The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Rice husks as a sustainable source of nanostructured silicon for high performance Li-ion battery anodes
Open accessAbstract
The recovery of useful materials from earth-abundant substances is of strategic importance for industrial processes. Despite the fact that Si is the second most abundant element in the Earth's crust, processes to form Si nanomaterials is usually complex, costly and energy-intensive. Here we show that pure Si nanoparticles (SiNPs) can be derived directly from rice husks (RHs), an abundant agricultural byproduct produced at a rate of 1.2 × 10(8) tons/year, with a conversion yield as high as 5% by mass. And owing to their small size (10-40 nm) and porous nature, these recovered SiNPs exhibits high performance as Li-ion battery anodes, with high reversible capacity (2,790 mA h g(-1), seven times greater than graphite anodes) and long cycle life (86% capacity retention over 300 cycles). Using RHs as the raw material source, overall energy-efficient, green, and large scale synthesis of low-cost and functional Si nanomaterials is possible.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
High-performance lithium battery anodes using silicon nanowires
Chan, C. K., Peng, H., Liu, G., McIlwrath, K., Zhang, X. F., Huggins, R. A., & Cui, Y. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2007.411 · Cited by 6,683
Self-citationA Laser Ablation Method for the Synthesis of Crystalline Semiconductor Nanowires
Morales, A. M., & Lieber, C. M. (1998) · Science · doi:10.1126/science.279.5348.208 · Cited by 4,383
Enhanced thermoelectric performance of rough silicon nanowires
Hochbaum, A. I., Chen, R., Delgado, R. D., Liang, W., Garnett, E. C., Najarian, M., Majumdar, A., & Yang, P. (2008) · Nature · doi:10.1038/nature06381 · Cited by 4,109
Functional Nanoscale Electronic Devices Assembled Using Silicon Nanowire Building Blocks
Cui, Y., & Lieber, C. M. (2001) · Science · doi:10.1126/science.291.5505.851 · Cited by 3,258
Self-citationCoaxial silicon nanowires as solar cells and nanoelectronic power sources
Tian, B., Zheng, X., Kempa, T. J., Fang, Y., Yu, N., Yu, G., Huang, J., & Lieber, C. M. (2007) · Nature · doi:10.1038/nature06181 · Cited by 2,929
Silicon nanowires as efficient thermoelectric materials
Boukai, A. I., Bunimovich, Y., Tahir-Kheli, J., Yu, J.-K., Goddard III, W. A., & Heath, J. R. (2008) · Nature · doi:10.1038/nature06458 · Cited by 2,729
Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
Kasavajjula, U., Wang, C., & Appleby, A. J. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.09.084 · Cited by 2,491
Wu, H., Chan, G., Choi, J. W., Ryu, I., Yao, Y., McDowell, M. T., Lee, S. W., Jackson, A., Yang, Y., Hu, L., et al. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.35 · Cited by 2,478
Self-citationSize-Dependent Fracture of Silicon Nanoparticles During Lithiation
Liu, X. H., Zhong, L., Huang, S., Mao, S. X., Zhu, T., & Huang, J. Y. (2012) · ACS Nano · doi:10.1021/nn204476h · Cited by 2,376
Designing nanostructured Si anodes for high energy lithium ion batteries
Wu, H., & Cui, Y. (2012) · Nano Today · doi:10.1016/j.nantod.2012.08.004 · Cited by 2,350
Self-citationOptical gain in silicon nanocrystals
Pavesi, L., Dal Negro, L., Mazzoleni, C., Franzò, G., & Priolo, F. (2000) · Nature · doi:10.1038/35044012 · Cited by 2,315
Valorization of Biomass: Deriving More Value from Waste
Tuck, C. O., Pérez, E., Horváth, I. T., Sheldon, R. A., & Poliakoff, M. (2012) · Science · doi:10.1126/science.1218930 · Cited by 2,165
High-performance lithium-ion anodes using a hierarchical bottom-up approach
Magasinski, A., Dixon, P., Hertzberg, B., Kvit, A., Ayala, J., & Yushin, G. (2010) · Nature Materials · doi:10.1038/nmat2725 · Cited by 2,044
Biodegradable luminescent porous silicon nanoparticles for in vivo applications
Park, J.-H., Gu, L., von Maltzahn, G., Ruoslahti, E., Bhatia, S. N., & Sailor, M. J. (2009) · Nature Materials · doi:10.1038/nmat2398 · Cited by 1,897
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
Liu, N., Wu, H., McDowell, M. T., Yao, Y., Wang, C., & Cui, Y. (2012) · Nano Letters · doi:10.1021/nl3014814 · Cited by 1,842
Self-citationA Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
Kovalenko, I., Zdyrko, B., Magasinski, A., Hertzberg, B., Milicev, Z., Burtovyy, R., Luzinov, I., & Yushin, G. (2011) · Science · doi:10.1126/science.1209150 · Cited by 1,802
Ma, J. F., Tamai, K., Yamaji, N., Mitani, N., Konishi, S., Katsuhara, M., Ishiguro, M., Murata, Y., & Yano, M. (2006) · Nature · doi:10.1038/nature04590 · Cited by 1,644
A map of rice genome variation reveals the origin of cultivated rice
Huang, X., Kurata, N., Wei, X., Wang, Z.-X., Wang, A., Zhao, Q., Zhao, Y., Liu, K., Lu, H., Li, W., et al. (2012) · Nature · doi:10.1038/nature11532 · Cited by 1,634
SEMICONDUCTOR NANOWIRES AND NANOTUBES
Law, M., Goldberger, J., & Yang, P. (2004) · Annual Review of Materials Research · doi:10.1146/annurev.matsci.34.040203.112300 · Cited by 1,369
Size Dependent Fracture of Silicon Nanoparticles during Lithiation.
