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High-resolution 13C NMR studies of cellulose and cellulose oligomers in ionic liquid solutions
Abstract
High-resolution 13C NMR studies of cellulose and cellulose oligomers dissolved in the ionic liquid (IL) 1-butyl-3-methylimidazolium chloride ([C4mim]Cl) show that the beta-(1-->4)-linked glucose oligomers are disordered in this medium and have a conformational behavior which parallels the one observed in water, and thus, reveal that the polymer is disordered in IL solution as well.
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Citations
Cited by
Applications of ionic liquids in the chemical industry
Plechkova, N. V., & Seddon, K. R. (2008) · Chem. Soc. Rev. · doi:10.1039/b006677j · Cited by 5,686
Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Dissolution of cellulose with ionic liquids and its application: a mini-review
Zhu, S., Wu, Y., Chen, Q., Yu, Z., Wang, C., Jin, S., Ding, Y., & Wu, G. (2006) · Green Chemistry · doi:10.1039/b601395c · Cited by 1,260
Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions
Fukaya, Y., Hayashi, K., Wada, M., & Ohno, H. (2008) · Green Chem. · doi:10.1039/b713289a · Cited by 775
Enhancement of cellulose saccharification kinetics using an ionic liquid pretreatment step
Dadi, A. P., Varanasi, S., & Schall, C. A. (2006) · Biotechnology and Bioengineering · doi:10.1002/bit.21047 · Cited by 574
Metadata
- Authors
- Moulthrop, J. S., Swatloski, R. P., Moyna, G., & Rogers, R. D.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Issue
- 12
- Pages
- 1557
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2129158845
- Cited by
- 345
- References
- 0
- FWCI
- 6.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Moulthrop, J. S., Swatloski, R. P., Moyna, G., & Rogers, R. D. (2005). High-resolution 13C NMR studies of cellulose and cellulose oligomers in ionic liquid solutions. Chemical Communications. https://doi.org/10.1039/b417745b
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