chen, Y., Wang, M. & Liu, X. Possible influence of anthropogenic aerosols on cirrus clouds and anthropogenic forcing. Atmos. Chem. Phys. 9, 879–896 (2009). · DOI
- Iglesias-Suarez, F. et al. Natural halogens buffer tropospheric ozone in a changing climate. Nat. Clim. Change 10, 147–154 (2020). · DOI
- Prados-Roman, C. et al. A negative feedback between anthropogenic ozone pollution and enhanced ocean emissions of iodine. Atmos. Chem. Phys. 15, 2215–2224 (2015). · DOI
- Li, Q. et al. Reactive halogens increase the global methane lifetime and radiative forcing in the 21st century. Nat. Commun. 13, 2768 (2022). · DOI
- Fernandez, R. P., Kinnison, D. E., Lamarque, J. F., Tilmes, S. & Saiz-Lopez, A. Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century. Atmos. Chem. Phys. 17, 1673–1688 (2017). · DOI
- Sherwen, T., Evans, M. J., Carpenter, L. J., Schmidt, J. A. & Mickley, L. J. Halogen chemistry reduces tropospheric O3 radiative forcing. Atmos. Chem. Phys. 17, 1557–1569 (2017). · DOI
- Li, Q. et al. Halogens enhance haze pollution in China. Environ. Sci. Technol. 55, 13625–13637 (2021). · DOI
- Baccarini, A. et al. Frequent new particle formation over the high Arctic pack ice by enhanced iodine emissions. Nat. Commun. 11, 4924 (2020). · DOI
- Hoffmann, E. H., Tilgner, A., Vogelsberg, U., Wolke, R. & Herrmann, H. Near-explicit multiphase modeling of halogen chemistry in a mixed urban and maritime coastal area. ACS Earth Space Chem. 3, 2452–2471 (2019). · DOI
- Cuevas, C. A. et al. The influence of iodine on the Antarctic stratospheric ozone hole. Proc. Natl Acad. Sci. USA 119, e2110864119 (2022). · DOI
- Cohen, J. et al. Recent Arctic amplification and extreme mid-latitude weather. Nat. Geosci. 7, 627–637 (2014). · DOI
- Lannuzel, D. et al. The future of Arctic sea-ice biogeochemistry and ice-associated ecosystems. Nat. Clim. Change 10, 983–992 (2020). · DOI
- Carpenter, L. J. et al. Atmospheric iodine levels influenced by sea surface emissions of inorganic iodine. Nat. Geosci. 6, 108–111 (2013). · DOI
- Kok, J. F. et al. Mineral dust aerosol impacts on global climate and climate change. Nat. Rev. Earth Environ. https://doi.org/10.1038/s43017-022-00379-5 (2023). · DOI
- Tilmes, S. et al. Representation of the Community Earth System Model (CESM1) CAM4-chem within the Chemistry–Climate Model Initiative (CCMI). Geosci. Model Dev. 9, 1853–1890 (2016). · DOI
- Lamarque, J.-F. et al. CAM-chem: description and evaluation of interactive atmospheric chemistry in the Community Earth System Model. Geosci. Model Dev. 5, 369–411 (2012). · DOI
- Neale, R. B. et al. The mean climate of the Community Atmosphere Model (CAM4) in forced SST and fully coupled experiments. J. Clim. 26, 5150–5168 (2013). · DOI
- Tilmes, S. et al. Description and evaluation of tropospheric chemistry and aerosols in the Community Earth System Model (CESM1.2). Geosci. Model Dev. 8, 1395–1426 (2015). · DOI
- Fernandez, R. P., Salawitch, R. J., Kinnison, D. E., Lamarque, J.-F. & Saiz-Lopez, A. Bromine partitioning in the tropical tropopause layer: implications for stratospheric injection. Atmos. Chem. Phys. 14, 13391–13410 (2014). · DOI
- Saiz-Lopez, A. et al. Injection of iodine to the stratosphere. Geophys. Res. Lett. 42, 6852–6859 (2015). · DOI
- Fernandez, R. P. et al. Modeling the sources and chemistry of polar tropospheric halogens (Cl, Br, and I) using the CAM-Chem global chemistry–climate model. J. Adv. Model. Earth Syst. 11, 2259–2289 (2019). · DOI
- Mahmud, A. & Barsanti, K. Improving the representation of secondary organic aerosol (SOA) in the MOZART-4 global chemical transport model. Geosci. Model Dev. 6, 961–980 (2013). · DOI
- Chen, Q., Sherwen, T., Evans, M. & Alexander, B. DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry. Atmos. Chem. Phys. 18, 13617–13637 (2018). · DOI
