Thioketone spin traps as mediating agents for free radical polymerization processes

Living Radical Polymerization by the RAFT Process

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Kinetics of living radical polymerization

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RAFTing down under: Tales of missing radicals, fancy architectures, and mysterious holes

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Kinetic Investigations of Reversible Addition Fragmentation Chain Transfer Polymerizations: Cumyl Phenyldithioacetate Mediated Homopolymerizations of Styrene and Methyl Methacrylate

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Consistent Experimental and Theoretical Evidence for Long-Lived Intermediate Radicals in Living Free Radical Polymerization

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Ab Initio Evidence for Slow Fragmentation in RAFT Polymerization

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Kinetic applications of electron paramagnetic resonance spectroscopy. 25. Radicals formed by spin trapping with di-tert-butyl thioketone

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A New Additive for Controlled Radical Polymerization

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Chemistry of organochromium(III) complexes

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Spin trapping with thiocarbonyl compounds

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Spin trapping with phosphonothionesters. Part VI. * Phosphoryl- and thiophosphoryl-thionformates

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The Nonlinear Time‐Dependent Response of Semicrystalline Polymers: Correlations Between the Configurational Entropy and the Rate of Rearrangement of Chains

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Controlled/living radical polymerization: Features, developments, and perspectives

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Living Radical Polymerization by the RAFT Process – A Third Update

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Living Radical Polymerization by the RAFT Process—A First Update

Moad, G., Rizzardo, E., & Thang, S. H. (2006) · Australian Journal of Chemistry · doi:10.1071/ch06250 · Cited by 847 · see citing works

Controlled/Living Radical Polymerization in Dispersed Systems

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Transition metal catalysts for controlled radical polymerization

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Mechanism and kinetics of dithiobenzoate‐mediated RAFT polymerization. I. The current situation

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Mass spectrometry in polymer chemistry: a state-of-the-art up-date

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Organometallic mediated radical polymerization

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RAFT Polymerization Kinetics: Combination of Apparently Conflicting Models

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Computational Studies of RAFT Polymerization–Mechanistic Insights and Practical Applications

Coote, M. L., Krenske, E. H., & Izgorodina, E. I. (2006) · Macromolecular Rapid Communications · doi:10.1002/marc.200500832 · Cited by 130 · see citing works

The Genesis of the Reversible Radical Addition–Fragmentation–Transfer of Thiocarbonylthio Derivatives from the Barton–McCombie Deoxygenation: A Brief Account and Some Mechanistic Observations*

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Fundamentals of Controlled/Living Radical Polymerization

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RAFT polymerization kinetics: How long are the cross‐terminating oligomers?

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Towards a Better Understanding of ‘Delocalized Charge’ in Ionic Liquid Anions

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Quantum Chemical Mapping of Initialization Processes in RAFT Polymerization

Coote, M. L., Izgorodina, E. I., Krenske, E. H., Busch, M., & Barner‐Kowollik, C. (2006) · Macromolecular Rapid Communications · doi:10.1002/marc.200600170 · Cited by 72 · see citing works

Quantum‐Chemical Modeling of Free‐Radical Polymerization

Coote, M. L. (2009) · Macromolecular Theory and Simulations · doi:10.1002/mats.200900050 · Cited by 69 · see citing works

The Mechanism and Kinetics of the RAFT Process: Overview, Rates, Stabilities, Side Reactions, Product Spectrum and Outstanding Challenges

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Nitrones in synthetic polymer chemistry

Wong, E. H. H., Junkers, T., & Barner‐Kowollik, C. (2011) · Polymer Chemistry · doi:10.1039/c0py00377h · Cited by 61 · see citing works

Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals

Chernikova, E. V., Golubev, V. B., Filippov, A., Lin, C. Y., & Coote, M. L. (2010) · Polymer Chemistry · doi:10.1039/c0py00245c · Cited by 57 · see citing works

Enhanced spin capturing polymerization: An efficient and versatile protocol for controlling molecular weight distributions

Wong, E. H. H., Junkers, T., & Barner‐Kowollik, C. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23025 · Cited by 52 · see citing works

Direct Radical Copolymerizations of Thioamides To Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbones

Watanabe, H., & Kamigaito, M. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c01796 · Cited by 51 · see citing works

Retardation in RAFT Polymerization: Does Cross-Termination Occur with Short Radicals Only?

