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CO2 activation and promotional effect in the oxidation of cyclic olefins over mesoporous carbon nitrides
Abstract
Mesoporous carbon nitrides (MCN) were prepared by a nano-casting method using mesoporous silica as a template with different carbon and nitrogen sources like melamine only (MS-MCN), urea-formaldehyde (UF-MCN) and melamine-glyoxal (MG-MCN). These mesoporous carbon nitride materials possess nitrogen moieties which behave like a CO2-philic surface facilitating oxidation of cyclic olefins by molecular oxygen in the co-presence of CO2 below supercritical conditions. The co-presence of CO2 augmented the conversions of cyclic olefins at low pressures of CO2, depicting a promotional effect. Approaches towards quantification of promotional effects and insights into the promotional aspects have been studied.
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Cites
A Mild Hydrothermal Route to Fix Carbon Dioxide to Simple Carboxylic Acids
He, C., Tian, G., Liu, Z., & Feng, S. (2010) · Organic Letters · doi:10.1021/ol9025414 · Cited by 116
Cited by
Zheng, Y., Liu, J., Liang, J., Jaroniec, M., & Qiao, S. Z. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03479d · Cited by 1,741
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2
Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., et al. (2014) · Science · doi:10.1126/science.1253057 · Cited by 1,452
Alves, M., Grignard, B., Mereau, R., Jerome, C., Tassaing, T., & Detrembleur, C. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy00438a · Cited by 531
Design and fabrication of mesoporous heterogeneous basic catalysts
Sun, L.-B., Liu, X.-Q., & Zhou, H.-C. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00090d · Cited by 386
Photoelectrochemical CO2 reduction by a p-type boron-doped g-C3N4 electrode under visible light
Sagara, N., Kamimura, S., Tsubota, T., & Ohno, T. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.03.055 · Cited by 361
Metadata
- Authors
- Ansari, M. B., Min, B.-H., Mo, Y.-H., & Park, S.-E.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 13
- Issue
- 6
- Pages
- 1416
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1981590485
- Cited by
- 162
- References
- 1
- FWCI
- 6.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: CO2 activation and promotional effect in the oxidation of cyclic olefins over mesoporous carbon nitrides. https://app.cochat.ai/papers/10.1039/c0gc00951b
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- Ansari, M. B., Min, B.-H., Mo, Y.-H., & Park, S.-E. (2011). CO2 activation and promotional effect in the oxidation of cyclic olefins over mesoporous carbon nitrides. Green Chemistry. https://doi.org/10.1039/c0gc00951b
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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