Cited by 122Carbon dioxide utilization in catalysisbiodegradable polymer synthesis and propertiesCarbon Dioxide Capture Technologies

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Direct Copolymerization of CO2 and Diols

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Tamura, Masazumi, Ito, Kazuki, Honda, Masayoshi, Nakagawa, Yoshinao, Sugimoto, Hiroshi, Tomishige, Keiichi·2016·Scientific Reports

DOI 10.1038/srep24038PMC PMC4831014

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Abstract

Direct polymerization of CO 2 and diols is promising as a simple and environmental-benign method in place of conventional processes using high-cost and/or hazardous reagents such as phosgene, carbon monoxide and epoxides, however, there are no reports on the direct method due to the inertness of CO 2 and severe equilibrium limitation of the reaction. Herein, we firstly substantiate the direct copolymerization of CO 2 and diols using CeO 2 catalyst and 2-cyanopyridine promotor, providing the alternating cooligomers in high diol-based yield (up to 99%) and selectivity (up to >99%). This catalyst system is applicable to various diols including linear C4-C10 α,ω-diols to provide high yields of the corresponding cooligomers, which cannot be obtained by well-known methods such as copolymerization of CO 2 and cyclic ethers and ring-opening polymerization of cyclic carbonates. This process provides us a facile synthesis method for versatile polycarbonates from various diols and CO 2 owing to simplicity of diols modification.

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Authors: Tamura, M., Ito, K., Honda, M., Nakagawa, Y., Sugimoto, H., & Tomishige, K.
Affiliations: Tohoku University (JP)
Tokyo University of Science (JP)
Corresponding author: Tamura, Masazumi
Tomishige, Keiichi
ORCID: Tamura, Masazumi
Ito, Kazuki
Honda, Masayoshi
Nakagawa, Yoshinao
Sugimoto, Hiroshi
Tomishige, Keiichi
Venue: Scientific Reports
Publisher: Springer Science and Business Media LLC
Published: 2016-04-14
Volume: 6
Issue: 1
Pages: 24038-24038
ISSN: 2045-2322 (ISSN-L)
DOI: 10.1038/srep24038
PMC: PMC4831014
OpenAlex: W2337703519
Cited by: 122
References: 69
Citations by year: 2026: 5 · 2025: 9 · 2024: 14 · 2023: 10 · 2022: 15 · 2021: 17 · 2020: 18 · 2019: 9 · 2018: 14 · 2017: 7 · 2016: 4
FWCI: 4.10
Type: journal article
Language: en
Open access: gold
doi.org
Licence: cc-by
creativecommons.org/licenses/by/4.0 (tdm)
creativecommons.org/licenses/by/4.0 (vor)
Locations: Scientific Reports (publishedVersion, cc-by)
Europe PMC (PubMed Central) (publishedVersion, cc-by)
PubMed Central (publishedVersion, cc-by)
PubMed (publishedVersion)
Funders: ENEOS Hydrogen Trust Fund
Japan Society for the Promotion of Science (16K14050)
Precursory Research for Embryonic Science and Technology
Topics: Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
Keywords: diols, copolymerization, cerium oxide catalyst, alternating copolymers, polycarbonate, α,ω-diols, CO2 utilization

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Direct Copolymerization of CO2 and Diols

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