- Liu, T. & Abbatt, J. P. D. An experimental assessment of the importance of S(IV) oxidation by hypohalous acids in the marine atmosphere. Geophys. Res. Lett. 47, e2019GL086465 (2020). · DOI
- Abbatt, J. P. D., Lee, A. K. Y. & Thornton, J. A. Quantifying trace gas uptake to tropospheric aerosol: recent advances and remaining challenges. Chem. Soc. Rev. 41, 6555–6581 (2012). · DOI
- Mahajan, A. S. et al. Measurement and modelling of tropospheric reactive halogen species over the tropical Atlantic Ocean. Atmos. Chem. Phys. 10, 4611–4624 (2010). · DOI
- Badia, A. et al. The role of natural halogens in global tropospheric ozone chemistry and budget under different 21st century climate scenarios. J. Geophys. Res. Atmos. 126, e2021JD034859 (2021). · DOI · Paper page
- Hossaini, R. et al. A global model of tropospheric chlorine chemistry: organic versus inorganic sources and impact on methane oxidation. J. Geophys. Res. 121, 14271–14297 (2016). · DOI
- Wang, X. et al. The role of chlorine in global tropospheric chemistry. Atmos. Chem. Phys. 19, 3981–4003 (2019). · DOI
- Keene, W. C. et al. Composite global emissions of reactive chlorine from anthropogenic and natural sources: reactive chlorine emissions inventory. J. Geophys. Res. Atmos. 104, 8429–8440 (1999). · DOI
- MacDonald, S. M. et al. A laboratory characterisation of inorganic iodine emissions from the sea surface: dependence on oceanic variables and parameterisation for global modelling. Atmos. Chem. Phys. 14, 5841–5852 (2014). · DOI
- Claxton, T. et al. A synthesis inversion to constrain global emissions of two very short lived chlorocarbons: dichloromethane, and perchloroethylene. J. Geophys. Res. Atmos. 125, e2019JD031818 (2020). · DOI
- Hossaini, R. et al. Recent trends in stratospheric chlorine from very short-lived substances. J. Geophys. Res. Atmos. 124, 2318–2335 (2019). · DOI
- Hegglin, M. I. et al. IGAC/SPARC Chemistry–Climate Model Initiative (CCMI) 2014 Science Workshop. SPARC Newsl. 43, 32–35 (2014).
- Granier, C. et al. Evolution of anthropogenic and biomass burning emissions of air pollutants at global and regional scales during the 1980–2010 period. Climatic Change 109, 163 (2011). · DOI
- Guenther, A. B. et al. The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions. Geosci. Model Dev. 5, 1471–1492 (2012). · DOI
- Meinshausen, M. et al. The RCP greenhouse gas concentrations and their extensions from 1765 to 2300. Climatic Change 109, 213 (2011). · DOI
- van Vuuren, D. P. et al. The representative concentration pathways: an overview. Climatic Change 109, 5 (2011). · DOI · Paper page
- Barrera, J. A. et al. Seasonal impact of biogenic very short-lived bromocarbons on lowermost stratospheric ozone between 60°N and 60°S during the 21st century. Atmos. Chem. Phys. 20, 8083–8102 (2020). · DOI
- Iacono, M. J. et al. Radiative forcing by long-lived greenhouse gases: calculations with the AER radiative transfer models. J. Geophys. Res. Atmos. 113, D13103 (2008). · DOI
- Danabasoglu, G. et al. The Community Earth System Model Version 2 (CESM2). J. Adv. Model. Earth Syst. 12, e2019MS001916 (2020). · DOI
- Lacis, A. A., Hansen, J. E., Russell, G. L., Oinas, V. & Jonas, J. The role of long-lived greenhouse gases as principal LW control knob that governs the global surface temperature for past and future climate change. Tellus B 65, 19734 (2013). · DOI
- Wild, M. The global energy balance as represented in CMIP6 climate models. Clim. Dyn. 55, 553–577 (2020). · DOI
- Schmidt, G. A., Ruedy, R. A., Miller, R. L. & Lacis, A. A. Attribution of the present-day total greenhouse effect. J. Geophys. Res. Atmos. 115, D20106 (2010). · DOI
