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Ultrafine Sulfur Nanoparticles in Conducting Polymer Shell as Cathode Materials for High Performance Lithium/Sulfur Batteries
Open accessAbstract
We report the synthesis of ultrafine S nanoparticles with diameter 10 ~ 20 nm via a membrane-assisted precipitation technique. The S nanoparticles were then coated with conducting poly (3,4-ethylenedioxythiophene) (PEDOT) to form S/PEDOT core/shell nanoparticles. The ultrasmall size of S nanoparticles facilitates the electrical conduction and improves sulfur utilization. The encapsulation of conducting PEDOT shell restricts the polysulfides diffusion, alleviates self-discharging and the shuttle effect, and thus enhances the cycling stability. The resulting S/PEDOT core/shell nanoparticles show initial discharge capacity of 1117 mAh g(-1) and a stable capacity of 930 mAh g(-1) after 50 cycles.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Cited by
Rechargeable Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., Chung, S.-H., Zu, C., & Su, Y.-S. (2014) · Chemical Reviews · doi:10.1021/cr500062v · Cited by 4,665
Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries
Peng, H., Huang, J., Cheng, X., & Zhang, Q. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700260 · Cited by 1,746
Li, W., Zhang, Q., Zheng, G., Seh, Z. W., Yao, H., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl403130h · Cited by 654
Current Status and Future Prospects of Metal–Sulfur Batteries
Chung, S., & Manthiram, A. (2019) · Advanced Materials · doi:10.1002/adma.201901125 · Cited by 622
A Comprehensive Understanding of Lithium–Sulfur Battery Technology
Li, T., Bai, X., Gulzar, U., Bai, Y., Capiglia, C., Deng, W., Zhou, X., Liu, Z., Feng, Z., & Proietti Zaccaria, R. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201901730 · Cited by 422
Metadata
- Authors
- Chen, H., Dong, W., Ge, J., Wang, C., Wu, X., Lu, W., & Chen, L.
- Venue
- Scientific Reports
- Published
- 2013-05-29
- Volume
- 3
- Issue
- 1
- Pages
- 1910-1910
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2132172114
- Cited by
- 233
- References
- 1
- FWCI
- 17.97
- Type
- journal article
- Language
- en
- Open access
- gold
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.