Huang, J., Liu, X., Zhong, L. S., Huang, S., Mao, S. X., & Zhu, T. (2011) · Nano Letters · Cited by 1,316
A Porous Silicon-Based Optical Interferometric Biosensor
Lin, V. S.-Y., Motesharei, K., Dancil, K.-P. S., Sailor, M. J., & Ghadiri, M. R. (1997) · Science · doi:10.1126/science.278.5339.840 · Cited by 1,299
Reversible Cycling of Crystalline Silicon Powder
Obrovac, M. N., & Krause, L. J. (2007) · Journal of The Electrochemical Society · doi:10.1149/1.2402112 · Cited by 1,259
Diameter-controlled synthesis of single-crystal silicon nanowires
Cui, Y., Lauhon, L. J., Gudiksen, M. S., Wang, J., & Lieber, C. M. (2001) · Applied Physics Letters · doi:10.1063/1.1363692 · Cited by 1,156
Self-citationIn Situ XRD and Electrochemical Study of the Reaction of Lithium with Amorphous Silicon
Hatchard, T. D., & Dahn, J. R. (2004) · Journal of The Electrochemical Society · doi:10.1149/1.1739217 · Cited by 1,113
Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid
Magasinski, A., Zdyrko, B., Kovalenko, I., Hertzberg, B., Burtovyy, R., Huebner, C. F., Fuller, T. F., Luzinov, I., & Yushin, G. (2010) · ACS Applied Materials & Interfaces · doi:10.1021/am100871y · Cited by 1,101
Three-Dimensional, Flexible Nanoscale Field-Effect Transistors as Localized Bioprobes
Tian, B., Cohen-Karni, T., Qing, Q., Duan, X., Xie, P., & Lieber, C. M. (2010) · Science · doi:10.1126/science.1192033 · Cited by 798
Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas
Bao, Z., Weatherspoon, M. R., Shian, S., Cai, Y., Graham, P. D., Allan, S. M., Ahmad, G., Dickerson, M. B., Church, B. C., Kang, Z., et al. (2007) · Nature · doi:10.1038/nature05570 · Cited by 796
Silica in Plants: Biological, Biochemical and Chemical Studies
Currie, H. A., & Perry, C. C. (2007) · Annals of Botany · doi:10.1093/aob/mcm247 · Cited by 717
Reversible Storage of Lithium in Silver‐Coated Three‐Dimensional Macroporous Silicon
Yu, Y., Gu, L., Zhu, C., Tsukimoto, S., van Aken, P. A., & Maier, J. (2010) · Advanced Materials · doi:10.1002/adma.200903755 · Cited by 592
Prelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries
Liu, N., Hu, L., McDowell, M. T., Jackson, A., & Cui, Y. (2011) · ACS Nano · doi:10.1021/nn2017167 · Cited by 578
Self-citationPolymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes
Liu, G., Xun, S., Vukmirovic, N., Song, X., Olalde‐Velasco, P., Zheng, H., Battaglia, V. S., Wang, L., & Yang, W. (2011) · Advanced Materials · doi:10.1002/adma.201102421 · Cited by 576
Molecular evidence for a single evolutionary origin of domesticated rice
Molina, J., Sikora, M., Garud, N., Flowers, J. M., Rubinstein, S., Reynolds, A., Huang, P., Jackson, S., Schaal, B. A., Bustamante, C. D., et al. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1104686108 · Cited by 516
Fracture of crystalline silicon nanopillars during electrochemical lithium insertion
Lee, S. W., McDowell, M. T., Berla, L. A., Nix, W. D., & Cui, Y. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1201088109 · Cited by 432
Self-citationSilicon-Based Materials from Rice Husks and Their Applications
Sun, L., & Gong, K. (2001) · Industrial & Engineering Chemistry Research · doi:10.1021/ie010284b · Cited by 410
Novel Three‐Dimensional Mesoporous Silicon for High Power Lithium‐Ion Battery Anode Material
