The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Structure sensitivity and nanoscale effects in electrocatalysis
Abstract
This review discusses the role of the detailed nanoscale structure of catalytic surfaces on the activity of various electrocatalytic reactions of importance for fuel cells, hydrogen production, and other environmentally important catalytic reactions, such as carbon monoxide oxidation, methanol and ethanol oxidation, ammonia oxidation, nitric oxide reduction, hydrogen evolution, and oxygen reduction. Specifically, results and insights obtained from surface-science single-crystal-based model experiments are linked to experiments on well-defined shape-controlled nanoparticles. A classification of structure sensitive effects in electrocatalysis is suggested, based both on empirical grounds and on quantum-chemical viz. thermochemical considerations. The mutual relation between the two classification schemes is also discussed. The review underscores the relevance of single-crystal modeling of nanoscale effects in catalysis, and points to the special role of two kinds of active sites for electrocatalysis on nanoparticulate surfaces: (i) steps and defects in (111) terraces or facets, and (ii) long-range (100) terraces or facets.
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Cites
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Cited by
Zheng, Y., Jiao, Y., Vasileff, A., & Qiao, S. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710556 · Cited by 1,489
Oxygen Reduction in Alkaline Media: From Mechanisms to Recent Advances of Catalysts
Ge, X., Sumboja, A., Wuu, D., An, T., Li, B., Goh, F. W. T., Hor, T. S. A., Zong, Y., & Liu, Z. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00524 · Cited by 1,341
Powering denitrification: the perspectives of electrocatalytic nitrate reduction
Duca, M., & Koper, M. T. M. (2012) · Energy & Environmental Science · doi:10.1039/c2ee23062c · Cited by 699
Self-citationHigh-entropy alloys in electrocatalysis: from fundamentals to applications
Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551
Nanoparticle Silver Catalysts That Show Enhanced Activity for Carbon Dioxide Electrolysis
Salehi-Khojin, A., Jhong, H.-R. M., Rosen, B. A., Zhu, W., Ma, S., Kenis, P. J. A., & Masel, R. I. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp310509z · Cited by 435
Metadata
- Authors
- Koper, M. T. M.
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 3
- Issue
- 5
- Pages
- 2054
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2060455496
- Cited by
- 468
- References
- 11
- FWCI
- 13.79
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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