The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
Postsynthetic ligand exchange as a route to functionalization of ‘inert’ metal–organic frameworks
Abstract
Herein, we report that the exchange of ligands from an intact metal–organic framework (MOF) can be exploited as a means to introduce functionalized ligands into MOFs under mild conditions. It is shown that ligand exchange can occur with ‘inert’ Zr(IV)-based UiO-66 MOFs in a solvent dependent manner. We call this process postsynthetic exchange (PSE) and show that it provides access to MOFs that are not readily prepared in high quality by solvothermal methods. It was found that ligand exchange can occur between UiO-66 MOFs as monitored by aerosol time-of-flight mass spectrometry (ATOFMS). ATOFMS was used to analyze the chemical composition of microcrystalline MOFs on the single particle level, providing information not available through bulk analysis. PSE is an important postsynthetic approach to the modification of MOFs, and the ligand exchange revealed by ATOFMS requires a re-evaluation of the assumed ‘stability’ of even the most robust MOFs.
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Cites
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Proton Transport in Metal–Organic Frameworks
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Metal–Organic Frameworks for Food Safety
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Metal-organic frameworks: Challenges and opportunities for ion-exchange/sorption applications
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When defects turn into virtues: The curious case of zirconium-based metal-organic frameworks
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Regeneration, degradation, and toxicity effect of MOFs: Opportunities and challenges
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Metadata
- Authors
- Kim, M., Cahill, J. F., Su, Y., Prather, K. A., & Cohen, S. M.
- Venue
- Chem. Sci.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 3
- Issue
- 1
- Pages
- 126-130
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W2151545559
- Cited by
- 455
- References
- 26
- FWCI
- 19.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kim, M., Cahill, J. F., Su, Y., Prather, K. A., & Cohen, S. M. (2012). Postsynthetic ligand exchange as a route to functionalization of ‘inert’ metal–organic frameworks. Chem. Sci. https://doi.org/10.1039/c1sc00394a
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