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Is the Addition‐Fragmentation Step of the RAFT Polymerisation Process Chain Length Dependent?

Izgorodina, E. I., & Coote, M. L. (2006) · Macromolecular Theory and Simulations · doi:10.1002/mats.200600021 · Cited by 50 · see citing works

Strongly electron deficient sulfonyldithioformate based RAFT agents for hetero Diels‐Alder conjugation: Computational design and experimental evaluation

Nebhani, L., Sinnwell, S., Lin, C. Y., Coote, M. L., Stenzel, M. H., & Barner‐Kowollik, C. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23647 · Cited by 50 · see citing works

How Well Can Theory Predict Addition–Fragmentation Equilibrium Constants in RAFT Polymerization?

Lin, C. Y., & Coote, M. L. (2009) · Australian Journal of Chemistry · doi:10.1071/ch09269 · Cited by 43 · see citing works

Thioketone‐Mediated Polymerization of Butyl Acrylate: Controlling Free‐Radical Polymerization via a Dormant Radical Species

Junkers, T., Stenzel, M. H., Davis, T. P., & Barner‐Kowollik, C. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200600885 · Cited by 41 · see citing works

The kinetics of enhanced spin capturing polymerization: Influence of the nitrone structure

Wong, E. H. H., Stenzel, M. H., Junkers, T., & Barner‐Kowollik, C. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23221 · Cited by 37 · see citing works

Radical Polymerization

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Radical ring-opening polymerization of sustainably-derived thionoisochromanone

Prebihalo, E. A., Luke, A. M., Reddi, Y., LaSalle, C. J., Shah, V. M., Cramer, C. J., & Reineke, T. M. (2023) · Chemical Science · doi:10.1039/d2sc06040j · Cited by 35 · see citing works

Studying the mechanism of thioketone‐mediated polymerization via electrospray ionization mass spectrometry

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Ab Initio Kinetic Modelling in Radical Polymerization: A Paradigm Shift in Reaction Kinetic Analysis

Coote, M. L., & Barner‐Kowollik, C. (2006) · Australian Journal of Chemistry · doi:10.1071/ch06194 · Cited by 25 · see citing works

Control of methyl methacrylate radical polymerization via Enhanced Spin Capturing Polymerization (ESCP)

Zang, L. Q., Wong, E. H. H., Barner‐Kowollik, C., & Junkers, T. (2010) · Polymer · doi:10.1016/j.polymer.2010.06.040 · Cited by 25 · see citing works

Revealing Model Dependencies in “Assessing the RAFT Equilibrium Constant via Model Systems: An EPR Study”

Junkers, T., Barner‐Kowollik, C., & Coote, M. L. (2011) · Macromolecular Rapid Communications · doi:10.1002/marc.201100494 · Cited by 21 · see citing works

An Ab Initio Investigation of the Chain-Length Dependence of the Addition–Fragmentation Equilibria in RAFT Polymerization

Lin, C. Y., & Coote, M. L. (2011) · Australian Journal of Chemistry · doi:10.1071/ch11069 · Cited by 19 · see citing works

Quantum‐Chemical Studies of RAFT Polymerization: Methodology, Structure‐Reactivity Correlations and Kinetic Implications

Coote, M. L., Krenske, E. H., & Izgorodina, E. I. (2008) · doi:10.1002/9783527622757.ch2 · Cited by 19 · see citing works

Low‐temperature controlled free‐radical polymerization of vinyl monomers in the presence of a novel cyclic dixanthate under γ‐ray irradiation

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Elucidation of Reaction Mechanisms and Polymer Structure: Living/Controlled Radical Polymerization

Barner‐Kowollik, C., Delaittre, G., Gruendling, T., & Pauloehrl, T. (2011) · Wiley eBooks · doi:10.1002/9783527641826.ch11 · Cited by 17 · see citing works

The Radical Chemistry of Thiocarbonylthio Compounds: An Overview

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Redox Active Compounds in Controlled Radical Polymerization and Dye‐Sensitized Solar Cells: Mutual Solutions to Disparate Problems

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Brønsted Acid Catalyzed (3+2)‐Cycloaddition of Thioketones and Indole‐2‐Carbinols Toward Thiazolo[3,4‐a]indoles

Sachse, F., & Schneider, C. (2021) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.202101168 · Cited by 12 · see citing works

