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Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry
Abstract
Electronic and steric ligand effects both play major roles in organometallic chemistry and consequently in metal-mediated catalysis. Quantifying such parameters is of interest to better understand not only the parameters governing catalyst performance but also reaction mechanisms. Nowadays, ligand molecular architectures are becoming significantly more elaborate and existing models describing ligand sterics prove lacking. This review presents the development of a more general method to determine the steric parameter of organometallic ligands. Two case studies are presented: the tertiary phosphines and the N-heterocyclic carbenes.
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Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
Cited by
Fortman, G. C., & Nolan, S. P. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15088j · Cited by 1,258
Self-citationComputational Ligand Descriptors for Catalyst Design
Durand, D. J., & Fey, N. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00588 · Cited by 406
Vummaleti, S. V. C., Nelson, D. J., Poater, A., Gómez-Suárez, A., Cordes, D. B., Slawin, A. M. Z., Nolan, S. P., & Cavallo, L. (2015) · Chemical Science · doi:10.1039/c4sc03264k · Cited by 286
Self-citationMechanistic Aspects of the Palladium‐Catalyzed Suzuki‐Miyaura Cross‐Coupling Reaction
D'Alterio, M. C., Casals‐Cruañas, È., Tzouras, N. V., Talarico, G., Nolan, S. P., & Poater, A. (2021) · Chemistry – A European Journal · doi:10.1002/chem.202101880 · Cited by 281
Self-citationMikami, K. (2020) · Polymer · doi:10.1016/j.polymer.2020.122738 · Cited by 22
Metadata
- Authors
- Clavier, H., & Nolan, S. P.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 46
- Issue
- 6
- Pages
- 841
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2139078293
- Cited by
- 1,098
- References
- 1
- FWCI
- 28.26
- Type
- journal article
- Language
- en
- Open access
- closed
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