Dynamical signatures of molecular symmetries in nonequilibrium quantum transport
Open accessAbstract
Symmetries play a crucial role in ubiquitous systems found in Nature. In this work, we propose an elegant approach to detect symmetries by measuring quantum currents. Our detection scheme relies on initiating the system in an anti-symmetric initial condition, with respect to the symmetric sites and using a probe that acts like a local noise. Depending on the position of the probe the currents exhibit unique signatures such as a quasi-stationary plateau indicating the presence of metastability and multi-exponential decays in case of multiple symmetries. The signatures are sensitive to the characteristics of the probe and vanish completely when the timescale of the coherent system dynamics is much longer than the timescale of the probe. These results are demonstrated using a 4-site model and an archetypal example of the para-benzene ring and are shown to be robust under a weak disorder.
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Spontaneous emission of light by an excited atom is a well-known example requiring fully quantized description.
“One well-known example is the process of spontaneous emission of light by an excited atom [50, 51, 52].”
From Fundamentals of quantum mechanics in Liouville space (2020) · cites this paper as [51]
The Methods section discusses exciton transport and a quantum master equation, but does not address spontaneous emission of light by an excited atom or whether it requires a fully quantized description. Searches for those terms found no passage on that point in our copy; page numbers were not provided. (LLM, conf=0.75)
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Behera, J., Bedkihal, S., Agarwalla, B. K., & Bandyopadhyay, M. (2025) · Physica A Statistical Mechanics and its Applications · doi:10.1016/j.physa.2025.131243
Enhancing exciton transfer efficiency in an open quantum battery via architecture engineering
Khodadad, Z., & Hanna, G. (2026) · The Journal of Chemical Physics · doi:10.1063/5.0302740
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Khodadad, Z., & Hanna, G. (2026) · Springer eBooks · doi:10.1007/978-981-95-9717-8_8
- Authors
- Thingna, J., Manzano, D., & Cao, J.
- Affiliations
- Singapore-MIT Alliance for Research and Technology (SG)
- Singapore University of Technology and Design (SG)
- Corresponding author
- Cao, Jianshu
- Venue
- Scientific Reports
- Published
- 2016-06-17
- Volume
- 6
- Issue
- 1
- Pages
- 28027-28027
- ISSN
- 2045-2322 (ISSN-L)
- PMC
- PMC4911572
- OpenAlex
- W2289283187
- Cited by
- 61
- References
- 61
- Citations by year
- 2026: 4 · 2025: 5 · 2024: 4 · 2023: 3 · 2022: 10 · 2021: 7 · 2020: 10 · 2019: 3 · 2018: 5 · 2017: 5 · 2016: 5
- FWCI
- 2.84
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Scientific Reports (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- arXiv (Cornell University) (submittedVersion)
- DSpace@MIT (Massachusetts Institute of Technology) (submittedVersion, cc-by-nc)
- arXiv (Cornell University)
- Nature
- Funders
- National Science Foundation (1112825)
- Singapore University of Technology and Design
- Junta de Andalucía (291780)
- Division of Chemistry (CHE-1112825)
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Quantum and electron transport phenomena
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Quantum many-body systems
- Physical Sciences › Physics and Astronomy › Statistical and Nonlinear Physics › Advanced Thermodynamics and Statistical Mechanics
- Keywords
- molecular symmetry, nonequilibrium quantum transport, quantum current, symmetry detection, metastability, multiexponential decay, weak disorder
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