A porphyrin-hexa-peri-hexabenzocoronene-porphyrin triad: synthesis, photophysical properties and performance in a photovoltaic device
Abstract
Hexa-peri-hexabenzocoronene (HBC) is a discotic polycyclic aromatic hydrocarbon with good charge transport characteristics while the light harvesting property of porphyrins is well-known. In order to take advantage of the properties of both materials, a porphyrin-hexa-peri-hexabenzocoronene-porphyrin triad 6 was synthesised for the first time. In photoluminescence studies, the emission from the higher energy HBC unit was completely quenched by the porphyrin unit indicating efficient energy transfer. This novel hybrid material 6 was tested in bulk heterojunction photovoltaic devices reaching a power conversion efficiency of 1.2%.
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F1 showed an efficiency of 1.20% that is higher than that of zinc-containing F2 (0.87%).
“F1 showed an e ffi ciency of 1.20% that is higher than that of zinc-containing F2 (0.87%).”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [115]
Cites
Acid-diffusion behaviour in organic thin films and its effect on patterning
Lee, J.-K., Chatzichristidi, M., Zakhidov, A. A., Hwang, H. S., Schwartz, E. L., Sha, J., Taylor, P. G., Fong, H. H., DeFranco, J. A., Murotani, E., et al. (2009) · Journal of Materials Chemistry · doi:10.1039/b817286b · Cited by 25 · see citing works
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Recent progress in porphyrin-based materials for organic solar cells
Mahmood, A., Hu, J.-Y., Xiao, B., Tang, A., Wang, X., & Zhou, E. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06392c · Cited by 311 · see citing works
Luo, X., Wu, F., Xiao, H., Guo, H., Liu, Y., & Tan, S. (2017) · Synthetic Metals · doi:10.1016/j.synthmet.2016.11.026 · Cited by 10 · see citing works
- Authors
- Wong, W. W. H., Khoury, T., Vak, D., Yan, C., Jones, D. J., Crossley, M. J., & Holmes, A. B.
- Affiliations
- The University of Melbourne (AU)
- The University of Sydney (AU)
- Corresponding author
- Wong, Wallace W. H.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 20
- Issue
- 33
- Pages
- 7005
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W1979342308
- Cited by
- 63
- References
- 1
- Citations by year
- 2026: 1 · 2025: 1 · 2023: 3 · 2022: 2 · 2021: 2 · 2020: 9 · 2019: 6 · 2018: 4 · 2017: 7 · 2016: 5 · 2015: 6 · 2014: 4 · 2013: 3 · 2012: 5
- FWCI
- 2.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Properties of Aromatic Compounds
- Keywords
- porphyrins, hexa-peri-hexabenzocoronene, discotic liquid crystals, energy transfer, photoluminescence quenching, bulk heterojunction solar cells, photovoltaic performance, charge transport, polycyclic aromatic hydrocarbons
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