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Understanding the polarity of ionic liquids
Abstract
The polarities of a wide range of ionic liquids have been determined using the Kamlet-Taft empirical polarity scales α, β and π*, with the dye set Reichardt's Dye, N,N-diethyl-4-nitroaniline and 4-nitroaniline. These have been compared to measurements of these parameters with different dye sets and to different polarity scales. The results emphasise the importance of recognising the role that the nature of the solute plays in determining these scales. It is particularly noted that polarity scales based upon charged solutes can give very different values for the polarity of ionic liquids compared to those based upon neutral probes. Finally, the effects of commonplace impurities in ionic liquids are reported.
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Citations
Cites
Applications of ionic liquids in the chemical industry
Plechkova, N. V., & Seddon, K. R. (2008) · Chem. Soc. Rev. · doi:10.1039/b006677j · Cited by 5,686
Esterification in Ionic Liquids: The Influence of Solvent Basicity
Wells, T. P., Hallett, J. P., Williams, C. K., & Welton, T. (2008) · The Journal of Organic Chemistry · doi:10.1021/jo8005864 · Cited by 65
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Cited by
Deconstruction of lignocellulosic biomass with ionic liquids
Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557
Self-citationThe Electrostatic Screening Length in Concentrated Electrolytes Increases with Concentration
Smith, A. M., Lee, A. A., & Perkin, S. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00867 · Cited by 611
Dyson, P. J., & Jessop, P. G. (2016) · Catalysis Science & Technology · doi:10.1039/c5cy02197a · Cited by 382
Metadata
- Authors
- Ab Rani, M. A., Brant, A., Crowhurst, L., Dolan, A., Lui, M., Hassan, N. H., Hallett, J. P., Hunt, P. A., Niedermeyer, H., Perez-Arlandis, J. M., Schrems, M., Welton, T., & Wilding, R.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 13
- Issue
- 37
- Pages
- 16831
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2140723396
- Cited by
- 524
- References
- 2
- FWCI
- 16.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ab Rani, M. A., Brant, A., Crowhurst, L., Dolan, A., Lui, M., Hassan, N. H., Hallett, J. P., Hunt, P. A., Niedermeyer, H., Perez-Arlandis, J. M., Schrems, M., Welton, T., & Wilding, R. (2011). Understanding the polarity of ionic liquids. Physical Chemistry Chemical Physics. https://doi.org/10.1039/c1cp21262a
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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