Jia, H., Gao, P., Yang, J., Wang, J., Nuli, Y., & Yang, Z. (2011) · Advanced Energy Materials · doi:10.1002/aenm.201100485 · Cited by 408
Gu, M., Li, Y., Li, X., Hu, S., Zhang, X., Xu, W., Thevuthasan, S., Baer, D. R., Zhang, J.-G., Liu, J., et al. (2012) · ACS Nano · doi:10.1021/nn303312m · Cited by 361
Time-resolved imaging of gas phase nanoparticle synthesis by laser ablation
Geohegan, D. B., Puretzky, A. A., Duscher, G., & Pennycook, S. J. (1998) · Applied Physics Letters · doi:10.1063/1.121516 · Cited by 340
Reversible Lithium‐Ion Storage in Silver‐Treated Nanoscale Hollow Porous Silicon Particles
Chen, D., Xiao, M., Ji, G., Lu, M., Xie, J., Lu, J., & Lee, J. Y. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107885 · Cited by 332
Shackley, S., Carter, S., Knowles, T., Middelink, E., Haefele, S., Sohi, S., Cross, A., & Haszeldine, S. (2012) · Energy Policy · doi:10.1016/j.enpol.2011.11.026 · Cited by 243
Silica Nanoparticles and Frameworks from Rice Husk Biomass
Wang, W., Martin, J. C., Fan, X., Han, A., Luo, Z., & Sun, L. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am201619u · Cited by 233
Reversible Lithium‐Ion Storage in Silver‐Treated Nanoscale Hollow Porous Silicon Particles
Chen, D., Xiao, M., Ji, G., Lu, M., Xie, J., Lu, J., & Lee, J. Y. (2012) · Angewandte Chemie · doi:10.1002/ange.201107885 · Cited by 125
Harvesting silica nanoparticles from rice husks
Wang, W., Martin, J. C., Zhang, N., Ma, C., Han, A., & Sun, L. (2011) · Journal of Nanoparticle Research · doi:10.1007/s11051-011-0609-3 · Cited by 123
Thermodynamics of the Si-C-O system for the production of silicon carbide and metallic silicon
Nagamori, M., Malinsky, I., & Claveau, A. (1986) · Metallurgical Transactions B · doi:10.1007/bf02670216 · Cited by 113
Hierarchical porous carbon from cell assemblies of rice husk for in vivo applications
Tabata, S., Iida, H., Horie, T., & Yamada, S. (2010) · MedChemComm · doi:10.1039/c0md00011f · Cited by 45
Cited by
Nanotechnology in agri-food production: an overview
Sekhon, B. (2014) · Nanotechnology, Science and Applications · doi:10.2147/nsa.s39406 · Cited by 1,073
Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors
Ding, J., Wang, H., Li, Z., Cui, K., Karpuzov, D., Tan, X., Kohandehghan, A., & Mitlin, D. (2015) · Energy & Environmental Science · doi:10.1039/c4ee02986k · Cited by 818
Biomass-derived porous carbon materials with sulfur and nitrogen dual-doping for energy storage
Xu, G., Han, J., Ding, B., Nie, P., Pan, J., Dou, H., Li, H., & Zhang, X. (2015) · Green Chemistry · doi:10.1039/c4gc02185a · Cited by 649
Exploitation of Food Industry Waste for High-Value Products
Ravindran, R., & Jaiswal, A. K. (2016) · Trends in Biotechnology · doi:10.1016/j.tibtech.2015.10.008 · Cited by 590
Surface and Interface Engineering of Silicon‐Based Anode Materials for Lithium‐Ion Batteries
Luo, W., Chen, X., Xia, Y., Chen, M., Wang, L., Wang, Q., Li, W., & Yang, J. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201701083 · Cited by 549
Metadata
- Authors
- Liu, N., Huo, K., McDowell, M. T., Zhao, J., & Cui, Y.
- Venue
- Scientific Reports
- Published
- 2013-05-29
- Volume
- 3
- Issue
- 1
- Pages
- 1919-1919
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2135410019
- Cited by
- 538
- References
- 44
- FWCI
- 28.76
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
