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Wastewater treatment with heterogeneous Fenton-type catalysts based on porous materials
Abstract
The Fenton reagent which was discovered by H. J. H. Fenton over 100 years ago is still of special interest for wastewater treatment in the present time. The main objective of heterogeneous Fenton catalysts is the combination of high activity, low iron leaching and the possibility of employing the system at pH environments near neutrality. This review discusses the use of iron-containing pillared clays as well as micro- and mesoporous (alumino-) silicate catalysts prepared by ion-exchange, impregnation or direct synthesis for the degradation of organic compounds like phenol and organic dyes including Orange II. Moreover, the treatment of more complex waste streams is reviewed. After a general introduction into the chemistry of the Fenton and the photo-Fenton reaction as well as the catalysts employed, specific examples are discussed with respect to the active species present, the stability of the catalyst and the influence of reaction conditions such as pH, temperature and the presence of impurities.
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Cites
LXXIII.—Oxidation of tartaric acid in presence of iron
Fenton, H. J. H. (1894) · J. Chem. Soc., Trans. · doi:10.1039/ct8946500899 · Cited by 3,179
De Laat, J., & Gallard, H. (1999) · Environmental Science & Technology · doi:10.1021/es981171v · Cited by 749
Cited by
Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes
Bokare, A. D., & Choi, W. (2014) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2014.04.054 · Cited by 2,368
Role of nanomaterials in water treatment applications: A review
Santhosh, C., Velmurugan, V., Jacob, G., Jeong, S. K., Grace, A. N., & Bhatnagar, A. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.08.053 · Cited by 1,256
A review on Fenton-like processes for organic wastewater treatment
Wang, N., Zheng, T., Zhang, G., & Wang, P. (2016) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2015.12.016 · Cited by 1,018
Heterogeneous Fenton catalysts: A review of recent advances
Thomas, N., Dionysiou, D. D., & Pillai, S. C. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.124082 · Cited by 889
Interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials: A review
He, J., Yang, X., Men, B., & Wang, D. (2016) · Journal of Environmental Sciences · doi:10.1016/j.jes.2015.12.003 · Cited by 587
Metadata
- Authors
- Hartmann, M., Kullmann, S., & Keller, H.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 20
- Issue
- 41
- Pages
- 9002
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2050745240
- Cited by
- 420
- References
- 2
- FWCI
- 13.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hartmann, M., Kullmann, S., & Keller, H. (2010). Wastewater treatment with heterogeneous Fenton-type catalysts based on porous materials. Journal of Materials Chemistry. https://doi.org/10.1039/c0jm00577k
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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