Polymerization Mechanism of MMA in the Presence of 1,1‐Diphenylethylene

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Mechanism of addition-fragmentation reaction of thiocarbonyls compounds in free radical polymerization. A DFT study

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1,1‐Diphenyl Ethylene‐Mediated Radical Polymerisation: A General Non‐Metal‐Based Technique For The Synthesis Of Precise Core Cross‐Linked Star Polymers

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Formation of two centre three electron bond by hydroxyl radical induced reaction of thiocoumarin: evidence from experimental and theoretical studies

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Towards a Living Radical Polymerization of Styrene by Using Dithiolactone as a New Type of Mediating Agent

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Kinetics and Molecular Weight Development of Dithiolactone‐Mediated Radical Polymerization of Styrene

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Controlled/Living Radical Polymerization Mediated by Stable Organic Radicals

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Controlled Radical Polymerization of Styrene Mediated by Xanthene-9-thione and Its Derivatives

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An ab initio study of the mechanisms of the di- and tri-merization of thiocarbonyl compounds resulting in cyclic oligomers

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Allylthioketone Mediated Free Radical Polymerization of Methacrylates

Zhong, F., Qiu, L., Hong, C., & Pan, C. (2017) · Polymers · doi:10.3390/polym9110608 · Cited by 6 · see citing works

Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic <i>quasi</i> -block copolymers

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Thioxanthene-9-thione Mediated MMA Polymerization

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Computational Methods for Modeling Free‐Radical Polymerization

Coote, M. L., & Lin, C. Y. (2011) · doi:10.1002/9780470930779.ch13 · Cited by 4 · see citing works

Quantum Chemical Studies of RAFT Polymerization

Coote, M. L. (2021) · doi:10.1002/9783527821358.ch6 · Cited by 4 · see citing works

Degradable vinyl copolymers featuring backbone dithiocarbonates by radical copolymerization of a cyclic xanthate

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Synthesis of double-bond-containing diblock copolymers via RAFT polymerization

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Single-Unit Comonomer Insertion Initiates Radical Polymerization of Thionolactone to Give Chemically and Thermally Degradable Polythioesters

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A Remarkable Ring Opening Observed in the Reaction of Cyclopropyl Ferrocenyl Thioketone with Triiron Dodecacarbonyl Fe3(CO)12

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Ab Initio Kinetic Modeling of Free‐Radical Polymerization

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Kinetics of the Diels–Alder Reaction of Thiofluorenone with 9,10-Dimethylanthracene

Kornilov, D. A., & Газизьянович, М. А. (2024) · Russian Journal of Organic Chemistry · doi:10.1134/s1070428024040055 · Cited by 1 · see citing works

Muonium addition to the CS sulfur in conformationally regulated thiobenzophenone

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Allylthioketone mediating radical polymerization of butyl acrylate

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Radical polymerization of styrene mediated by 9-(1-phenylethyl)-9-((1-phenylethyl)thio)-9H-thioxanthene

Wang, S., Wang, L., Yu, H., Shao, J., & Yang, W. (2018) · Scientia Sinica Chimica · doi:10.1360/n032017-00204

High Hydrostatic Pressure, Temperature, and Solvent Effect on the Rate of the Diels–Alder Reaction between Thiofluorenone and trans,trans-1,4-Diphenylbuta-1,3-diene

Kornilov, D. A., & Газизьянович, М. А. (2026) · Russian Journal of Organic Chemistry · doi:10.1134/s1070428026603687

Allylthioketone Mediated Free Radical Polymerization of Methacrylates

Zhong, F., Qiu, L., Hong, C., & Pan, C. (2017) · Polymers · doi:10.3390/polym9110608 · Cited by 6 · see citing works

Thioketone‐Mediated Polymerization of Butyl Acrylate: Controlling Free‐Radical Polymerization via a Dormant Radical Species

Junkers, T., Stenzel, M. H., Davis, T. P., & Barner‐Kowollik, C. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200600885 · Cited by 41 · see citing works

Allylthioketone Mediating Radical Polymerization of Styrene

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Thioketone‐Mediated Polymerization with Dithiobenzoates: Proof for the Existence of Stable Radical Intermediates in RAFT Polymerization

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Quantum-chemical tools for understanding and controlling free-radical polymerization

Coote, M. L., & Izgorodina, E. I. (2005)