High effectiveness of oligothienylenevinylene as molecular wires in Zn-porphyrin and C60 connected systems
Abstract
Photoinduced energy transfer and electron transfer processes have been found between the excited singlet state of Zn-porphyrin and C(60) via an oligothienylenevinylene bridge depending on the length of the oligothiophene and solvent polarity.
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The exceptionally low values of the attenuation factor shown by TVs (β = 0.016 Å−1) favor excellent electronic coupling between the donor and acceptor moieties.
“The exceptionally low values of the attenuation factor shown by TVs ( b ¼ 0.016 ˚ A 1 ) favor excellent electronic coupling between the donor and acceptor moieties.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [106]
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Recent progress in porphyrin-based materials for organic solar cells
Mahmood, A., Hu, J.-Y., Xiao, B., Tang, A., Wang, X., & Zhou, E. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06392c · Cited by 311 · see citing works
Arrechea, S., Aljarilla, A., de la Cruz, P., Palomares, E., Sharma, G. D., & Langa, F. (2016) · Nanoscale · doi:10.1039/c6nr06374h · Cited by 27 · see citing works
Self-citation
- Authors
- Oswald, F., Islam, D.-M. S., Araki, Y., Troiani, V., Caballero, R., Cruz, P. D. L., Ito, O., & Langa, F.
- Affiliations
- University of Castilla-La Mancha (ES)
- Tohoku University (JP)
- Corresponding author
- Ito, Osamu
- Langa, Fernando
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2007
- Issue
- 43
- Pages
- 4498
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2042606167
- Cited by
- 42
- References
- 0
- Citations by year
- 2021: 2 · 2020: 2 · 2018: 3 · 2017: 4 · 2016: 3 · 2015: 3 · 2014: 1 · 2013: 6 · 2012: 6
- FWCI
- 1.84
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- RUIdeRA - Institutional University Repository (University of Castilla-La Mancha) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Physical Sciences › Chemistry › Organic Chemistry › Fullerene Chemistry and Applications
- Keywords
- molecular wires, zinc porphyrin, C60, photoinduced energy transfer, electron transfer, singlet excited state, solvent polarity
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