Controlled Growth of Platinum Nanowire Arrays on Sulfur Doped Graphene as High Performance Electrocatalyst
Open accessAbstract
Graphene supported Pt nanostructures have great potential to be used as catalysts in electrochemical energy conversion and storage technologies; however the simultaneous control of Pt morphology and dispersion, along with ideally tailoring the physical properties of the catalyst support properties has proven very challenging. Using sulfur doped graphene (SG) as a support material, the heterogeneous dopant atoms could serve as nucleation sites allowing for the preparation of SG supported Pt nanowire arrays with ultra-thin diameters (2-5 nm) and dense surface coverage. Detailed investigation of the preparation technique reveals that the structure of the resulting composite could be readily controlled by fine tuning the Pt nanowire nucleation and growth reaction kinetics and the Pt-support interactions, whereby a mechanistic platinum nanowire array growth model is proposed. Electrochemical characterization demonstrates that the composite materials have 2-3 times higher catalytic activities toward the oxygen reduction and methanol oxidation reaction compared with commercial Pt/C catalyst.
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Strong Pt-S interaction is essential to contribute to uniform nucleation of Pt on sulphur doped graphene, whereas non-uniform nucleation was observed on pristine graphene supports.
“The strong Pt-S interaction is essential to contribute to the uniform nucleation of Pt on SG, whereas non-uniform nucleation was observed on pristine graphene supports.”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [125]
The Results report uniform Pt nanowire arrays on sulfur-doped graphene and non-uniform growth on pristine graphene under dilute conditions, attributing the difference most likely to stronger SG–Pt interactions. But the Results also report uniform nucleation on pristine graphene at higher reactant concentrations. The claim omits that condition and calls the interaction essential, whereas the paper offers it as a likely explanation. (LLM, conf=0.90)
Experimental — accuracy not yet measuredSG composite materials have 2-3 times higher catalytic activities toward ORR compared with the commercial Pt/C catalyst.
“Electrochemical characterization shows that the SG composite materials have 2-3 times higher catalytic activities toward ORR compared with the commercial Pt/C catalyst.125”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [125]
The Discussion reports that SG-PtNW-3 had twice the ECSA-specific ORR kinetic current density of commercial Pt/C at 0.9 V, but does not establish a general 2–3-fold ORR advantage. Its approximately threefold comparison concerns methanol oxidation (MOR), not ORR. (LLM, conf=0.88)
Experimental — accuracy not yet measuredThe structure of the resulting SG composite could be readily controlled by fine tuning the Pt nanowire nucleation and growth reaction kinetics in addition to the Pt-support interactions.
“They revealed that the structure of the resulting composite could be readily controlled by ne tuning the Pt nanowire nucleation and growth reaction kinetics in addition to the Ptsupport interactions.118,125”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [125]
SG supported Pt nanowire arrays were manufactured with diameters of 2-5 nm and dense surface coverage.
“Using SG as a support material, where the heterogeneous dopant atoms could serve as nucleation sites, SG supported Pt nanowire arrays were manufactured with diameters of 2-5 nm and dense surface coverage.”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [125]
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- Authors
- Wang, R., Higgins, D. C., Hoque, M. A., Lee, D., Hassan, F., & Chen, Z.
- Affiliations
- University of Waterloo (CA)
- Corresponding author
- Chen, Zhongwei
- Venue
- Scientific Reports
- Published
- 2013-08-14
- Volume
- 3
- Issue
- 1
- Pages
- 2431-2431
- ISSN
- 2045-2322 (ISSN-L)
- PMC
- PMC3743054
- OpenAlex
- W2059175667
- Cited by
- 82
- References
- 42
- Citations by year
- 2025: 2 · 2024: 2 · 2023: 2 · 2022: 2 · 2021: 6 · 2020: 4 · 2019: 7 · 2018: 10 · 2017: 8 · 2016: 14 · 2015: 13 · 2014: 11 · 2013: 1
- FWCI
- 4.73
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Scientific Reports (publishedVersion, cc-by-nc-nd)
- Europe PMC (PubMed Central) (publishedVersion, cc-by-nc-nd)
- PubMed Central (publishedVersion, cc-by-nc-nd)
- PubMed (publishedVersion)
- Funders
- University of Waterloo
- Natural Sciences and Engineering Research Council of Canada
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Keywords
- sulfur-doped graphene, nucleation sites, nanowire growth mechanism, Pt-support interaction, oxygen reduction reaction, methanol oxidation, electrocatalysts, electrochemical energy conversion
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