The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters
Open accessAbstract
A new heteroleptic ethyl-zinc complex stabilized by a chelating bis(morpholinomethyl)phenoxy ligand has been synthesised and shown to be a highly potent initiator for the immortal ring-opening polymerisation (ROP) of lactide and beta-butyrolactone, being able to convert up to 50,000 equiv. of monomer in the presence of up to 1000 equiv. of an alcohol as transfer agent. Two related heteroleptic complexes of magnesium and calcium have also been prepared. These complexes are stable in solution, even in the presence of large amounts of alcohol, and constitute effective catalysts for the immortal ROP of lactide under mild conditions.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
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Controlled Ring-Opening Polymerization of Lactide and Glycolide
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Organocatalytic Ring-Opening Polymerization
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Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism
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Polymerization of lactide and related cyclic esters by discrete metal complexes
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Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization
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Lewis acid catalyzed polymerization of L-lactide. Kinetics and mechanism of the bulk polymerization
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Self-citation
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Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates
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Thevenon, A., Romain, C., Bennington, M. S., White, A. J. P., Davidson, H. J., Brooker, S., & Williams, C. K. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602930 · Cited by 151
Metadata
- Authors
- Poirier, V., Roisnel, T., Carpentier, J.-F., & Sarazin, Y.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Issue
- 44
- Pages
- 9820
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2051848007
- Cited by
- 219
- References
- 13
- FWCI
- 10.67
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Poirier, V., Roisnel, T., Carpentier, J.-F., & Sarazin, Y. (2009). Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters. Dalton Transactions. https://doi.org/10.1039/b917799j
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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