The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Catalytic dehydration of fructose into 5-hydroxymethylfurfural by ion-exchange resin in mixed-aqueous system by microwave heating
Abstract
Catalytic dehydration of fructose into 5-hydroxymethylfurfural by microwave heating was studied in acetone-water mixtures in the presence of a cation exchange resin catalyst. The use of acetone–water reaction media resulted in yields of 5-HMF as high as 73.4% for 94% conversion at 150 °C. It was confirmed that there was no decrease of catalytic activity and selectivity for five reuses of the resin, which was in accordance with the elemental analysis results that showed that sulfonic acid groups attached on the resin were stable at the experimental conditions. A comparison between conventional sand bath heating and microwave heating revealed that the latter had a remarkable accelerating effect not only on fructose conversion, but also on 5-HMF yield. Under the conditions (5 ml of 2 wt% fructose solution, 0.1 g of resin, 150 °C and 10 min), fructose conversion and HMF yields by microwave heating (91.7% and 70.3%, respectively) were higher than those by sand bath heating (22.1% and 13.9% respectively). Therefore, the process that we developed in this study showed that high 5-HMF yields from fructose could be achieved under mild conditions.
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Cites
Controlled Microwave Heating in Modern Organic Synthesis
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Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose
Román-Leshkov, Y., Chheda, J. N., & Dumesic, J. A. (2006) · Science · doi:10.1126/science.1126337 · Cited by 1,670
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Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
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Biomass into chemicals: Conversion of sugars to furan derivatives by catalytic processes
Tong, X., Ma, Y., & Li, Y. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2010.06.049 · Cited by 847
Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R. (2011) · Chemical Reviews · doi:10.1021/cr100171a · Cited by 800
Weingarten, R., Cho, J., Conner, Jr., & Huber, G. W. (2010) · Green Chemistry · doi:10.1039/c003459b · Cited by 408
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Metadata
- Authors
- Qi, X., Watanabe, M., Aida, T. M., & Smith, Jr.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 7
- Pages
- 799
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2039108277
- Cited by
- 379
- References
- 34
- FWCI
- 14.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Qi, X., Watanabe, M., Aida, T. M., & Smith, Jr. (2008). Catalytic dehydration of fructose into 5-hydroxymethylfurfural by ion-exchange resin in mixed-aqueous system by microwave heating. Green Chemistry. https://doi.org/10.1039/b801641k
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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