- Fu, X. et al. Anthropogenic emissions of hydrogen chloride and fine particulate chloride in China. Environ. Sci. Technol. 52, 1644–1654 (2018). · DOI
- Vassilev, S. V., Eskenazy, G. M. & Vassileva, C. G. Contents, modes of occurrence and behaviour of chlorine and bromine in combustion wastes from coal-fired power stations. Fuel 79, 923–938 (2000). · DOI
- Yudovich, Y. E. & Ketris, M. P. Chlorine in coal: a review. Int. J. Coal Geol. 67, 127–144 (2006). · DOI
- Ma, Q. et al. Impacts of coal burning on ambient PM2.5 pollution in China. Atmos. Chem. Phys. 17, 4477–4491 (2017). · DOI
- Wang, S. X. et al. Emission trends and mitigation options for air pollutants in East Asia. Atmos. Chem. Phys. 14, 6571–6603 (2014). · DOI
- Zhao, B. et al. Impact of national NOx and SO2 control policies on particulate matter pollution in China. Atmos. Environ. 77, 453–463 (2013). · DOI
- Jin, Y., Tao, L., Chi, Y. & Yan, J. Conversion of bromine during thermal decomposition of printed circuit boards at high temperature. J. Hazard. Mater. 186, 707–712 (2011). · DOI
- Peng, B.-X., Li, L. & Wu, D.-S. Distribution of bromine and iodine in thermal power plant. J. Coal Sci. Eng. 19, 387–391 (2013). · DOI
- Li, Q. et al. Potential effect of halogens on atmospheric oxidation and air quality in China. J. Geophys. Res. Atmos. 125, e2019JD032058 (2020). · DOI
- Fernandez, R. P. et al. Intercomparison between surrogate, explicit, and full treatments of VSL bromine chemistry within the CAM-Chem chemistry–climate model. Geophys. Res. Lett. 48, e2020GL091125 (2021). · DOI
- Riese, M. et al. Impact of uncertainties in atmospheric mixing on simulated UTLS composition and related radiative effects. J. Geophys. Res. Atmos. 117, D16305 (2012). · DOI
- Wu, Y. & Polvani, L. M. Recent trends in extreme precipitation and temperature over southeastern South America: the dominant role of stratospheric ozone depletion in the CESM large ensemble. J. Clim. 30, 6433–6441 (2017). · DOI
- Saiz-Lopez, A. & Fernandez, R. P. On the formation of tropical rings of atomic halogens: causes and implications. Geophys. Res. Lett. 43, 2928–2935 (2016). · DOI
- Frith, S. M. et al. Recent changes in total column ozone based on the SBUV Version 8.6 merged ozone data set. J. Geophys. Res. Atmos. 119, 9735–9751 (2014). · DOI
- Frith, S. M., Stolarski, R. S., Kramarova, N. A. & McPeters, R. D. Estimating uncertainties in the SBUV version 8.6 merged profile ozone data set. Atmos. Chem. Phys. 17, 14695–14707 (2017). · DOI
- Li, Q. et al. Role of iodine recycling on sea-salt aerosols in the global marine boundary layer. Geophys. Res. Lett. 49, e2021GL097567 (2022). · DOI
- Etminan, M., Myhre, G., Highwood, E. J. & Shine, K. P. Radiative forcing of carbon dioxide, methane, and nitrous oxide: a significant revision of the methane radiative forcing. Geophys. Res. Lett. 43, 12,612–614,623 (2016). · DOI · Paper page
- Etheridge, D. M., Steele, L. P., Francey, R. J. & Langenfelds, R. L. Atmospheric methane between 1000 A.D. and present: evidence of anthropogenic emissions and climatic variability. J. Geophys. Res. Atmos. 103, 15979–15993 (1998). · DOI
- Mickley, L. J., Jacob, D. J. & Rind, D. Uncertainty in preindustrial abundance of tropospheric ozone: implications for radiative forcing calculations. J. Geophys. Res. Atmos. 106, 3389–3399 (2001). · DOI
- Lan, X., Thoning, K. W. & Dlugokencky, E. J. Trends in globally-averaged CH4, N2O, and SF6 determined from NOAA Global Monitoring Laboratory measurements. Version 2022-12. Global Monitoring Laboratory https://doi.org/10.15138/P8XG-AA10 (2022). · DOI
- Gaudel, A. et al. Tropospheric Ozone Assessment Report: present-day distribution and trends of tropospheric ozone relevant to climate and global atmospheric chemistry model evaluation. Elem. Sci. Anthr. 6, 39 (2018). · DOI
