The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Catalytic production of levulinic acid from cellulose and other biomass-derived carbohydrates with sulfonated hyperbranched poly(arylene oxindole)s
Abstract
Innovative catalyst design holds the key to fundamental advances in the transformation of cellulose to chemicals and transportation fuels, both of which are vital to meet the challenge of increasing energy costs and the finite nature of fossil fuel reserves. Here we report on the functionalization, characterization and successful application of sulfonated hyperbranched poly(arylene oxindole)s for the direct catalytic conversion of cellulose to levulinic acid. The use of water-soluble hyperbranched polymers in combination with ultrafiltration is conceptually novel and opens new horizons in the aqueous-phase processing of cellulose substrates with various degrees of crystallinity. Compared to most conventional types of acid catalysts, these highly acidic polymers demonstrate superior catalytic performance in terms of both activity and selectivity. Additionally, this molecular approach can be successfully transferred to the acid-catalyzed degradation of other abundant biomass resources, including starch, inulin and xylan.
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Citations
Cites
Catalytic conversion of biomass to biofuels
Alonso, D. M., Bond, J. Q., & Dumesic, J. A. (2010) · Green Chemistry · doi:10.1039/c004654j · Cited by 2,333
Acid-Catalyzed Production of 5-Hydroxymethyl Furfural from d-Fructose in Subcritical Water
Salak Asghari, F., & Yoshida, H. (2006) · Industrial & Engineering Chemistry Research · doi:10.1021/ie051088y · Cited by 500
Solubility of Carbohydrates in Ionic Liquids
Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R. (2010) · Energy & Fuels · doi:10.1021/ef901215m · Cited by 490
Cited by
From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis
Kang, S., Fu, J., & Zhang, G. (2018) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2018.06.016 · Cited by 580
Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass
Kobayashi, H., & Fukuoka, A. (2013) · Green Chemistry · doi:10.1039/c3gc00060e · Cited by 489
Yan, K., Jarvis, C., Gu, J., & Yan, Y. (2015) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2015.07.021 · Cited by 366
Abdelrahman, O. A., Heyden, A., & Bond, J. Q. (2014) · ACS Catalysis · doi:10.1021/cs401177p · Cited by 316
Iglesias, J., Martínez-Salazar, I., Maireles-Torres, P., Martin Alonso, D., Mariscal, R., & López Granados, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00177e · Cited by 292
Metadata
- Authors
- Van de Vyver, S., Thomas, J., Geboers, J., Keyzer, S., Smet, M., Dehaen, W., Jacobs, P. A., & Sels, B. F.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 4
- Issue
- 9
- Pages
- 3601
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2143375710
- Cited by
- 225
- References
- 3
- FWCI
- 14.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- Van de Vyver, S., Thomas, J., Geboers, J., Keyzer, S., Smet, M., Dehaen, W., Jacobs, P. A., & Sels, B. F. (2011). Catalytic production of levulinic acid from cellulose and other biomass-derived carbohydrates with sulfonated hyperbranched poly(arylene oxindole)s. Energy & Environmental Science. https://doi.org/10.1039/c1ee01418h
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