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The combustion behavior of large scale lithium titanate battery

Open access
Huang, Peifeng, Wang, Qingsong, Li, Ke, Ping, Ping, Sun, Jinhua·2015·Scientific Reports

Abstract

Safety problem is always a big obstacle for lithium battery marching to large scale application. However, the knowledge on the battery combustion behavior is limited. To investigate the combustion behavior of large scale lithium battery, three 50 Ah Li(Ni(x)Co(y)Mn(z))O2/Li(4)Ti(5)O(12) batteries under different state of charge (SOC) were heated to fire. The flame size variation is depicted to analyze the combustion behavior directly. The mass loss rate, temperature and heat release rate are used to analyze the combustion behavior in reaction way deeply. Based on the phenomenon, the combustion process is divided into three basic stages, even more complicated at higher SOC with sudden smoke flow ejected. The reason is that a phase change occurs in Li(Ni(x)Co(y)Mn(z))O2 material from layer structure to spinel structure. The critical temperatures of ignition are at 112-121 °C on anode tab and 139 to 147 °C on upper surface for all cells. But the heating time and combustion time become shorter with the ascending of SOC. The results indicate that the battery fire hazard increases with the SOC. It is analyzed that the internal short and the Li(+) distribution are the main causes that lead to the difference.

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Metadata

Authors
Huang, P., Wang, Q., Li, K., Ping, P., & Sun, J.
Venue
Scientific Reports
Published
2015-01-14
Volume
5
Issue
1
Pages
7788-7788
ISSN
2045-2322 (ISSN-L)
OpenAlex
W2050301042
Cited by
182
References
1
FWCI
10.93
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: The combustion behavior of large scale lithium titanate battery. https://app.cochat.ai/papers/10.1038/srep07788
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Huang, P., Wang, Q., Li, K., Ping, P., & Sun, J. (2015). The combustion behavior of large scale lithium titanate battery. Scientific Reports. https://doi.org/10.1038/srep07788

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