The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Size matters: why nanomaterials are different
Abstract
Gold is known as a shiny, yellow noble metal that does not tarnish, has a face centred cubic structure, is non-magnetic and melts at 1336 K. However, a small sample of the same gold is quite different, providing it is tiny enough: 10 nm particles absorb green light and thus appear red. The melting temperature decreases dramatically as the size goes down. Moreover, gold ceases to be noble, and 2-3 nm nanoparticles are excellent catalysts which also exhibit considerable magnetism. At this size they are still metallic, but smaller ones turn into insulators. Their equilibrium structure changes to icosahedral symmetry, or they are even hollow or planar, depending on size. The present tutorial review intends to explain the origin of this special behaviour of nanomaterials.
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Cites
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au 8 Clusters on MgO
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Nanomaterials and nanoparticles: Sources and toxicity
Buzea, C., Pacheco, I. I., & Robbie, K. (2007) · Biointerphases · doi:10.1116/1.2815690 · Cited by 3,789
Catalysis by Supported Single Metal Atoms
Liu, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b01534 · Cited by 1,331
Recent Advances in Flexible and Stretchable Bio‐Electronic Devices Integrated with Nanomaterials
Choi, S., Lee, H., Ghaffari, R., Hyeon, T., & Kim, D. (2016) · Advanced Materials · doi:10.1002/adma.201504150 · Cited by 1,104
Qu, X., Brame, J., Li, Q., & Alvarez, P. J. J. (2013) · Accounts of Chemical Research · doi:10.1021/ar300029v · Cited by 799
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Metadata
- Authors
- Roduner, E.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2006
- Volume
- 35
- Issue
- 7
- Pages
- 583
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2156043887
- Cited by
- 2,317
- References
- 3
- FWCI
- 1.83
- Type
- journal article
- Language
- en
- Open access
- closed
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