- Lamarque, J.-F. et al. The Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP): overview and description of models, simulations and climate diagnostics. Geosci. Model Dev. 6, 179–206 (2013). · DOI
- Graedel, T. E. & Keene, W. C. Tropospheric budget of reactive chlorine. Glob. Biogeochem. Cycles 9, 47–77 (1995). · DOI
- Parrella, J. P. et al. Tropospheric bromine chemistry: implications for present and pre-industrial ozone and mercury. Atmos. Chem. Phys. 12, 6723–6740 (2012). · DOI
- Schmidt, J. A. et al. Modeling the observed tropospheric BrO background: importance of multiphase chemistry and implications for ozone, OH, and mercury. J. Geophys. Res. 121, 11819–11835 (2016). · DOI
- Yang, X. et al. Tropospheric bromine chemistry and its impacts on ozone: a model study. J. Geophys. Res. Atmos. 110, D23311 (2005). · DOI
- Koenig, T. K. et al. BrO and inferred Bry profiles over the western Pacific: relevance of inorganic bromine sources and a Bry minimum in the aged tropical tropopause layer. Atmos. Chem. Phys. 17, 15245–15270 (2017). · DOI
- Karagodin-Doyennel, A. et al. Iodine chemistry in the chemistry–climate model SOCOL-AERv2-I. Geosci. Model Dev. 14, 6623–6645 (2021). · DOI
- Claxton, T., Hossaini, R., Wild, O., Chipperfield, M. P. & Wilson, C. On the regional and seasonal ozone depletion potential of chlorinated very short-lived substances. Geophys. Res. Lett. 46, 5489–5498 (2019). · DOI
Cited by
Sorted by citations
Neale, P. J., Hylander, S., Banaszak, A. T., Häder, D.-P., Rose, K. C., Vione, D., Wängberg, S.-Å., Jansen, M. A. K., Busquets, R., Andersen, M. P. S., et al. (2025) · Photochemical & Photobiological Sciences · doi:10.1007/s43630-025-00687-x · Cited by 32
“5, respectively [81].”
Influential
Metadata
- Authors
- Saiz-Lopez, A., Fernandez, R. P., Li, Q., Cuevas, C. A., Fu, X., Kinnison, D. E., Tilmes, S., Mahajan, A. S., Gómez Martín, J. C., Iglesias-Suarez, F., Hossaini, R., Plane, J. M. C., Myhre, G., & Lamarque, J.-F.
- Affiliations
- Hong Kong Polytechnic University (HK)
- Instituto de Química Física Blas Cabrera (ES)
- Tsinghua Shenzhen International Graduate School (CN)
- NSF National Center for Atmospheric Research (US)
- Indian Institute of Tropical Meteorology (IN)
- Lancaster University (GB)
- University of Leeds (GB)
- CICERO Center for International Climate Research (NO)
- ORCID
- Venue
- Nature
- Published
- 2023-06-28
- Volume
- 618
- Issue
- 7967
- Pages
- 967-973
- ISSN
- 0028-0836 (ISSN-L)
- 1476-4687
- PMC
- PMC10307623
- OpenAlex
- W4382358386
- Cited by
- 91
- References
- 3
- Citations by year
- 2026: 24 · 2025: 27 · 2024: 35 · 2023: 5
- FWCI
- 10.05
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Nature (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- White Rose Research Online (University of Leeds, The University of Sheffield, University of York) (acceptedVersion)
- elib (German Aerospace Center) (submittedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (submittedVersion, cc-by)
- Lancaster EPrints (Lancaster University) (submittedVersion)
- PolyU Institutional Research Archive (Hong Kong Polytechnic University) (submittedVersion, cc-by)
- NORA - Norwegian Open Research Archives (submittedVersion, cc-by)
- Funders
- Natural Environment Research Council (NE/N014375/1)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric Ozone and Climate
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric aerosols and clouds
- Keywords
- indirect radiative effect, ozone depletion, methane, aerosols, stratospheric water vapor, radiation balance, climate change projections
- MeSH terms
- Climate Models, Atmosphere, Climate, Cold Temperature, Halogens, Human Activities, Hydrocarbons, Halogenated, Oceans and Seas, Seawater, Climate Change
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review